Aromaticidade: evolução histórica do conceito e critérios quantitativos

Detalhes bibliográficos
Autor(a) principal: Caramori,Giovanni Finoto
Data de Publicação: 2009
Outros Autores: Oliveira,Kleber Thiago de
Tipo de documento: Artigo
Idioma: por
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000700034
Resumo: In this paper the evolution of the concept of aromaticity is discussed. It considers not only historical aspects of the aromaticity concept but also the different criteria (theoretical and experimental) that have appeared to explain the properties of the aromatic compounds. The topics range from the isolation of benzene by Faraday (1825) until the modern criteria based on geometries, magnetic properties, resonance energy (RE), aromatic stabilization energy (ASE), topological analyses, and others. A chronological separation of issues concerning aromaticity was made, splitting the definitions before and after the appearance of the quantum chemistry. This work reviews the concept of aromaticity.
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spelling Aromaticidade: evolução histórica do conceito e critérios quantitativosaromaticity concepthistoric evolutionquantitative indexesIn this paper the evolution of the concept of aromaticity is discussed. It considers not only historical aspects of the aromaticity concept but also the different criteria (theoretical and experimental) that have appeared to explain the properties of the aromatic compounds. The topics range from the isolation of benzene by Faraday (1825) until the modern criteria based on geometries, magnetic properties, resonance energy (RE), aromatic stabilization energy (ASE), topological analyses, and others. A chronological separation of issues concerning aromaticity was made, splitting the definitions before and after the appearance of the quantum chemistry. This work reviews the concept of aromaticity.Sociedade Brasileira de Química2009-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000700034Química Nova v.32 n.7 2009reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422009000700034info:eu-repo/semantics/openAccessCaramori,Giovanni FinotoOliveira,Kleber Thiago depor2009-10-22T00:00:00Zoai:scielo:S0100-40422009000700034Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2009-10-22T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Aromaticidade: evolução histórica do conceito e critérios quantitativos
title Aromaticidade: evolução histórica do conceito e critérios quantitativos
spellingShingle Aromaticidade: evolução histórica do conceito e critérios quantitativos
Caramori,Giovanni Finoto
aromaticity concept
historic evolution
quantitative indexes
title_short Aromaticidade: evolução histórica do conceito e critérios quantitativos
title_full Aromaticidade: evolução histórica do conceito e critérios quantitativos
title_fullStr Aromaticidade: evolução histórica do conceito e critérios quantitativos
title_full_unstemmed Aromaticidade: evolução histórica do conceito e critérios quantitativos
title_sort Aromaticidade: evolução histórica do conceito e critérios quantitativos
author Caramori,Giovanni Finoto
author_facet Caramori,Giovanni Finoto
Oliveira,Kleber Thiago de
author_role author
author2 Oliveira,Kleber Thiago de
author2_role author
dc.contributor.author.fl_str_mv Caramori,Giovanni Finoto
Oliveira,Kleber Thiago de
dc.subject.por.fl_str_mv aromaticity concept
historic evolution
quantitative indexes
topic aromaticity concept
historic evolution
quantitative indexes
description In this paper the evolution of the concept of aromaticity is discussed. It considers not only historical aspects of the aromaticity concept but also the different criteria (theoretical and experimental) that have appeared to explain the properties of the aromatic compounds. The topics range from the isolation of benzene by Faraday (1825) until the modern criteria based on geometries, magnetic properties, resonance energy (RE), aromatic stabilization energy (ASE), topological analyses, and others. A chronological separation of issues concerning aromaticity was made, splitting the definitions before and after the appearance of the quantum chemistry. This work reviews the concept of aromaticity.
publishDate 2009
dc.date.none.fl_str_mv 2009-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000700034
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000700034
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv 10.1590/S0100-40422009000700034
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.32 n.7 2009
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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