A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors

Detalhes bibliográficos
Autor(a) principal: Santos,Alcindo A. dos
Data de Publicação: 2001
Outros Autores: Clososki,Giuliano C., Simonelli,Fabio, Oliveira,Alfredo R. M. de, Marques,Francisco de A., Zarbin,Paulo H. G.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000500011
Resumo: Introduction of a synthon equivalent to a carboxymethyl anion to enones and nitroalkenes, through a 1,4-addition reaction of 2,4,4-trimethyl-2-oxazoline cyanocuprate 3, proved to be an interesting methodology for the synthesis of natural products such as (±)-methyl jasmonate (1) and (±)-baclofen (2).
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spelling A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors2-oxazoline cyanocuprate1,4-additiontandem reactionmethyl jasmonatebaclofenIntroduction of a synthon equivalent to a carboxymethyl anion to enones and nitroalkenes, through a 1,4-addition reaction of 2,4,4-trimethyl-2-oxazoline cyanocuprate 3, proved to be an interesting methodology for the synthesis of natural products such as (±)-methyl jasmonate (1) and (±)-baclofen (2).Sociedade Brasileira de Química2001-10-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000500011Journal of the Brazilian Chemical Society v.12 n.5 2001reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532001000500011info:eu-repo/semantics/openAccessSantos,Alcindo A. dosClososki,Giuliano C.Simonelli,FabioOliveira,Alfredo R. M. deMarques,Francisco de A.Zarbin,Paulo H. G.eng2001-11-01T00:00:00Zoai:scielo:S0103-50532001000500011Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2001-11-01T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors
title A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors
spellingShingle A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors
Santos,Alcindo A. dos
2-oxazoline cyanocuprate
1,4-addition
tandem reaction
methyl jasmonate
baclofen
title_short A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors
title_full A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors
title_fullStr A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors
title_full_unstemmed A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors
title_sort A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors
author Santos,Alcindo A. dos
author_facet Santos,Alcindo A. dos
Clososki,Giuliano C.
Simonelli,Fabio
Oliveira,Alfredo R. M. de
Marques,Francisco de A.
Zarbin,Paulo H. G.
author_role author
author2 Clososki,Giuliano C.
Simonelli,Fabio
Oliveira,Alfredo R. M. de
Marques,Francisco de A.
Zarbin,Paulo H. G.
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Santos,Alcindo A. dos
Clososki,Giuliano C.
Simonelli,Fabio
Oliveira,Alfredo R. M. de
Marques,Francisco de A.
Zarbin,Paulo H. G.
dc.subject.por.fl_str_mv 2-oxazoline cyanocuprate
1,4-addition
tandem reaction
methyl jasmonate
baclofen
topic 2-oxazoline cyanocuprate
1,4-addition
tandem reaction
methyl jasmonate
baclofen
description Introduction of a synthon equivalent to a carboxymethyl anion to enones and nitroalkenes, through a 1,4-addition reaction of 2,4,4-trimethyl-2-oxazoline cyanocuprate 3, proved to be an interesting methodology for the synthesis of natural products such as (±)-methyl jasmonate (1) and (±)-baclofen (2).
publishDate 2001
dc.date.none.fl_str_mv 2001-10-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000500011
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000500011
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532001000500011
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.12 n.5 2001
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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