Structural Invariance of a ZnII Coordination Polymer with 5-Aminoisophthalic Acid under Different Synthetic Conditions

Detalhes bibliográficos
Autor(a) principal: Rosa,Iara M. L.
Data de Publicação: 2017
Outros Autores: Santos,Ana C. Z. dos, Giusto,Luana A. R., Pinheiro,Carlos B., Doriguetto,Antonio C.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017001102073
Resumo: A same coordination polymer [Zn(aip)(DMSO)] (aip: 5-aminoisophthalate and DMSO: dimethylsulfoxide) was synthesized using the same reactants (ZnSO4, aip and H2O/DMSO) but in different conditions, in which the stoichiometry (1:1-4:1 metal:ligand ratio), temperature (70 and 100 °C) and synthetic method (liquid-liquid diffusion, solvothermal and conventional with stirring) varied. A liquid assisted mechanochemical approach using ZnO as ZnII source instead ZnSO4, but keeping DMSO as milling liquid, also resulted in the same compound. This new coordination polymer was investigated using single-crystal X-ray diffraction technique, revealing a two-dimensional honeycomb-type network formation. The crystal structure was compared with either similar or isostructural compounds reported in the literature. Our studies show that the synthetic method and other synthetic variables do not affect the formation of [Zn(aip)(DMSO)] coordination polymers and probe the high stability (thermodynamic and kinetic) and structural invariance of this structure.
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spelling Structural Invariance of a ZnII Coordination Polymer with 5-Aminoisophthalic Acid under Different Synthetic Conditionscoordination polymerzinc aminoisophthalatenetwork stabilityX-ray diffractionA same coordination polymer [Zn(aip)(DMSO)] (aip: 5-aminoisophthalate and DMSO: dimethylsulfoxide) was synthesized using the same reactants (ZnSO4, aip and H2O/DMSO) but in different conditions, in which the stoichiometry (1:1-4:1 metal:ligand ratio), temperature (70 and 100 °C) and synthetic method (liquid-liquid diffusion, solvothermal and conventional with stirring) varied. A liquid assisted mechanochemical approach using ZnO as ZnII source instead ZnSO4, but keeping DMSO as milling liquid, also resulted in the same compound. This new coordination polymer was investigated using single-crystal X-ray diffraction technique, revealing a two-dimensional honeycomb-type network formation. The crystal structure was compared with either similar or isostructural compounds reported in the literature. Our studies show that the synthetic method and other synthetic variables do not affect the formation of [Zn(aip)(DMSO)] coordination polymers and probe the high stability (thermodynamic and kinetic) and structural invariance of this structure.Sociedade Brasileira de Química2017-11-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017001102073Journal of the Brazilian Chemical Society v.28 n.11 2017reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0103-5053.20170052info:eu-repo/semantics/openAccessRosa,Iara M. L.Santos,Ana C. Z. dosGiusto,Luana A. R.Pinheiro,Carlos B.Doriguetto,Antonio C.eng2017-10-26T00:00:00Zoai:scielo:S0103-50532017001102073Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2017-10-26T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Structural Invariance of a ZnII Coordination Polymer with 5-Aminoisophthalic Acid under Different Synthetic Conditions
title Structural Invariance of a ZnII Coordination Polymer with 5-Aminoisophthalic Acid under Different Synthetic Conditions
spellingShingle Structural Invariance of a ZnII Coordination Polymer with 5-Aminoisophthalic Acid under Different Synthetic Conditions
Rosa,Iara M. L.
coordination polymer
zinc aminoisophthalate
network stability
X-ray diffraction
title_short Structural Invariance of a ZnII Coordination Polymer with 5-Aminoisophthalic Acid under Different Synthetic Conditions
title_full Structural Invariance of a ZnII Coordination Polymer with 5-Aminoisophthalic Acid under Different Synthetic Conditions
title_fullStr Structural Invariance of a ZnII Coordination Polymer with 5-Aminoisophthalic Acid under Different Synthetic Conditions
title_full_unstemmed Structural Invariance of a ZnII Coordination Polymer with 5-Aminoisophthalic Acid under Different Synthetic Conditions
title_sort Structural Invariance of a ZnII Coordination Polymer with 5-Aminoisophthalic Acid under Different Synthetic Conditions
author Rosa,Iara M. L.
author_facet Rosa,Iara M. L.
Santos,Ana C. Z. dos
Giusto,Luana A. R.
Pinheiro,Carlos B.
Doriguetto,Antonio C.
author_role author
author2 Santos,Ana C. Z. dos
Giusto,Luana A. R.
Pinheiro,Carlos B.
Doriguetto,Antonio C.
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Rosa,Iara M. L.
Santos,Ana C. Z. dos
Giusto,Luana A. R.
Pinheiro,Carlos B.
Doriguetto,Antonio C.
dc.subject.por.fl_str_mv coordination polymer
zinc aminoisophthalate
network stability
X-ray diffraction
topic coordination polymer
zinc aminoisophthalate
network stability
X-ray diffraction
description A same coordination polymer [Zn(aip)(DMSO)] (aip: 5-aminoisophthalate and DMSO: dimethylsulfoxide) was synthesized using the same reactants (ZnSO4, aip and H2O/DMSO) but in different conditions, in which the stoichiometry (1:1-4:1 metal:ligand ratio), temperature (70 and 100 °C) and synthetic method (liquid-liquid diffusion, solvothermal and conventional with stirring) varied. A liquid assisted mechanochemical approach using ZnO as ZnII source instead ZnSO4, but keeping DMSO as milling liquid, also resulted in the same compound. This new coordination polymer was investigated using single-crystal X-ray diffraction technique, revealing a two-dimensional honeycomb-type network formation. The crystal structure was compared with either similar or isostructural compounds reported in the literature. Our studies show that the synthetic method and other synthetic variables do not affect the formation of [Zn(aip)(DMSO)] coordination polymers and probe the high stability (thermodynamic and kinetic) and structural invariance of this structure.
publishDate 2017
dc.date.none.fl_str_mv 2017-11-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
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dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017001102073
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017001102073
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.21577/0103-5053.20170052
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.28 n.11 2017
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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