Kinetics and Product Analysis of the Electrochemical Dehalogenation of Hexachlorobenzene

Detalhes bibliográficos
Autor(a) principal: Gallardo-Rivas,Nohra V.
Data de Publicação: 2015
Outros Autores: Guzman,Javier, Gutierrez-Granados,Silvia, Garcia-Jimenez,Maria Guadalupe, Ibanez,Jorge G., Paramo-Garcia,Ulises
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532015000400790
Resumo: A method for establishing the kinetics and products of the electrochemical degradation of hexachlorobenzene (HCB) is described. One plausible way of reducing HCB´s toxicity is through cathodic dehalogenation. The characterization of products formed during the electrochemical reduction and the reaction kinetics are both reported. Pentachlorobenzene (PCB), tetrachlorobenzene (TCB) and trichlorobenzene (TriCB) were identified among the degradation products by high performance liquid chromatography (HPLC) with ultraviolet (UV) detection. The kinetics is analyzed under different electrolysis conditions.
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spelling Kinetics and Product Analysis of the Electrochemical Dehalogenation of Hexachlorobenzenehexachlorobenzeneelectrochemical dehalogenationkineticsA method for establishing the kinetics and products of the electrochemical degradation of hexachlorobenzene (HCB) is described. One plausible way of reducing HCB´s toxicity is through cathodic dehalogenation. The characterization of products formed during the electrochemical reduction and the reaction kinetics are both reported. Pentachlorobenzene (PCB), tetrachlorobenzene (TCB) and trichlorobenzene (TriCB) were identified among the degradation products by high performance liquid chromatography (HPLC) with ultraviolet (UV) detection. The kinetics is analyzed under different electrolysis conditions.Sociedade Brasileira de Química2015-04-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532015000400790Journal of the Brazilian Chemical Society v.26 n.4 2015reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20150041info:eu-repo/semantics/openAccessGallardo-Rivas,Nohra V.Guzman,JavierGutierrez-Granados,SilviaGarcia-Jimenez,Maria GuadalupeIbanez,Jorge G.Paramo-Garcia,Uliseseng2015-05-11T00:00:00Zoai:scielo:S0103-50532015000400790Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2015-05-11T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Kinetics and Product Analysis of the Electrochemical Dehalogenation of Hexachlorobenzene
title Kinetics and Product Analysis of the Electrochemical Dehalogenation of Hexachlorobenzene
spellingShingle Kinetics and Product Analysis of the Electrochemical Dehalogenation of Hexachlorobenzene
Gallardo-Rivas,Nohra V.
hexachlorobenzene
electrochemical dehalogenation
kinetics
title_short Kinetics and Product Analysis of the Electrochemical Dehalogenation of Hexachlorobenzene
title_full Kinetics and Product Analysis of the Electrochemical Dehalogenation of Hexachlorobenzene
title_fullStr Kinetics and Product Analysis of the Electrochemical Dehalogenation of Hexachlorobenzene
title_full_unstemmed Kinetics and Product Analysis of the Electrochemical Dehalogenation of Hexachlorobenzene
title_sort Kinetics and Product Analysis of the Electrochemical Dehalogenation of Hexachlorobenzene
author Gallardo-Rivas,Nohra V.
author_facet Gallardo-Rivas,Nohra V.
Guzman,Javier
Gutierrez-Granados,Silvia
Garcia-Jimenez,Maria Guadalupe
Ibanez,Jorge G.
Paramo-Garcia,Ulises
author_role author
author2 Guzman,Javier
Gutierrez-Granados,Silvia
Garcia-Jimenez,Maria Guadalupe
Ibanez,Jorge G.
Paramo-Garcia,Ulises
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Gallardo-Rivas,Nohra V.
Guzman,Javier
Gutierrez-Granados,Silvia
Garcia-Jimenez,Maria Guadalupe
Ibanez,Jorge G.
Paramo-Garcia,Ulises
dc.subject.por.fl_str_mv hexachlorobenzene
electrochemical dehalogenation
kinetics
topic hexachlorobenzene
electrochemical dehalogenation
kinetics
description A method for establishing the kinetics and products of the electrochemical degradation of hexachlorobenzene (HCB) is described. One plausible way of reducing HCB´s toxicity is through cathodic dehalogenation. The characterization of products formed during the electrochemical reduction and the reaction kinetics are both reported. Pentachlorobenzene (PCB), tetrachlorobenzene (TCB) and trichlorobenzene (TriCB) were identified among the degradation products by high performance liquid chromatography (HPLC) with ultraviolet (UV) detection. The kinetics is analyzed under different electrolysis conditions.
publishDate 2015
dc.date.none.fl_str_mv 2015-04-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532015000400790
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532015000400790
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.5935/0103-5053.20150041
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.26 n.4 2015
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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