A solvent-free synthesis of beta-enamino trihalomethyl ketones

Detalhes bibliográficos
Autor(a) principal: Martins,Marcos A. P.
Data de Publicação: 2007
Outros Autores: Peres,Rodrigo L., Fiss,Gabriela F., Dimer,Frantiescoli A., Mayer,Rodrigo, Frizzo,Clarissa P., Marzari,Mara R. B., Zanatta,Nilo, Bonacorso,Helio G.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532007000800006
Resumo: An efficient green procedure to prepare a series of twenty-six 4-amino-1,1,1-trihalo-3-alken-2-ones [CX3C(O)CH=C(R¹)NR² R³, where X = F, Cl, R¹ = H, Me, and R²/R³ = H/Ph, H/4-F-Ph, H/Bn, H/(CH2)2OH, Me/Ph, Me/Bu, Et/Et, -(CH2)4-] from the solvent-free reaction of 1,1,1-trihalo-4-alkoxy-3-alken-2-ones with primary and secondary amines at room temperature for five minutes is reported (yields of 73-99%).
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spelling A solvent-free synthesis of beta-enamino trihalomethyl ketonessolvent-freeenaminonesenonestrihalomethyl-compoundsgreen chemistryAn efficient green procedure to prepare a series of twenty-six 4-amino-1,1,1-trihalo-3-alken-2-ones [CX3C(O)CH=C(R¹)NR² R³, where X = F, Cl, R¹ = H, Me, and R²/R³ = H/Ph, H/4-F-Ph, H/Bn, H/(CH2)2OH, Me/Ph, Me/Bu, Et/Et, -(CH2)4-] from the solvent-free reaction of 1,1,1-trihalo-4-alkoxy-3-alken-2-ones with primary and secondary amines at room temperature for five minutes is reported (yields of 73-99%).Sociedade Brasileira de Química2007-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532007000800006Journal of the Brazilian Chemical Society v.18 n.8 2007reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532007000800006info:eu-repo/semantics/openAccessMartins,Marcos A. P.Peres,Rodrigo L.Fiss,Gabriela F.Dimer,Frantiescoli A.Mayer,RodrigoFrizzo,Clarissa P.Marzari,Mara R. B.Zanatta,NiloBonacorso,Helio G.eng2008-02-12T00:00:00Zoai:scielo:S0103-50532007000800006Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2008-02-12T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv A solvent-free synthesis of beta-enamino trihalomethyl ketones
title A solvent-free synthesis of beta-enamino trihalomethyl ketones
spellingShingle A solvent-free synthesis of beta-enamino trihalomethyl ketones
Martins,Marcos A. P.
solvent-free
enaminones
enones
trihalomethyl-compounds
green chemistry
title_short A solvent-free synthesis of beta-enamino trihalomethyl ketones
title_full A solvent-free synthesis of beta-enamino trihalomethyl ketones
title_fullStr A solvent-free synthesis of beta-enamino trihalomethyl ketones
title_full_unstemmed A solvent-free synthesis of beta-enamino trihalomethyl ketones
title_sort A solvent-free synthesis of beta-enamino trihalomethyl ketones
author Martins,Marcos A. P.
author_facet Martins,Marcos A. P.
Peres,Rodrigo L.
Fiss,Gabriela F.
Dimer,Frantiescoli A.
Mayer,Rodrigo
Frizzo,Clarissa P.
Marzari,Mara R. B.
Zanatta,Nilo
Bonacorso,Helio G.
author_role author
author2 Peres,Rodrigo L.
Fiss,Gabriela F.
Dimer,Frantiescoli A.
Mayer,Rodrigo
Frizzo,Clarissa P.
Marzari,Mara R. B.
Zanatta,Nilo
Bonacorso,Helio G.
author2_role author
author
author
author
author
author
author
author
dc.contributor.author.fl_str_mv Martins,Marcos A. P.
Peres,Rodrigo L.
Fiss,Gabriela F.
Dimer,Frantiescoli A.
Mayer,Rodrigo
Frizzo,Clarissa P.
Marzari,Mara R. B.
Zanatta,Nilo
Bonacorso,Helio G.
dc.subject.por.fl_str_mv solvent-free
enaminones
enones
trihalomethyl-compounds
green chemistry
topic solvent-free
enaminones
enones
trihalomethyl-compounds
green chemistry
description An efficient green procedure to prepare a series of twenty-six 4-amino-1,1,1-trihalo-3-alken-2-ones [CX3C(O)CH=C(R¹)NR² R³, where X = F, Cl, R¹ = H, Me, and R²/R³ = H/Ph, H/4-F-Ph, H/Bn, H/(CH2)2OH, Me/Ph, Me/Bu, Et/Et, -(CH2)4-] from the solvent-free reaction of 1,1,1-trihalo-4-alkoxy-3-alken-2-ones with primary and secondary amines at room temperature for five minutes is reported (yields of 73-99%).
publishDate 2007
dc.date.none.fl_str_mv 2007-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532007000800006
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532007000800006
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532007000800006
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.18 n.8 2007
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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