Aspectos estruturais de algumas neolignanas hidrobenzofurânicas

Detalhes bibliográficos
Autor(a) principal: Yoshida,Massayoshi
Data de Publicação: 2012
Tipo de documento: Artigo
Idioma: por
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012001100034
Resumo: The neolignans are defined as dimers of allylphenol and propenylphenol between itself or crossed, whose bond does not occur by the 8-8' carbons like lignans. This review centered on stereochemical aspects of the hydrobenzofuran type, a widespread skeleton among neolignans. The chemical structures established based on spectrometric data are registered in the literature. The absolute configurations reported previously were determined by chiroptical techniques. Some chemical transformations with neolignans, performed in previous studies, afforded products which are accumulated in other vegetal species and contributed to assign the unknown stereochemistry of these natural compounds. Possible biosynthetic pathways are also proposed.
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spelling Aspectos estruturais de algumas neolignanas hidrobenzofurânicasneolignanshydrobenzofuran skeletonLauraceaeThe neolignans are defined as dimers of allylphenol and propenylphenol between itself or crossed, whose bond does not occur by the 8-8' carbons like lignans. This review centered on stereochemical aspects of the hydrobenzofuran type, a widespread skeleton among neolignans. The chemical structures established based on spectrometric data are registered in the literature. The absolute configurations reported previously were determined by chiroptical techniques. Some chemical transformations with neolignans, performed in previous studies, afforded products which are accumulated in other vegetal species and contributed to assign the unknown stereochemistry of these natural compounds. Possible biosynthetic pathways are also proposed.Sociedade Brasileira de Química2012-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012001100034Química Nova v.35 n.11 2012reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422012001100034info:eu-repo/semantics/openAccessYoshida,Massayoshipor2012-12-03T00:00:00Zoai:scielo:S0100-40422012001100034Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2012-12-03T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Aspectos estruturais de algumas neolignanas hidrobenzofurânicas
title Aspectos estruturais de algumas neolignanas hidrobenzofurânicas
spellingShingle Aspectos estruturais de algumas neolignanas hidrobenzofurânicas
Yoshida,Massayoshi
neolignans
hydrobenzofuran skeleton
Lauraceae
title_short Aspectos estruturais de algumas neolignanas hidrobenzofurânicas
title_full Aspectos estruturais de algumas neolignanas hidrobenzofurânicas
title_fullStr Aspectos estruturais de algumas neolignanas hidrobenzofurânicas
title_full_unstemmed Aspectos estruturais de algumas neolignanas hidrobenzofurânicas
title_sort Aspectos estruturais de algumas neolignanas hidrobenzofurânicas
author Yoshida,Massayoshi
author_facet Yoshida,Massayoshi
author_role author
dc.contributor.author.fl_str_mv Yoshida,Massayoshi
dc.subject.por.fl_str_mv neolignans
hydrobenzofuran skeleton
Lauraceae
topic neolignans
hydrobenzofuran skeleton
Lauraceae
description The neolignans are defined as dimers of allylphenol and propenylphenol between itself or crossed, whose bond does not occur by the 8-8' carbons like lignans. This review centered on stereochemical aspects of the hydrobenzofuran type, a widespread skeleton among neolignans. The chemical structures established based on spectrometric data are registered in the literature. The absolute configurations reported previously were determined by chiroptical techniques. Some chemical transformations with neolignans, performed in previous studies, afforded products which are accumulated in other vegetal species and contributed to assign the unknown stereochemistry of these natural compounds. Possible biosynthetic pathways are also proposed.
publishDate 2012
dc.date.none.fl_str_mv 2012-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
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status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012001100034
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012001100034
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv 10.1590/S0100-40422012001100034
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.35 n.11 2012
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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