Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas
Autor(a) principal: | |
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Data de Publicação: | 2002 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Química Nova (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422002000400023 |
Resumo: | The 2,2'-bipyridine has been entitled as the most widely used ligand. Nowadays there is a large variety of known molecules comprising at least two 2,2'-bipyridine units and the number of applications in many areas such as catalysis, new materials, optoeletronics and electrochemistry have increased very much in the past decades. Nevertheless, there is no article that gives an overview of the main synthetic methods for obtaining the substituted 2,2'-bipyridines, generally non available. This article presents a synthetic discussion about the three different methods (coupling reaction, ciclo-functionalization and functionalization of the heteroaromatic rings of 2,2'-bipyridine) for preparing these heterocyclic compounds and also provides a practical and fundamental guide, for obtaining more than eighty different symmetric and unsymmetrical substituted 2,2'-bipyridines, shown in a table with the corresponding references. |
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Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas2,2'-bipyridinessynthesiscouplingfunctionalizationThe 2,2'-bipyridine has been entitled as the most widely used ligand. Nowadays there is a large variety of known molecules comprising at least two 2,2'-bipyridine units and the number of applications in many areas such as catalysis, new materials, optoeletronics and electrochemistry have increased very much in the past decades. Nevertheless, there is no article that gives an overview of the main synthetic methods for obtaining the substituted 2,2'-bipyridines, generally non available. This article presents a synthetic discussion about the three different methods (coupling reaction, ciclo-functionalization and functionalization of the heteroaromatic rings of 2,2'-bipyridine) for preparing these heterocyclic compounds and also provides a practical and fundamental guide, for obtaining more than eighty different symmetric and unsymmetrical substituted 2,2'-bipyridines, shown in a table with the corresponding references.Sociedade Brasileira de Química2002-07-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422002000400023Química Nova v.25 n.4 2002reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422002000400023info:eu-repo/semantics/openAccessDonnici,Claudio LuisOliveira,Ione Maria Ferreira deTemba,Eliane Sílvia CodoCastro,Maurício Costa Rogério depor2002-08-26T00:00:00Zoai:scielo:S0100-40422002000400023Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2002-08-26T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas |
title |
Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas |
spellingShingle |
Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas Donnici,Claudio Luis 2,2'-bipyridines synthesis coupling functionalization |
title_short |
Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas |
title_full |
Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas |
title_fullStr |
Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas |
title_full_unstemmed |
Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas |
title_sort |
Métodos sintéticos para preparação de 2,2'-bipiridinas substituídas |
author |
Donnici,Claudio Luis |
author_facet |
Donnici,Claudio Luis Oliveira,Ione Maria Ferreira de Temba,Eliane Sílvia Codo Castro,Maurício Costa Rogério de |
author_role |
author |
author2 |
Oliveira,Ione Maria Ferreira de Temba,Eliane Sílvia Codo Castro,Maurício Costa Rogério de |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Donnici,Claudio Luis Oliveira,Ione Maria Ferreira de Temba,Eliane Sílvia Codo Castro,Maurício Costa Rogério de |
dc.subject.por.fl_str_mv |
2,2'-bipyridines synthesis coupling functionalization |
topic |
2,2'-bipyridines synthesis coupling functionalization |
description |
The 2,2'-bipyridine has been entitled as the most widely used ligand. Nowadays there is a large variety of known molecules comprising at least two 2,2'-bipyridine units and the number of applications in many areas such as catalysis, new materials, optoeletronics and electrochemistry have increased very much in the past decades. Nevertheless, there is no article that gives an overview of the main synthetic methods for obtaining the substituted 2,2'-bipyridines, generally non available. This article presents a synthetic discussion about the three different methods (coupling reaction, ciclo-functionalization and functionalization of the heteroaromatic rings of 2,2'-bipyridine) for preparing these heterocyclic compounds and also provides a practical and fundamental guide, for obtaining more than eighty different symmetric and unsymmetrical substituted 2,2'-bipyridines, shown in a table with the corresponding references. |
publishDate |
2002 |
dc.date.none.fl_str_mv |
2002-07-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422002000400023 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422002000400023 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
10.1590/S0100-40422002000400023 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Química Nova v.25 n.4 2002 reponame:Química Nova (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Química Nova (Online) |
collection |
Química Nova (Online) |
repository.name.fl_str_mv |
Química Nova (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
quimicanova@sbq.org.br |
_version_ |
1750318102718971904 |