Poly(dimethylsiloxane) and Poly[vinyltrimethoxysilane-co-2-(dimethylamino)ethyl methacrylate] Based Cross-Linked Organic-Inorganic Hybrid Adsorbent for Copper(II) Removal from Aqueous Solutions
Autor(a) principal: | |
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Data de Publicação: | 2016 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016001202181 |
Resumo: | An organic-inorganic hybrid adsorbent was prepared and its application for the uptake of CuII ions from aqueous solutions was studied. The polymer network was composed of poly(dimethylsiloxane) (PDMS), vinyltrimethoxysilane (VTMS), and 2-(dimethylamino)ethyl methacrylate (DMAEMA), described as PDMS-net-P(VTMS-co-DMAEMA). The chemical groups, thermal stability and morphology of this hybrid adsorbent were characterized using techniques of attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). In adsorption studies, saturation of the active sites of the material was observed at pH 5, after 3 days, with each gram of material capable of adsorbing 0.48 mmol of copper(II). The fractionary-order and Sips models provided the best fits to the experimental data in kinetic and equilibrium studies of the adsorption process, respectively. Moreover, an acceptable reusability was found for this cross-linked organic-inorganic hybrid adsorbent after usage-regeneration cycles without significantly losing its original activity. |
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Poly(dimethylsiloxane) and Poly[vinyltrimethoxysilane-co-2-(dimethylamino)ethyl methacrylate] Based Cross-Linked Organic-Inorganic Hybrid Adsorbent for Copper(II) Removal from Aqueous Solutionspoly(dimethylsiloxane)2-(dimethylamino)ethyl methacrylatepolymer networkheavy metal ions removaladsorption-desorption cyclesAn organic-inorganic hybrid adsorbent was prepared and its application for the uptake of CuII ions from aqueous solutions was studied. The polymer network was composed of poly(dimethylsiloxane) (PDMS), vinyltrimethoxysilane (VTMS), and 2-(dimethylamino)ethyl methacrylate (DMAEMA), described as PDMS-net-P(VTMS-co-DMAEMA). The chemical groups, thermal stability and morphology of this hybrid adsorbent were characterized using techniques of attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). In adsorption studies, saturation of the active sites of the material was observed at pH 5, after 3 days, with each gram of material capable of adsorbing 0.48 mmol of copper(II). The fractionary-order and Sips models provided the best fits to the experimental data in kinetic and equilibrium studies of the adsorption process, respectively. Moreover, an acceptable reusability was found for this cross-linked organic-inorganic hybrid adsorbent after usage-regeneration cycles without significantly losing its original activity.Sociedade Brasileira de Química2016-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016001202181Journal of the Brazilian Chemical Society v.27 n.12 2016reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20160110info:eu-repo/semantics/openAccessSilva,Fábio A. B.Chagas-Silva,Fátima A.Florenzano,Fábio H.Pissetti,Fábio L.eng2016-12-01T00:00:00Zoai:scielo:S0103-50532016001202181Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2016-12-01T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Poly(dimethylsiloxane) and Poly[vinyltrimethoxysilane-co-2-(dimethylamino)ethyl methacrylate] Based Cross-Linked Organic-Inorganic Hybrid Adsorbent for Copper(II) Removal from Aqueous Solutions |
title |
Poly(dimethylsiloxane) and Poly[vinyltrimethoxysilane-co-2-(dimethylamino)ethyl methacrylate] Based Cross-Linked Organic-Inorganic Hybrid Adsorbent for Copper(II) Removal from Aqueous Solutions |
spellingShingle |
Poly(dimethylsiloxane) and Poly[vinyltrimethoxysilane-co-2-(dimethylamino)ethyl methacrylate] Based Cross-Linked Organic-Inorganic Hybrid Adsorbent for Copper(II) Removal from Aqueous Solutions Silva,Fábio A. B. poly(dimethylsiloxane) 2-(dimethylamino)ethyl methacrylate polymer network heavy metal ions removal adsorption-desorption cycles |
title_short |
Poly(dimethylsiloxane) and Poly[vinyltrimethoxysilane-co-2-(dimethylamino)ethyl methacrylate] Based Cross-Linked Organic-Inorganic Hybrid Adsorbent for Copper(II) Removal from Aqueous Solutions |
title_full |
Poly(dimethylsiloxane) and Poly[vinyltrimethoxysilane-co-2-(dimethylamino)ethyl methacrylate] Based Cross-Linked Organic-Inorganic Hybrid Adsorbent for Copper(II) Removal from Aqueous Solutions |
title_fullStr |
Poly(dimethylsiloxane) and Poly[vinyltrimethoxysilane-co-2-(dimethylamino)ethyl methacrylate] Based Cross-Linked Organic-Inorganic Hybrid Adsorbent for Copper(II) Removal from Aqueous Solutions |
title_full_unstemmed |
Poly(dimethylsiloxane) and Poly[vinyltrimethoxysilane-co-2-(dimethylamino)ethyl methacrylate] Based Cross-Linked Organic-Inorganic Hybrid Adsorbent for Copper(II) Removal from Aqueous Solutions |
title_sort |
Poly(dimethylsiloxane) and Poly[vinyltrimethoxysilane-co-2-(dimethylamino)ethyl methacrylate] Based Cross-Linked Organic-Inorganic Hybrid Adsorbent for Copper(II) Removal from Aqueous Solutions |
author |
Silva,Fábio A. B. |
author_facet |
Silva,Fábio A. B. Chagas-Silva,Fátima A. Florenzano,Fábio H. Pissetti,Fábio L. |
author_role |
author |
author2 |
Chagas-Silva,Fátima A. Florenzano,Fábio H. Pissetti,Fábio L. |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Silva,Fábio A. B. Chagas-Silva,Fátima A. Florenzano,Fábio H. Pissetti,Fábio L. |
dc.subject.por.fl_str_mv |
poly(dimethylsiloxane) 2-(dimethylamino)ethyl methacrylate polymer network heavy metal ions removal adsorption-desorption cycles |
topic |
poly(dimethylsiloxane) 2-(dimethylamino)ethyl methacrylate polymer network heavy metal ions removal adsorption-desorption cycles |
description |
An organic-inorganic hybrid adsorbent was prepared and its application for the uptake of CuII ions from aqueous solutions was studied. The polymer network was composed of poly(dimethylsiloxane) (PDMS), vinyltrimethoxysilane (VTMS), and 2-(dimethylamino)ethyl methacrylate (DMAEMA), described as PDMS-net-P(VTMS-co-DMAEMA). The chemical groups, thermal stability and morphology of this hybrid adsorbent were characterized using techniques of attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). In adsorption studies, saturation of the active sites of the material was observed at pH 5, after 3 days, with each gram of material capable of adsorbing 0.48 mmol of copper(II). The fractionary-order and Sips models provided the best fits to the experimental data in kinetic and equilibrium studies of the adsorption process, respectively. Moreover, an acceptable reusability was found for this cross-linked organic-inorganic hybrid adsorbent after usage-regeneration cycles without significantly losing its original activity. |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016001202181 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016001202181 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.5935/0103-5053.20160110 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.27 n.12 2016 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318179080470528 |