Electrochemical Behavior of 4-keto Isophorone in Non-Aqueous Medium in the Presence of Carbon Dioxide

Detalhes bibliográficos
Autor(a) principal: Andrade,A.R. de
Data de Publicação: 1998
Outros Autores: Boodts,J.F.C.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000200007
Resumo: The kinetics of the slow coupling of CO2 with the anion-radical of 4-keto isophorone (4KI) in acetonitrile and on a gold/amalgamated electrode has been analyzed by using cyclic voltammetry and double potential step chronoamperometry. The coupling rate is estimated as 0.35 s-1 and the electrode mechanism at slow sweep rates (nu < 1 V s-1) is predominantly DISP1.
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spelling Electrochemical Behavior of 4-keto Isophorone in Non-Aqueous Medium in the Presence of Carbon Dioxide4-keto isophoronekinetcsCO2 and ECE-DISP mechanismThe kinetics of the slow coupling of CO2 with the anion-radical of 4-keto isophorone (4KI) in acetonitrile and on a gold/amalgamated electrode has been analyzed by using cyclic voltammetry and double potential step chronoamperometry. The coupling rate is estimated as 0.35 s-1 and the electrode mechanism at slow sweep rates (nu < 1 V s-1) is predominantly DISP1.Sociedade Brasileira de Química1998-04-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000200007Journal of the Brazilian Chemical Society v.9 n.2 1998reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50531998000200007info:eu-repo/semantics/openAccessAndrade,A.R. deBoodts,J.F.C.eng2005-12-12T00:00:00Zoai:scielo:S0103-50531998000200007Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2005-12-12T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Electrochemical Behavior of 4-keto Isophorone in Non-Aqueous Medium in the Presence of Carbon Dioxide
title Electrochemical Behavior of 4-keto Isophorone in Non-Aqueous Medium in the Presence of Carbon Dioxide
spellingShingle Electrochemical Behavior of 4-keto Isophorone in Non-Aqueous Medium in the Presence of Carbon Dioxide
Andrade,A.R. de
4-keto isophorone
kinetcs
CO2 and ECE-DISP mechanism
title_short Electrochemical Behavior of 4-keto Isophorone in Non-Aqueous Medium in the Presence of Carbon Dioxide
title_full Electrochemical Behavior of 4-keto Isophorone in Non-Aqueous Medium in the Presence of Carbon Dioxide
title_fullStr Electrochemical Behavior of 4-keto Isophorone in Non-Aqueous Medium in the Presence of Carbon Dioxide
title_full_unstemmed Electrochemical Behavior of 4-keto Isophorone in Non-Aqueous Medium in the Presence of Carbon Dioxide
title_sort Electrochemical Behavior of 4-keto Isophorone in Non-Aqueous Medium in the Presence of Carbon Dioxide
author Andrade,A.R. de
author_facet Andrade,A.R. de
Boodts,J.F.C.
author_role author
author2 Boodts,J.F.C.
author2_role author
dc.contributor.author.fl_str_mv Andrade,A.R. de
Boodts,J.F.C.
dc.subject.por.fl_str_mv 4-keto isophorone
kinetcs
CO2 and ECE-DISP mechanism
topic 4-keto isophorone
kinetcs
CO2 and ECE-DISP mechanism
description The kinetics of the slow coupling of CO2 with the anion-radical of 4-keto isophorone (4KI) in acetonitrile and on a gold/amalgamated electrode has been analyzed by using cyclic voltammetry and double potential step chronoamperometry. The coupling rate is estimated as 0.35 s-1 and the electrode mechanism at slow sweep rates (nu < 1 V s-1) is predominantly DISP1.
publishDate 1998
dc.date.none.fl_str_mv 1998-04-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000200007
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000200007
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50531998000200007
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.9 n.2 1998
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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