A concise enantioselective synthesis of (+)-endo-brevicomin accomplished by a tellurium/metal exchange reaction

Detalhes bibliográficos
Autor(a) principal: Ferrarini,Renan S.
Data de Publicação: 2008
Outros Autores: Princival,Jefferson L., Comasseto,João V., Dos Santos,Alcindo A.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532008000500002
Resumo: A homoenolate generated by tellurium/lithium exchange reaction was employed in a straightforward enantioselective synthesis of (+)-endo-brevicomin in 70% yield and 84.4% e.e.
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spelling A concise enantioselective synthesis of (+)-endo-brevicomin accomplished by a tellurium/metal exchange reactiontellurium/lithium exchangehomoenolateepoxide openingA homoenolate generated by tellurium/lithium exchange reaction was employed in a straightforward enantioselective synthesis of (+)-endo-brevicomin in 70% yield and 84.4% e.e.Sociedade Brasileira de Química2008-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532008000500002Journal of the Brazilian Chemical Society v.19 n.5 2008reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532008000500002info:eu-repo/semantics/openAccessFerrarini,Renan S.Princival,Jefferson L.Comasseto,João V.Dos Santos,Alcindo A.eng2008-08-05T00:00:00Zoai:scielo:S0103-50532008000500002Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2008-08-05T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv A concise enantioselective synthesis of (+)-endo-brevicomin accomplished by a tellurium/metal exchange reaction
title A concise enantioselective synthesis of (+)-endo-brevicomin accomplished by a tellurium/metal exchange reaction
spellingShingle A concise enantioselective synthesis of (+)-endo-brevicomin accomplished by a tellurium/metal exchange reaction
Ferrarini,Renan S.
tellurium/lithium exchange
homoenolate
epoxide opening
title_short A concise enantioselective synthesis of (+)-endo-brevicomin accomplished by a tellurium/metal exchange reaction
title_full A concise enantioselective synthesis of (+)-endo-brevicomin accomplished by a tellurium/metal exchange reaction
title_fullStr A concise enantioselective synthesis of (+)-endo-brevicomin accomplished by a tellurium/metal exchange reaction
title_full_unstemmed A concise enantioselective synthesis of (+)-endo-brevicomin accomplished by a tellurium/metal exchange reaction
title_sort A concise enantioselective synthesis of (+)-endo-brevicomin accomplished by a tellurium/metal exchange reaction
author Ferrarini,Renan S.
author_facet Ferrarini,Renan S.
Princival,Jefferson L.
Comasseto,João V.
Dos Santos,Alcindo A.
author_role author
author2 Princival,Jefferson L.
Comasseto,João V.
Dos Santos,Alcindo A.
author2_role author
author
author
dc.contributor.author.fl_str_mv Ferrarini,Renan S.
Princival,Jefferson L.
Comasseto,João V.
Dos Santos,Alcindo A.
dc.subject.por.fl_str_mv tellurium/lithium exchange
homoenolate
epoxide opening
topic tellurium/lithium exchange
homoenolate
epoxide opening
description A homoenolate generated by tellurium/lithium exchange reaction was employed in a straightforward enantioselective synthesis of (+)-endo-brevicomin in 70% yield and 84.4% e.e.
publishDate 2008
dc.date.none.fl_str_mv 2008-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532008000500002
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532008000500002
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532008000500002
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.19 n.5 2008
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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