Antimony (V) Oxide Adsorbed on a Silica-Zirconia Mixed Oxide Obtained by the Sol-Gel Processing Method: Preparation and Acid Properties

• Autor(a) principal: Zaitseva,Galina
• Data de Publicação: 2002
• Outros Autores: Gushikem,Yoshitaka
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Journal of the Brazilian Chemical Society (Online)
• Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000500011
• topic: sol-gel method; silica-zirconia-antimony mixed oxide; Brønsted; Lewis acid sites

The preparation, degree of dispersion, thermal stability and Lewis and Brønsted acidity of antimony (V) oxide adsorbed on SiO2/ZrO2 mixed oxide, previously prepared by the sol-gel processing method, are described herein. The samples SiO2/ZrO2/Sb2O5, with compositions (in wt %): (a) Zr= 8.1 and Sb= 6.3; (b) Zr= 14.9 and Sb= 11.4, were prepared. Scanning electron microscopy images connected to a X-ray energy dispersive spectrometer showed that both metals, Zr and Sb, were highly dispersed in the matrices. The X-ray diffraction patterns of SiO2/ZrO2/Sb2O5 heated at different temperatures showed that, up to 1023 K, the matrix was amorphous. At 1273 K a crystalline phase of ZrO2 (baddeleyite) was observed and raising the temperature to 1573 K, crystalline phases of SiO2 (cristobalite) and presumably of ZrO2/Sb2O5 were observed. Using pyridine as a molecular probe, Brønsted acid sites on the SiO2/ZrO2/Sb2O5 matrix, heat treated up to 523 K, were shown to be very stable.