Polarographic and Spectrophotometric Study of Lead Complexes with Diethanoldithiocarbamate
Autor(a) principal: | |
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Data de Publicação: | 1998 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000600005 |
Resumo: | Experimental and theoretical aspects concerning the behaviour of lead-dietanoldithiocarbamate complexes in aqueous solutions were studied. The reaction occurs through complexation and formation of a yellow precipitate, which is soluble in ligand excess and in some polar solvents. The results from elementary and gravimetric analyses show a stoichiometric relationship of 1:2 (Pb(II): DEDC). Some ambiguous interpretations have been clarified on the application in this system of Linganes equation. Polarographic measurements were used to determine the coordination number (<FONT FACE=Symbol>@</FONT> 3.0) and overall formation constant betaMLn (<FONT FACE=Symbol>@</FONT> 4 x 10(16)), of the lead complexes with ammonium diethanoldithiocarbamate, which show a good agreement with previous potentiometric results for the same system. A kinetic-spectrophotometric study was carried out in order to establish the decomposition of these complexes in acid medium. |
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Polarographic and Spectrophotometric Study of Lead Complexes with Diethanoldithiocarbamateleaddithiocarbamate complexesspectrophotometrypolarographypotentiometryExperimental and theoretical aspects concerning the behaviour of lead-dietanoldithiocarbamate complexes in aqueous solutions were studied. The reaction occurs through complexation and formation of a yellow precipitate, which is soluble in ligand excess and in some polar solvents. The results from elementary and gravimetric analyses show a stoichiometric relationship of 1:2 (Pb(II): DEDC). Some ambiguous interpretations have been clarified on the application in this system of Linganes equation. Polarographic measurements were used to determine the coordination number (<FONT FACE=Symbol>@</FONT> 3.0) and overall formation constant betaMLn (<FONT FACE=Symbol>@</FONT> 4 x 10(16)), of the lead complexes with ammonium diethanoldithiocarbamate, which show a good agreement with previous potentiometric results for the same system. A kinetic-spectrophotometric study was carried out in order to establish the decomposition of these complexes in acid medium.Sociedade Brasileira de Química1998-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000600005Journal of the Brazilian Chemical Society v.9 n.6 1998reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50531998000600005info:eu-repo/semantics/openAccessMarques,A.L.B.Chierice,G.O.eng2002-10-25T00:00:00Zoai:scielo:S0103-50531998000600005Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2002-10-25T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Polarographic and Spectrophotometric Study of Lead Complexes with Diethanoldithiocarbamate |
title |
Polarographic and Spectrophotometric Study of Lead Complexes with Diethanoldithiocarbamate |
spellingShingle |
Polarographic and Spectrophotometric Study of Lead Complexes with Diethanoldithiocarbamate Marques,A.L.B. lead dithiocarbamate complexes spectrophotometry polarography potentiometry |
title_short |
Polarographic and Spectrophotometric Study of Lead Complexes with Diethanoldithiocarbamate |
title_full |
Polarographic and Spectrophotometric Study of Lead Complexes with Diethanoldithiocarbamate |
title_fullStr |
Polarographic and Spectrophotometric Study of Lead Complexes with Diethanoldithiocarbamate |
title_full_unstemmed |
Polarographic and Spectrophotometric Study of Lead Complexes with Diethanoldithiocarbamate |
title_sort |
Polarographic and Spectrophotometric Study of Lead Complexes with Diethanoldithiocarbamate |
author |
Marques,A.L.B. |
author_facet |
Marques,A.L.B. Chierice,G.O. |
author_role |
author |
author2 |
Chierice,G.O. |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Marques,A.L.B. Chierice,G.O. |
dc.subject.por.fl_str_mv |
lead dithiocarbamate complexes spectrophotometry polarography potentiometry |
topic |
lead dithiocarbamate complexes spectrophotometry polarography potentiometry |
description |
Experimental and theoretical aspects concerning the behaviour of lead-dietanoldithiocarbamate complexes in aqueous solutions were studied. The reaction occurs through complexation and formation of a yellow precipitate, which is soluble in ligand excess and in some polar solvents. The results from elementary and gravimetric analyses show a stoichiometric relationship of 1:2 (Pb(II): DEDC). Some ambiguous interpretations have been clarified on the application in this system of Linganes equation. Polarographic measurements were used to determine the coordination number (<FONT FACE=Symbol>@</FONT> 3.0) and overall formation constant betaMLn (<FONT FACE=Symbol>@</FONT> 4 x 10(16)), of the lead complexes with ammonium diethanoldithiocarbamate, which show a good agreement with previous potentiometric results for the same system. A kinetic-spectrophotometric study was carried out in order to establish the decomposition of these complexes in acid medium. |
publishDate |
1998 |
dc.date.none.fl_str_mv |
1998-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000600005 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000600005 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-50531998000600005 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.9 n.6 1998 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318163451445248 |