Electrochemical Investigations of Li2Fe0.8-xMn0.2MxSiO4 (M = Mg2+, Zn2+) Cathodes for Lithium Ion Batteries
Autor(a) principal: | |
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Data de Publicação: | 2016 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016001102011 |
Resumo: | The Mn2+ and Mg2+ (or Zn2+) co-doped Li2Fe0.8-xMn0.2MxSiO4 (x = 0.05 and 0.1) are synthesized by a solid-state reaction route. Compared with the single doped Li2Fe0.8Mn0.2SiO4, the co-doped samples show improved cycling performance. The capacity retention can stay above 50% after 50 cycles, which is significantly higher than 30.4% for Li2Fe0.8Mn0.2SiO4. This phenomenon could be attributed to the increased structural stability caused by the incorporation of the electrochemically inactive M2+ ions. However, except for Li2Fe0.75Mn0.2Mg0.05SiO4, the other samples show decreased capacities, especially in the case of the Mn/Zn co-doping. Further tests indicate that the promotion of Li+ diffusivity may be a key reason for the improved rate and cycling performances. By contrast, the incorporation of Zn2+ impaired the cell performances such as increased internal polarization, hindered charge transfer, decreased Li+ diffusivity. In this work, the Mg2+ with smaller radius seems to be a better choice as the co-doping element at Fe sites than Zn2+. |
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Electrochemical Investigations of Li2Fe0.8-xMn0.2MxSiO4 (M = Mg2+, Zn2+) Cathodes for Lithium Ion Batterieschemically modified electrodelithium batteryapplied electrochemistrycomposite and nanocomposite materialsThe Mn2+ and Mg2+ (or Zn2+) co-doped Li2Fe0.8-xMn0.2MxSiO4 (x = 0.05 and 0.1) are synthesized by a solid-state reaction route. Compared with the single doped Li2Fe0.8Mn0.2SiO4, the co-doped samples show improved cycling performance. The capacity retention can stay above 50% after 50 cycles, which is significantly higher than 30.4% for Li2Fe0.8Mn0.2SiO4. This phenomenon could be attributed to the increased structural stability caused by the incorporation of the electrochemically inactive M2+ ions. However, except for Li2Fe0.75Mn0.2Mg0.05SiO4, the other samples show decreased capacities, especially in the case of the Mn/Zn co-doping. Further tests indicate that the promotion of Li+ diffusivity may be a key reason for the improved rate and cycling performances. By contrast, the incorporation of Zn2+ impaired the cell performances such as increased internal polarization, hindered charge transfer, decreased Li+ diffusivity. In this work, the Mg2+ with smaller radius seems to be a better choice as the co-doping element at Fe sites than Zn2+.Sociedade Brasileira de Química2016-11-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016001102011Journal of the Brazilian Chemical Society v.27 n.11 2016reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20160091info:eu-repo/semantics/openAccessLi,Shu-DanZhao,YunWang,Chen-YiGao,Kuneng2016-11-04T00:00:00Zoai:scielo:S0103-50532016001102011Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2016-11-04T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Electrochemical Investigations of Li2Fe0.8-xMn0.2MxSiO4 (M = Mg2+, Zn2+) Cathodes for Lithium Ion Batteries |
title |
Electrochemical Investigations of Li2Fe0.8-xMn0.2MxSiO4 (M = Mg2+, Zn2+) Cathodes for Lithium Ion Batteries |
spellingShingle |
Electrochemical Investigations of Li2Fe0.8-xMn0.2MxSiO4 (M = Mg2+, Zn2+) Cathodes for Lithium Ion Batteries Li,Shu-Dan chemically modified electrode lithium battery applied electrochemistry composite and nanocomposite materials |
title_short |
Electrochemical Investigations of Li2Fe0.8-xMn0.2MxSiO4 (M = Mg2+, Zn2+) Cathodes for Lithium Ion Batteries |
title_full |
Electrochemical Investigations of Li2Fe0.8-xMn0.2MxSiO4 (M = Mg2+, Zn2+) Cathodes for Lithium Ion Batteries |
title_fullStr |
Electrochemical Investigations of Li2Fe0.8-xMn0.2MxSiO4 (M = Mg2+, Zn2+) Cathodes for Lithium Ion Batteries |
title_full_unstemmed |
Electrochemical Investigations of Li2Fe0.8-xMn0.2MxSiO4 (M = Mg2+, Zn2+) Cathodes for Lithium Ion Batteries |
title_sort |
Electrochemical Investigations of Li2Fe0.8-xMn0.2MxSiO4 (M = Mg2+, Zn2+) Cathodes for Lithium Ion Batteries |
author |
Li,Shu-Dan |
author_facet |
Li,Shu-Dan Zhao,Yun Wang,Chen-Yi Gao,Kun |
author_role |
author |
author2 |
Zhao,Yun Wang,Chen-Yi Gao,Kun |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Li,Shu-Dan Zhao,Yun Wang,Chen-Yi Gao,Kun |
dc.subject.por.fl_str_mv |
chemically modified electrode lithium battery applied electrochemistry composite and nanocomposite materials |
topic |
chemically modified electrode lithium battery applied electrochemistry composite and nanocomposite materials |
description |
The Mn2+ and Mg2+ (or Zn2+) co-doped Li2Fe0.8-xMn0.2MxSiO4 (x = 0.05 and 0.1) are synthesized by a solid-state reaction route. Compared with the single doped Li2Fe0.8Mn0.2SiO4, the co-doped samples show improved cycling performance. The capacity retention can stay above 50% after 50 cycles, which is significantly higher than 30.4% for Li2Fe0.8Mn0.2SiO4. This phenomenon could be attributed to the increased structural stability caused by the incorporation of the electrochemically inactive M2+ ions. However, except for Li2Fe0.75Mn0.2Mg0.05SiO4, the other samples show decreased capacities, especially in the case of the Mn/Zn co-doping. Further tests indicate that the promotion of Li+ diffusivity may be a key reason for the improved rate and cycling performances. By contrast, the incorporation of Zn2+ impaired the cell performances such as increased internal polarization, hindered charge transfer, decreased Li+ diffusivity. In this work, the Mg2+ with smaller radius seems to be a better choice as the co-doping element at Fe sites than Zn2+. |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016-11-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016001102011 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016001102011 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.5935/0103-5053.20160091 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.27 n.11 2016 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318178787917824 |