Metal glycerolates as catalysts in the transesterification of refined soybean oil with methanol under reflux conditions

Detalhes bibliográficos
Autor(a) principal: Lisboa,Fábio da Silva
Data de Publicação: 2014
Outros Autores: Silva,Fabiano Rosa da, Cordeiro,Claudiney Soares, Ramos,Luiz Pereira, Wypych,Fernando
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000900007
Resumo: Divalent metal glycerolates were synthesized and investigated in the methyl transesterification of refined soybean oil. Higher conversions to monoacylesters were obtained for strontium and barium monoglycerolates and calcium diglycerolate. Calcium diglycerolate was shown to be stable up to a third reuse cycle, decomposing to an inactive mixture of CaCO3 and Ca(OH)2.
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spelling Metal glycerolates as catalysts in the transesterification of refined soybean oil with methanol under reflux conditionsmetal glycerolatesheterogeneous catalyststransesterificationmethyl estersbiodieselDivalent metal glycerolates were synthesized and investigated in the methyl transesterification of refined soybean oil. Higher conversions to monoacylesters were obtained for strontium and barium monoglycerolates and calcium diglycerolate. Calcium diglycerolate was shown to be stable up to a third reuse cycle, decomposing to an inactive mixture of CaCO3 and Ca(OH)2.Sociedade Brasileira de Química2014-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000900007Journal of the Brazilian Chemical Society v.25 n.9 2014reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20140144info:eu-repo/semantics/openAccessLisboa,Fábio da SilvaSilva,Fabiano Rosa daCordeiro,Claudiney SoaresRamos,Luiz PereiraWypych,Fernandoeng2014-09-30T00:00:00Zoai:scielo:S0103-50532014000900007Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2014-09-30T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Metal glycerolates as catalysts in the transesterification of refined soybean oil with methanol under reflux conditions
title Metal glycerolates as catalysts in the transesterification of refined soybean oil with methanol under reflux conditions
spellingShingle Metal glycerolates as catalysts in the transesterification of refined soybean oil with methanol under reflux conditions
Lisboa,Fábio da Silva
metal glycerolates
heterogeneous catalysts
transesterification
methyl esters
biodiesel
title_short Metal glycerolates as catalysts in the transesterification of refined soybean oil with methanol under reflux conditions
title_full Metal glycerolates as catalysts in the transesterification of refined soybean oil with methanol under reflux conditions
title_fullStr Metal glycerolates as catalysts in the transesterification of refined soybean oil with methanol under reflux conditions
title_full_unstemmed Metal glycerolates as catalysts in the transesterification of refined soybean oil with methanol under reflux conditions
title_sort Metal glycerolates as catalysts in the transesterification of refined soybean oil with methanol under reflux conditions
author Lisboa,Fábio da Silva
author_facet Lisboa,Fábio da Silva
Silva,Fabiano Rosa da
Cordeiro,Claudiney Soares
Ramos,Luiz Pereira
Wypych,Fernando
author_role author
author2 Silva,Fabiano Rosa da
Cordeiro,Claudiney Soares
Ramos,Luiz Pereira
Wypych,Fernando
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Lisboa,Fábio da Silva
Silva,Fabiano Rosa da
Cordeiro,Claudiney Soares
Ramos,Luiz Pereira
Wypych,Fernando
dc.subject.por.fl_str_mv metal glycerolates
heterogeneous catalysts
transesterification
methyl esters
biodiesel
topic metal glycerolates
heterogeneous catalysts
transesterification
methyl esters
biodiesel
description Divalent metal glycerolates were synthesized and investigated in the methyl transesterification of refined soybean oil. Higher conversions to monoacylesters were obtained for strontium and barium monoglycerolates and calcium diglycerolate. Calcium diglycerolate was shown to be stable up to a third reuse cycle, decomposing to an inactive mixture of CaCO3 and Ca(OH)2.
publishDate 2014
dc.date.none.fl_str_mv 2014-09-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000900007
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000900007
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.5935/0103-5053.20140144
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.25 n.9 2014
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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