Layered metal laurates as active catalysts in the methyl/ethyl esterification reactions of lauric acid

Detalhes bibliográficos
Autor(a) principal: Lisboa,Fábio da Silva
Data de Publicação: 2012
Outros Autores: Gardolinski,José Eduardo F. da, Cordeiro,Claudiney S., Wypych,Fernando
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532012000100008
Resumo: In this work we report the synthesis, characterization and investigation of the catalytic activity of layered copper(II), manganese(II), lanthanum(III) and nickel(II) laurates in the methyl and ethyl esterification reactions of lauric acid. In the methyl esterification, conversions between 80 and 90% were observed for all catalysts, while for the ethyl esterification only manganese laurate showed reasonable catalytic activity, with conversions close to 75%. Reuse of copper and lanthanum laurates in three cycles of reaction was also investigated and both catalysts preserved the structure and retained catalytic activity close to that observed for the first reaction cycle.
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spelling Layered metal laurates as active catalysts in the methyl/ethyl esterification reactions of lauric acidmetal carboxylateslayered lauratesbiodiesellauric acid esterificationIn this work we report the synthesis, characterization and investigation of the catalytic activity of layered copper(II), manganese(II), lanthanum(III) and nickel(II) laurates in the methyl and ethyl esterification reactions of lauric acid. In the methyl esterification, conversions between 80 and 90% were observed for all catalysts, while for the ethyl esterification only manganese laurate showed reasonable catalytic activity, with conversions close to 75%. Reuse of copper and lanthanum laurates in three cycles of reaction was also investigated and both catalysts preserved the structure and retained catalytic activity close to that observed for the first reaction cycle.Sociedade Brasileira de Química2012-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532012000100008Journal of the Brazilian Chemical Society v.23 n.1 2012reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532012000100008info:eu-repo/semantics/openAccessLisboa,Fábio da SilvaGardolinski,José Eduardo F. daCordeiro,Claudiney S.Wypych,Fernandoeng2012-02-02T00:00:00Zoai:scielo:S0103-50532012000100008Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2012-02-02T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Layered metal laurates as active catalysts in the methyl/ethyl esterification reactions of lauric acid
title Layered metal laurates as active catalysts in the methyl/ethyl esterification reactions of lauric acid
spellingShingle Layered metal laurates as active catalysts in the methyl/ethyl esterification reactions of lauric acid
Lisboa,Fábio da Silva
metal carboxylates
layered laurates
biodiesel
lauric acid esterification
title_short Layered metal laurates as active catalysts in the methyl/ethyl esterification reactions of lauric acid
title_full Layered metal laurates as active catalysts in the methyl/ethyl esterification reactions of lauric acid
title_fullStr Layered metal laurates as active catalysts in the methyl/ethyl esterification reactions of lauric acid
title_full_unstemmed Layered metal laurates as active catalysts in the methyl/ethyl esterification reactions of lauric acid
title_sort Layered metal laurates as active catalysts in the methyl/ethyl esterification reactions of lauric acid
author Lisboa,Fábio da Silva
author_facet Lisboa,Fábio da Silva
Gardolinski,José Eduardo F. da
Cordeiro,Claudiney S.
Wypych,Fernando
author_role author
author2 Gardolinski,José Eduardo F. da
Cordeiro,Claudiney S.
Wypych,Fernando
author2_role author
author
author
dc.contributor.author.fl_str_mv Lisboa,Fábio da Silva
Gardolinski,José Eduardo F. da
Cordeiro,Claudiney S.
Wypych,Fernando
dc.subject.por.fl_str_mv metal carboxylates
layered laurates
biodiesel
lauric acid esterification
topic metal carboxylates
layered laurates
biodiesel
lauric acid esterification
description In this work we report the synthesis, characterization and investigation of the catalytic activity of layered copper(II), manganese(II), lanthanum(III) and nickel(II) laurates in the methyl and ethyl esterification reactions of lauric acid. In the methyl esterification, conversions between 80 and 90% were observed for all catalysts, while for the ethyl esterification only manganese laurate showed reasonable catalytic activity, with conversions close to 75%. Reuse of copper and lanthanum laurates in three cycles of reaction was also investigated and both catalysts preserved the structure and retained catalytic activity close to that observed for the first reaction cycle.
publishDate 2012
dc.date.none.fl_str_mv 2012-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532012000100008
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532012000100008
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532012000100008
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.23 n.1 2012
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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