Análise química de sais de cobre fabricados entre 1877 e 1995
Autor(a) principal: | |
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Data de Publicação: | 2004 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Química Nova (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422004000400027 |
Resumo: | Samples of copper compounds covering all of the XXth century and the end of the XIXth century were submitted to classical and instrumental quantitative analysis. The amount of impurities greatly decreased with time, reaching a constant level since the 1960's. The gravimetric method was suitable for the determination of copper although other procedures also gave good or reasonable results. However, for metal contaminants, atomic absorption spectrometry was the best choice because of its lower detection limits, being able to determine several elements in the oldest samples. Ion chromatography detected several anions in copper salts manufactured before the 1950's. An increasing quality of raw materials and a better sensitivity of analytical methods led to quality improvement of copper compounds with time. |
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Análise química de sais de cobre fabricados entre 1877 e 1995copper saltschemical analysisquality controlSamples of copper compounds covering all of the XXth century and the end of the XIXth century were submitted to classical and instrumental quantitative analysis. The amount of impurities greatly decreased with time, reaching a constant level since the 1960's. The gravimetric method was suitable for the determination of copper although other procedures also gave good or reasonable results. However, for metal contaminants, atomic absorption spectrometry was the best choice because of its lower detection limits, being able to determine several elements in the oldest samples. Ion chromatography detected several anions in copper salts manufactured before the 1950's. An increasing quality of raw materials and a better sensitivity of analytical methods led to quality improvement of copper compounds with time.Sociedade Brasileira de Química2004-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422004000400027Química Nova v.27 n.4 2004reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422004000400027info:eu-repo/semantics/openAccessAfonso,Júlio CarlosAguiar,Renata de MeloGomes,Lôla Maria Bragapor2004-08-02T00:00:00Zoai:scielo:S0100-40422004000400027Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2004-08-02T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Análise química de sais de cobre fabricados entre 1877 e 1995 |
title |
Análise química de sais de cobre fabricados entre 1877 e 1995 |
spellingShingle |
Análise química de sais de cobre fabricados entre 1877 e 1995 Afonso,Júlio Carlos copper salts chemical analysis quality control |
title_short |
Análise química de sais de cobre fabricados entre 1877 e 1995 |
title_full |
Análise química de sais de cobre fabricados entre 1877 e 1995 |
title_fullStr |
Análise química de sais de cobre fabricados entre 1877 e 1995 |
title_full_unstemmed |
Análise química de sais de cobre fabricados entre 1877 e 1995 |
title_sort |
Análise química de sais de cobre fabricados entre 1877 e 1995 |
author |
Afonso,Júlio Carlos |
author_facet |
Afonso,Júlio Carlos Aguiar,Renata de Melo Gomes,Lôla Maria Braga |
author_role |
author |
author2 |
Aguiar,Renata de Melo Gomes,Lôla Maria Braga |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Afonso,Júlio Carlos Aguiar,Renata de Melo Gomes,Lôla Maria Braga |
dc.subject.por.fl_str_mv |
copper salts chemical analysis quality control |
topic |
copper salts chemical analysis quality control |
description |
Samples of copper compounds covering all of the XXth century and the end of the XIXth century were submitted to classical and instrumental quantitative analysis. The amount of impurities greatly decreased with time, reaching a constant level since the 1960's. The gravimetric method was suitable for the determination of copper although other procedures also gave good or reasonable results. However, for metal contaminants, atomic absorption spectrometry was the best choice because of its lower detection limits, being able to determine several elements in the oldest samples. Ion chromatography detected several anions in copper salts manufactured before the 1950's. An increasing quality of raw materials and a better sensitivity of analytical methods led to quality improvement of copper compounds with time. |
publishDate |
2004 |
dc.date.none.fl_str_mv |
2004-08-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422004000400027 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422004000400027 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
10.1590/S0100-40422004000400027 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Química Nova v.27 n.4 2004 reponame:Química Nova (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Química Nova (Online) |
collection |
Química Nova (Online) |
repository.name.fl_str_mv |
Química Nova (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
quimicanova@sbq.org.br |
_version_ |
1750318103886036992 |