Synthesis and characterization of organic-inorganic hybrids formed between conducting polymers and crystalline antimonic acid

Detalhes bibliográficos
Autor(a) principal: Beleze,Fábio A.
Data de Publicação: 2001
Outros Autores: Zarbin,Aldo J. G.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000400017
Resumo: In this paper we report the synthesis and characterization of novel organic-inorganic hybrid materials between the crystalline antimonic acid (CAA) and two conductive polymers: polypyrrole and polyaniline. The hybrids were obtained by in situ oxidative polymerization of monomers by the Sb(V) present in the pyrochlore-like CAA structure. The materials were characterized by infrared and Raman spectroscopy, X-ray diffraction, cyclic voltammetry, CHN elemental analysis and electronic paramagnetic resonance spectroscopy. The results showed that both polymers were formed in their oxidized form, with the CAA structure acting as a counter anion.
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spelling Synthesis and characterization of organic-inorganic hybrids formed between conducting polymers and crystalline antimonic acidorganic-inorganic hybrid materialsconducting polymerscrystalline antimonic acidIn this paper we report the synthesis and characterization of novel organic-inorganic hybrid materials between the crystalline antimonic acid (CAA) and two conductive polymers: polypyrrole and polyaniline. The hybrids were obtained by in situ oxidative polymerization of monomers by the Sb(V) present in the pyrochlore-like CAA structure. The materials were characterized by infrared and Raman spectroscopy, X-ray diffraction, cyclic voltammetry, CHN elemental analysis and electronic paramagnetic resonance spectroscopy. The results showed that both polymers were formed in their oxidized form, with the CAA structure acting as a counter anion.Sociedade Brasileira de Química2001-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000400017Journal of the Brazilian Chemical Society v.12 n.4 2001reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532001000400017info:eu-repo/semantics/openAccessBeleze,Fábio A.Zarbin,Aldo J. G.eng2001-10-17T00:00:00Zoai:scielo:S0103-50532001000400017Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2001-10-17T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Synthesis and characterization of organic-inorganic hybrids formed between conducting polymers and crystalline antimonic acid
title Synthesis and characterization of organic-inorganic hybrids formed between conducting polymers and crystalline antimonic acid
spellingShingle Synthesis and characterization of organic-inorganic hybrids formed between conducting polymers and crystalline antimonic acid
Beleze,Fábio A.
organic-inorganic hybrid materials
conducting polymers
crystalline antimonic acid
title_short Synthesis and characterization of organic-inorganic hybrids formed between conducting polymers and crystalline antimonic acid
title_full Synthesis and characterization of organic-inorganic hybrids formed between conducting polymers and crystalline antimonic acid
title_fullStr Synthesis and characterization of organic-inorganic hybrids formed between conducting polymers and crystalline antimonic acid
title_full_unstemmed Synthesis and characterization of organic-inorganic hybrids formed between conducting polymers and crystalline antimonic acid
title_sort Synthesis and characterization of organic-inorganic hybrids formed between conducting polymers and crystalline antimonic acid
author Beleze,Fábio A.
author_facet Beleze,Fábio A.
Zarbin,Aldo J. G.
author_role author
author2 Zarbin,Aldo J. G.
author2_role author
dc.contributor.author.fl_str_mv Beleze,Fábio A.
Zarbin,Aldo J. G.
dc.subject.por.fl_str_mv organic-inorganic hybrid materials
conducting polymers
crystalline antimonic acid
topic organic-inorganic hybrid materials
conducting polymers
crystalline antimonic acid
description In this paper we report the synthesis and characterization of novel organic-inorganic hybrid materials between the crystalline antimonic acid (CAA) and two conductive polymers: polypyrrole and polyaniline. The hybrids were obtained by in situ oxidative polymerization of monomers by the Sb(V) present in the pyrochlore-like CAA structure. The materials were characterized by infrared and Raman spectroscopy, X-ray diffraction, cyclic voltammetry, CHN elemental analysis and electronic paramagnetic resonance spectroscopy. The results showed that both polymers were formed in their oxidized form, with the CAA structure acting as a counter anion.
publishDate 2001
dc.date.none.fl_str_mv 2001-08-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000400017
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000400017
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532001000400017
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.12 n.4 2001
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
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instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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