Sesquiterpenos e outros constituintes das folhas de Pterodon pubescens Benth (Leguminosae)

Detalhes bibliográficos
Autor(a) principal: Miranda,Mayker Lazaro Dantas
Data de Publicação: 2014
Outros Autores: Garcez,Fernanda Rodrigues, Abot,Alfredo Raúl, Garcez,Walmir Silva
Tipo de documento: Artigo
Idioma: por
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422014000300014
Resumo: In addition to β-sitosterol, stigmasterol, phaeophitin A, luteolin, kaempferol, quercetin, (+)-catechin, quercetin-3-O-α-L-rhamnopyranoside, rutin, and p-hydroxy-benzoic acid, six known sesquiterpenes, namely (rel)-2β,6β-epoxy-5β-hydroxy-isodaucane, oplopanone, 1β,6α-dihydroxy-4(15)-eudesmene, caryophyllene oxide, α-cadinol, and spathulenol, were isolated from the leaves of Pterodon pubescens (Leguminosae) growing in the Cerrado of Mato Grosso do Sul, Brazil. The (rel)-2β,6β-epoxy-5β-hydroxy-isodaucane corresponds to the correct structure of homalomenol D. The sesquiterpene oplopanone, which bears a modified cadinane skeleton, is being reported for the first time in this genus. The structures of the compounds were determined on the basis of spectral data (MS, IR, and NMR-1D and 2D) and subsequent comparison with data reported in the literature.
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spelling Sesquiterpenos e outros constituintes das folhas de Pterodon pubescens Benth (Leguminosae)Pterodon pubescenssesquiterpenesisodaucane.In addition to β-sitosterol, stigmasterol, phaeophitin A, luteolin, kaempferol, quercetin, (+)-catechin, quercetin-3-O-α-L-rhamnopyranoside, rutin, and p-hydroxy-benzoic acid, six known sesquiterpenes, namely (rel)-2β,6β-epoxy-5β-hydroxy-isodaucane, oplopanone, 1β,6α-dihydroxy-4(15)-eudesmene, caryophyllene oxide, α-cadinol, and spathulenol, were isolated from the leaves of Pterodon pubescens (Leguminosae) growing in the Cerrado of Mato Grosso do Sul, Brazil. The (rel)-2β,6β-epoxy-5β-hydroxy-isodaucane corresponds to the correct structure of homalomenol D. The sesquiterpene oplopanone, which bears a modified cadinane skeleton, is being reported for the first time in this genus. The structures of the compounds were determined on the basis of spectral data (MS, IR, and NMR-1D and 2D) and subsequent comparison with data reported in the literature.Sociedade Brasileira de Química2014-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422014000300014Química Nova v.37 n.3 2014reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0100-4042.20140065info:eu-repo/semantics/openAccessMiranda,Mayker Lazaro DantasGarcez,Fernanda RodriguesAbot,Alfredo RaúlGarcez,Walmir Silvapor2014-05-05T00:00:00Zoai:scielo:S0100-40422014000300014Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2014-05-05T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Sesquiterpenos e outros constituintes das folhas de Pterodon pubescens Benth (Leguminosae)
title Sesquiterpenos e outros constituintes das folhas de Pterodon pubescens Benth (Leguminosae)
spellingShingle Sesquiterpenos e outros constituintes das folhas de Pterodon pubescens Benth (Leguminosae)
Miranda,Mayker Lazaro Dantas
Pterodon pubescens
sesquiterpenes
isodaucane.
title_short Sesquiterpenos e outros constituintes das folhas de Pterodon pubescens Benth (Leguminosae)
title_full Sesquiterpenos e outros constituintes das folhas de Pterodon pubescens Benth (Leguminosae)
title_fullStr Sesquiterpenos e outros constituintes das folhas de Pterodon pubescens Benth (Leguminosae)
title_full_unstemmed Sesquiterpenos e outros constituintes das folhas de Pterodon pubescens Benth (Leguminosae)
title_sort Sesquiterpenos e outros constituintes das folhas de Pterodon pubescens Benth (Leguminosae)
author Miranda,Mayker Lazaro Dantas
author_facet Miranda,Mayker Lazaro Dantas
Garcez,Fernanda Rodrigues
Abot,Alfredo Raúl
Garcez,Walmir Silva
author_role author
author2 Garcez,Fernanda Rodrigues
Abot,Alfredo Raúl
Garcez,Walmir Silva
author2_role author
author
author
dc.contributor.author.fl_str_mv Miranda,Mayker Lazaro Dantas
Garcez,Fernanda Rodrigues
Abot,Alfredo Raúl
Garcez,Walmir Silva
dc.subject.por.fl_str_mv Pterodon pubescens
sesquiterpenes
isodaucane.
topic Pterodon pubescens
sesquiterpenes
isodaucane.
description In addition to β-sitosterol, stigmasterol, phaeophitin A, luteolin, kaempferol, quercetin, (+)-catechin, quercetin-3-O-α-L-rhamnopyranoside, rutin, and p-hydroxy-benzoic acid, six known sesquiterpenes, namely (rel)-2β,6β-epoxy-5β-hydroxy-isodaucane, oplopanone, 1β,6α-dihydroxy-4(15)-eudesmene, caryophyllene oxide, α-cadinol, and spathulenol, were isolated from the leaves of Pterodon pubescens (Leguminosae) growing in the Cerrado of Mato Grosso do Sul, Brazil. The (rel)-2β,6β-epoxy-5β-hydroxy-isodaucane corresponds to the correct structure of homalomenol D. The sesquiterpene oplopanone, which bears a modified cadinane skeleton, is being reported for the first time in this genus. The structures of the compounds were determined on the basis of spectral data (MS, IR, and NMR-1D and 2D) and subsequent comparison with data reported in the literature.
publishDate 2014
dc.date.none.fl_str_mv 2014-06-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422014000300014
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422014000300014
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv 10.5935/0100-4042.20140065
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.37 n.3 2014
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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