Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas

Detalhes bibliográficos
Autor(a) principal: Donnici,Claudio Luis
Data de Publicação: 2002
Outros Autores: Oliveira,Ione Maria Ferreira de, Temba,Eliane Sílvia Codo, Castro,Maurício Costa Rogério de
Tipo de documento: Artigo
Idioma: por
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422002000400023
Resumo: The 2,2'-bipyridine has been entitled as the most widely used ligand. Nowadays there is a large variety of known molecules comprising at least two 2,2'-bipyridine units and the number of applications in many areas such as catalysis, new materials, optoeletronics and electrochemistry have increased very much in the past decades. Nevertheless, there is no article that gives an overview of the main synthetic methods for obtaining the substituted 2,2'-bipyridines, generally non available. This article presents a synthetic discussion about the three different methods (coupling reaction, ciclo-functionalization and functionalization of the heteroaromatic rings of 2,2'-bipyridine) for preparing these heterocyclic compounds and also provides a practical and fundamental guide, for obtaining more than eighty different symmetric and unsymmetrical substituted 2,2'-bipyridines, shown in a table with the corresponding references.
id SBQ-3_1a7210dca4bed0f870584458d1efbbb9
oai_identifier_str oai:scielo:S0100-40422002000400023
network_acronym_str SBQ-3
network_name_str Química Nova (Online)
repository_id_str
spelling Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas2,2'-bipyridinessynthesiscouplingfunctionalizationThe 2,2'-bipyridine has been entitled as the most widely used ligand. Nowadays there is a large variety of known molecules comprising at least two 2,2'-bipyridine units and the number of applications in many areas such as catalysis, new materials, optoeletronics and electrochemistry have increased very much in the past decades. Nevertheless, there is no article that gives an overview of the main synthetic methods for obtaining the substituted 2,2'-bipyridines, generally non available. This article presents a synthetic discussion about the three different methods (coupling reaction, ciclo-functionalization and functionalization of the heteroaromatic rings of 2,2'-bipyridine) for preparing these heterocyclic compounds and also provides a practical and fundamental guide, for obtaining more than eighty different symmetric and unsymmetrical substituted 2,2'-bipyridines, shown in a table with the corresponding references.Sociedade Brasileira de Química2002-07-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422002000400023Química Nova v.25 n.4 2002reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422002000400023info:eu-repo/semantics/openAccessDonnici,Claudio LuisOliveira,Ione Maria Ferreira deTemba,Eliane Sílvia CodoCastro,Maurício Costa Rogério depor2002-08-26T00:00:00Zoai:scielo:S0100-40422002000400023Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2002-08-26T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas
title Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas
spellingShingle Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas
Donnici,Claudio Luis
2,2'-bipyridines
synthesis
coupling
functionalization
title_short Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas
title_full Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas
title_fullStr Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas
title_full_unstemmed Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas
title_sort Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas
author Donnici,Claudio Luis
author_facet Donnici,Claudio Luis
Oliveira,Ione Maria Ferreira de
Temba,Eliane Sílvia Codo
Castro,Maurício Costa Rogério de
author_role author
author2 Oliveira,Ione Maria Ferreira de
Temba,Eliane Sílvia Codo
Castro,Maurício Costa Rogério de
author2_role author
author
author
dc.contributor.author.fl_str_mv Donnici,Claudio Luis
Oliveira,Ione Maria Ferreira de
Temba,Eliane Sílvia Codo
Castro,Maurício Costa Rogério de
dc.subject.por.fl_str_mv 2,2'-bipyridines
synthesis
coupling
functionalization
topic 2,2'-bipyridines
synthesis
coupling
functionalization
description The 2,2'-bipyridine has been entitled as the most widely used ligand. Nowadays there is a large variety of known molecules comprising at least two 2,2'-bipyridine units and the number of applications in many areas such as catalysis, new materials, optoeletronics and electrochemistry have increased very much in the past decades. Nevertheless, there is no article that gives an overview of the main synthetic methods for obtaining the substituted 2,2'-bipyridines, generally non available. This article presents a synthetic discussion about the three different methods (coupling reaction, ciclo-functionalization and functionalization of the heteroaromatic rings of 2,2'-bipyridine) for preparing these heterocyclic compounds and also provides a practical and fundamental guide, for obtaining more than eighty different symmetric and unsymmetrical substituted 2,2'-bipyridines, shown in a table with the corresponding references.
publishDate 2002
dc.date.none.fl_str_mv 2002-07-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422002000400023
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422002000400023
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv 10.1590/S0100-40422002000400023
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.25 n.4 2002
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
_version_ 1750318102718971904