A RENEWABLE CATALYST FOR A RENEWABLE CHEMICAL: GRAM-SCALE CONVERSION OF FURFURAL TO FURFURYL ALCOHOL BY THE CARROT (Daucus carota)
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Química Nova (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422020000100032 |
Resumo: | The bioconversion of furfural to furfuryl alcohol using only carrot bits in water at room temperature and ambient pressure is presented. This reaction led to the bioreduction of furfural with 99% conversion and 99% selectivity to an alcohol. This simple and “fully” green process may represent an alternative to classic hydrogenation processes. Also, without work-up procedure, we demonstrate the aqueous solution can be submitted to microwave irradiation to obtain 4-hydroxy-2-cyclopentenone. |
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A RENEWABLE CATALYST FOR A RENEWABLE CHEMICAL: GRAM-SCALE CONVERSION OF FURFURAL TO FURFURYL ALCOHOL BY THE CARROT (Daucus carota)furansbiomassbiocatalysis and sustainable processThe bioconversion of furfural to furfuryl alcohol using only carrot bits in water at room temperature and ambient pressure is presented. This reaction led to the bioreduction of furfural with 99% conversion and 99% selectivity to an alcohol. This simple and “fully” green process may represent an alternative to classic hydrogenation processes. Also, without work-up procedure, we demonstrate the aqueous solution can be submitted to microwave irradiation to obtain 4-hydroxy-2-cyclopentenone.Sociedade Brasileira de Química2020-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422020000100032Química Nova v.43 n.1 2020reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0100-4042.20170451info:eu-repo/semantics/openAccessOmori,Alvaro T.Capeletto,Marina G.Yamamoto,Daniela Y.Oliveira Filho,Ronaldo E. deeng2020-06-05T00:00:00Zoai:scielo:S0100-40422020000100032Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2020-06-05T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
A RENEWABLE CATALYST FOR A RENEWABLE CHEMICAL: GRAM-SCALE CONVERSION OF FURFURAL TO FURFURYL ALCOHOL BY THE CARROT (Daucus carota) |
title |
A RENEWABLE CATALYST FOR A RENEWABLE CHEMICAL: GRAM-SCALE CONVERSION OF FURFURAL TO FURFURYL ALCOHOL BY THE CARROT (Daucus carota) |
spellingShingle |
A RENEWABLE CATALYST FOR A RENEWABLE CHEMICAL: GRAM-SCALE CONVERSION OF FURFURAL TO FURFURYL ALCOHOL BY THE CARROT (Daucus carota) Omori,Alvaro T. furans biomass biocatalysis and sustainable process |
title_short |
A RENEWABLE CATALYST FOR A RENEWABLE CHEMICAL: GRAM-SCALE CONVERSION OF FURFURAL TO FURFURYL ALCOHOL BY THE CARROT (Daucus carota) |
title_full |
A RENEWABLE CATALYST FOR A RENEWABLE CHEMICAL: GRAM-SCALE CONVERSION OF FURFURAL TO FURFURYL ALCOHOL BY THE CARROT (Daucus carota) |
title_fullStr |
A RENEWABLE CATALYST FOR A RENEWABLE CHEMICAL: GRAM-SCALE CONVERSION OF FURFURAL TO FURFURYL ALCOHOL BY THE CARROT (Daucus carota) |
title_full_unstemmed |
A RENEWABLE CATALYST FOR A RENEWABLE CHEMICAL: GRAM-SCALE CONVERSION OF FURFURAL TO FURFURYL ALCOHOL BY THE CARROT (Daucus carota) |
title_sort |
A RENEWABLE CATALYST FOR A RENEWABLE CHEMICAL: GRAM-SCALE CONVERSION OF FURFURAL TO FURFURYL ALCOHOL BY THE CARROT (Daucus carota) |
author |
Omori,Alvaro T. |
author_facet |
Omori,Alvaro T. Capeletto,Marina G. Yamamoto,Daniela Y. Oliveira Filho,Ronaldo E. de |
author_role |
author |
author2 |
Capeletto,Marina G. Yamamoto,Daniela Y. Oliveira Filho,Ronaldo E. de |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Omori,Alvaro T. Capeletto,Marina G. Yamamoto,Daniela Y. Oliveira Filho,Ronaldo E. de |
dc.subject.por.fl_str_mv |
furans biomass biocatalysis and sustainable process |
topic |
furans biomass biocatalysis and sustainable process |
description |
The bioconversion of furfural to furfuryl alcohol using only carrot bits in water at room temperature and ambient pressure is presented. This reaction led to the bioreduction of furfural with 99% conversion and 99% selectivity to an alcohol. This simple and “fully” green process may represent an alternative to classic hydrogenation processes. Also, without work-up procedure, we demonstrate the aqueous solution can be submitted to microwave irradiation to obtain 4-hydroxy-2-cyclopentenone. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422020000100032 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422020000100032 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.21577/0100-4042.20170451 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Química Nova v.43 n.1 2020 reponame:Química Nova (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Química Nova (Online) |
collection |
Química Nova (Online) |
repository.name.fl_str_mv |
Química Nova (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
quimicanova@sbq.org.br |
_version_ |
1750318120087584768 |