POSTSYNTHESIS OF TITANIUM INCORPORATED WITH AMINO-FUNCTIONALIZATION UIO-66 FOR ENHANCING CO2 UPTAKE

Detalhes bibliográficos
Autor(a) principal: Ge,Jinlong
Data de Publicação: 2019
Outros Autores: Wu,Zhong, Wang,Qiuqin, Yang,Shanshan
Tipo de documento: Artigo
Idioma: por
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019000200129
Resumo: Metal-organic frameworks (MOFs) are promising nanomaterials with unprecedented capacity to store small molecules. Titanium cooperated with NH2-UiO-66 were prepared via post synthesis modifications approach and their structures and properties were characterized by X-raydiffraction,Fourier transform infrared spectroscopy, thermogravimetric analysis, nitrogen adsorption isotherms, and scanning electron microscopy. The resultant titanium cooperated with NH2-UiO-66 showed excellent performance for CO2 adsorption via the formation of oxo-bridged hetero-Zr-Ti clusters. This result clearly demonstrates that the smaller Ti ions exchanged with the Zr ions of NH2-UiO-66 may decrease the pore sizes within the framework to be closer to the ideal pore sizes for CO2 adsorption.
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spelling POSTSYNTHESIS OF TITANIUM INCORPORATED WITH AMINO-FUNCTIONALIZATION UIO-66 FOR ENHANCING CO2 UPTAKEmetal-organic frameworksNH2-UiO-66CO2 uptake;TitaniumMetal-organic frameworks (MOFs) are promising nanomaterials with unprecedented capacity to store small molecules. Titanium cooperated with NH2-UiO-66 were prepared via post synthesis modifications approach and their structures and properties were characterized by X-raydiffraction,Fourier transform infrared spectroscopy, thermogravimetric analysis, nitrogen adsorption isotherms, and scanning electron microscopy. The resultant titanium cooperated with NH2-UiO-66 showed excellent performance for CO2 adsorption via the formation of oxo-bridged hetero-Zr-Ti clusters. This result clearly demonstrates that the smaller Ti ions exchanged with the Zr ions of NH2-UiO-66 may decrease the pore sizes within the framework to be closer to the ideal pore sizes for CO2 adsorption.Sociedade Brasileira de Química2019-02-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019000200129Química Nova v.42 n.2 2019reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0100-4042.20170312info:eu-repo/semantics/openAccessGe,JinlongWu,ZhongWang,QiuqinYang,Shanshanpor2019-03-25T00:00:00Zoai:scielo:S0100-40422019000200129Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2019-03-25T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv POSTSYNTHESIS OF TITANIUM INCORPORATED WITH AMINO-FUNCTIONALIZATION UIO-66 FOR ENHANCING CO2 UPTAKE
title POSTSYNTHESIS OF TITANIUM INCORPORATED WITH AMINO-FUNCTIONALIZATION UIO-66 FOR ENHANCING CO2 UPTAKE
spellingShingle POSTSYNTHESIS OF TITANIUM INCORPORATED WITH AMINO-FUNCTIONALIZATION UIO-66 FOR ENHANCING CO2 UPTAKE
Ge,Jinlong
metal-organic frameworks
NH2-UiO-66
CO2 uptake;Titanium
title_short POSTSYNTHESIS OF TITANIUM INCORPORATED WITH AMINO-FUNCTIONALIZATION UIO-66 FOR ENHANCING CO2 UPTAKE
title_full POSTSYNTHESIS OF TITANIUM INCORPORATED WITH AMINO-FUNCTIONALIZATION UIO-66 FOR ENHANCING CO2 UPTAKE
title_fullStr POSTSYNTHESIS OF TITANIUM INCORPORATED WITH AMINO-FUNCTIONALIZATION UIO-66 FOR ENHANCING CO2 UPTAKE
title_full_unstemmed POSTSYNTHESIS OF TITANIUM INCORPORATED WITH AMINO-FUNCTIONALIZATION UIO-66 FOR ENHANCING CO2 UPTAKE
title_sort POSTSYNTHESIS OF TITANIUM INCORPORATED WITH AMINO-FUNCTIONALIZATION UIO-66 FOR ENHANCING CO2 UPTAKE
author Ge,Jinlong
author_facet Ge,Jinlong
Wu,Zhong
Wang,Qiuqin
Yang,Shanshan
author_role author
author2 Wu,Zhong
Wang,Qiuqin
Yang,Shanshan
author2_role author
author
author
dc.contributor.author.fl_str_mv Ge,Jinlong
Wu,Zhong
Wang,Qiuqin
Yang,Shanshan
dc.subject.por.fl_str_mv metal-organic frameworks
NH2-UiO-66
CO2 uptake;Titanium
topic metal-organic frameworks
NH2-UiO-66
CO2 uptake;Titanium
description Metal-organic frameworks (MOFs) are promising nanomaterials with unprecedented capacity to store small molecules. Titanium cooperated with NH2-UiO-66 were prepared via post synthesis modifications approach and their structures and properties were characterized by X-raydiffraction,Fourier transform infrared spectroscopy, thermogravimetric analysis, nitrogen adsorption isotherms, and scanning electron microscopy. The resultant titanium cooperated with NH2-UiO-66 showed excellent performance for CO2 adsorption via the formation of oxo-bridged hetero-Zr-Ti clusters. This result clearly demonstrates that the smaller Ti ions exchanged with the Zr ions of NH2-UiO-66 may decrease the pore sizes within the framework to be closer to the ideal pore sizes for CO2 adsorption.
publishDate 2019
dc.date.none.fl_str_mv 2019-02-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019000200129
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019000200129
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv 10.21577/0100-4042.20170312
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.42 n.2 2019
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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