Adsorção de arsênio(V) pela quitosana ferro - III reticulada
Autor(a) principal: | |
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Data de Publicação: | 2008 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Química Nova (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000600006 |
Resumo: | The removal of As(V) by a crosslinked iron(III)-chitosan adsorbent was evaluated under various conditions. The adsorption capacity of CH-FeCL was around 54 mg/g of As(V). The kinetics of adsorption obeys a pseudo-first-order model with rate constants equal to 0.022, 0.028, and 0.033 min-1 at 15, 25 and 35 ºC respectively. Adsorption data were well described by the Langmuir model, although they could be modeled also by the Langmuir-Freundlich equation. The maximum adsorption capacity, calculated with the Langmuir model, was 127 mg g-1 of As(V). The inhibition by competing anions is dependant on their kind and valence. |
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Adsorção de arsênio(V) pela quitosana ferro - III reticuladacrosslinked iron(III)-chitosanarsenateadsorptionThe removal of As(V) by a crosslinked iron(III)-chitosan adsorbent was evaluated under various conditions. The adsorption capacity of CH-FeCL was around 54 mg/g of As(V). The kinetics of adsorption obeys a pseudo-first-order model with rate constants equal to 0.022, 0.028, and 0.033 min-1 at 15, 25 and 35 ºC respectively. Adsorption data were well described by the Langmuir model, although they could be modeled also by the Langmuir-Freundlich equation. The maximum adsorption capacity, calculated with the Langmuir model, was 127 mg g-1 of As(V). The inhibition by competing anions is dependant on their kind and valence.Sociedade Brasileira de Química2008-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000600006Química Nova v.31 n.6 2008reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422008000600006info:eu-repo/semantics/openAccessFagundes,TathyaneBachmann,Amanda Wolff LedraTomaz,Heloísa Sonálio OverrathRodrigues,Clóvis Antoniopor2008-10-10T00:00:00Zoai:scielo:S0100-40422008000600006Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2008-10-10T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Adsorção de arsênio(V) pela quitosana ferro - III reticulada |
title |
Adsorção de arsênio(V) pela quitosana ferro - III reticulada |
spellingShingle |
Adsorção de arsênio(V) pela quitosana ferro - III reticulada Fagundes,Tathyane crosslinked iron(III)-chitosan arsenate adsorption |
title_short |
Adsorção de arsênio(V) pela quitosana ferro - III reticulada |
title_full |
Adsorção de arsênio(V) pela quitosana ferro - III reticulada |
title_fullStr |
Adsorção de arsênio(V) pela quitosana ferro - III reticulada |
title_full_unstemmed |
Adsorção de arsênio(V) pela quitosana ferro - III reticulada |
title_sort |
Adsorção de arsênio(V) pela quitosana ferro - III reticulada |
author |
Fagundes,Tathyane |
author_facet |
Fagundes,Tathyane Bachmann,Amanda Wolff Ledra Tomaz,Heloísa Sonálio Overrath Rodrigues,Clóvis Antonio |
author_role |
author |
author2 |
Bachmann,Amanda Wolff Ledra Tomaz,Heloísa Sonálio Overrath Rodrigues,Clóvis Antonio |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Fagundes,Tathyane Bachmann,Amanda Wolff Ledra Tomaz,Heloísa Sonálio Overrath Rodrigues,Clóvis Antonio |
dc.subject.por.fl_str_mv |
crosslinked iron(III)-chitosan arsenate adsorption |
topic |
crosslinked iron(III)-chitosan arsenate adsorption |
description |
The removal of As(V) by a crosslinked iron(III)-chitosan adsorbent was evaluated under various conditions. The adsorption capacity of CH-FeCL was around 54 mg/g of As(V). The kinetics of adsorption obeys a pseudo-first-order model with rate constants equal to 0.022, 0.028, and 0.033 min-1 at 15, 25 and 35 ºC respectively. Adsorption data were well described by the Langmuir model, although they could be modeled also by the Langmuir-Freundlich equation. The maximum adsorption capacity, calculated with the Langmuir model, was 127 mg g-1 of As(V). The inhibition by competing anions is dependant on their kind and valence. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000600006 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000600006 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
10.1590/S0100-40422008000600006 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Química Nova v.31 n.6 2008 reponame:Química Nova (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Química Nova (Online) |
collection |
Química Nova (Online) |
repository.name.fl_str_mv |
Química Nova (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
quimicanova@sbq.org.br |
_version_ |
1750318107953463296 |