A NEW HOMOGENEOUS ELECTROCATALYST FOR ELECTROCHEMICAL CARBONYLATION OF METHANOL TO DIMETHYL CARBONATE
Autor(a) principal: | |
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Data de Publicação: | 2015 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Química Nova (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422015000300298 |
Resumo: | Electrosynthesis of dimethyl carbonate (DMC) from methanol and carbon monoxide using an Cu(phen)Cl2 catalyst was achieved at room temperature and atmospheric pressure. The catalytic activity of the ligand 1,10-phenanthroline (phen) and the catalytic system were analyzed. The IR characterization results for the complex catalyst showed that copper ions were coordinated by nitrogen atoms of phen. In addition, the effects of the influencing factors, such as reaction time (t), reaction temperature (T) and the surface area of the working electrode (SWE) were studied. |
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Química Nova (Online) |
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A NEW HOMOGENEOUS ELECTROCATALYST FOR ELECTROCHEMICAL CARBONYLATION OF METHANOL TO DIMETHYL CARBONATEelectro-synthesisDMChomogeneous catalystElectrosynthesis of dimethyl carbonate (DMC) from methanol and carbon monoxide using an Cu(phen)Cl2 catalyst was achieved at room temperature and atmospheric pressure. The catalytic activity of the ligand 1,10-phenanthroline (phen) and the catalytic system were analyzed. The IR characterization results for the complex catalyst showed that copper ions were coordinated by nitrogen atoms of phen. In addition, the effects of the influencing factors, such as reaction time (t), reaction temperature (T) and the surface area of the working electrode (SWE) were studied.Sociedade Brasileira de Química2015-03-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422015000300298Química Nova v.38 n.3 2015reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0100-4042.20150003info:eu-repo/semantics/openAccessWang,XiaoyanJia,GanYu,YutingGao,YanfangZhang,WenWang,HongCao,ZhenzhuLiu,Jinrongeng2015-05-12T00:00:00Zoai:scielo:S0100-40422015000300298Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2015-05-12T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
A NEW HOMOGENEOUS ELECTROCATALYST FOR ELECTROCHEMICAL CARBONYLATION OF METHANOL TO DIMETHYL CARBONATE |
title |
A NEW HOMOGENEOUS ELECTROCATALYST FOR ELECTROCHEMICAL CARBONYLATION OF METHANOL TO DIMETHYL CARBONATE |
spellingShingle |
A NEW HOMOGENEOUS ELECTROCATALYST FOR ELECTROCHEMICAL CARBONYLATION OF METHANOL TO DIMETHYL CARBONATE Wang,Xiaoyan electro-synthesis DMC homogeneous catalyst |
title_short |
A NEW HOMOGENEOUS ELECTROCATALYST FOR ELECTROCHEMICAL CARBONYLATION OF METHANOL TO DIMETHYL CARBONATE |
title_full |
A NEW HOMOGENEOUS ELECTROCATALYST FOR ELECTROCHEMICAL CARBONYLATION OF METHANOL TO DIMETHYL CARBONATE |
title_fullStr |
A NEW HOMOGENEOUS ELECTROCATALYST FOR ELECTROCHEMICAL CARBONYLATION OF METHANOL TO DIMETHYL CARBONATE |
title_full_unstemmed |
A NEW HOMOGENEOUS ELECTROCATALYST FOR ELECTROCHEMICAL CARBONYLATION OF METHANOL TO DIMETHYL CARBONATE |
title_sort |
A NEW HOMOGENEOUS ELECTROCATALYST FOR ELECTROCHEMICAL CARBONYLATION OF METHANOL TO DIMETHYL CARBONATE |
author |
Wang,Xiaoyan |
author_facet |
Wang,Xiaoyan Jia,Gan Yu,Yuting Gao,Yanfang Zhang,Wen Wang,Hong Cao,Zhenzhu Liu,Jinrong |
author_role |
author |
author2 |
Jia,Gan Yu,Yuting Gao,Yanfang Zhang,Wen Wang,Hong Cao,Zhenzhu Liu,Jinrong |
author2_role |
author author author author author author author |
dc.contributor.author.fl_str_mv |
Wang,Xiaoyan Jia,Gan Yu,Yuting Gao,Yanfang Zhang,Wen Wang,Hong Cao,Zhenzhu Liu,Jinrong |
dc.subject.por.fl_str_mv |
electro-synthesis DMC homogeneous catalyst |
topic |
electro-synthesis DMC homogeneous catalyst |
description |
Electrosynthesis of dimethyl carbonate (DMC) from methanol and carbon monoxide using an Cu(phen)Cl2 catalyst was achieved at room temperature and atmospheric pressure. The catalytic activity of the ligand 1,10-phenanthroline (phen) and the catalytic system were analyzed. The IR characterization results for the complex catalyst showed that copper ions were coordinated by nitrogen atoms of phen. In addition, the effects of the influencing factors, such as reaction time (t), reaction temperature (T) and the surface area of the working electrode (SWE) were studied. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-03-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422015000300298 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422015000300298 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.5935/0100-4042.20150003 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Química Nova v.38 n.3 2015 reponame:Química Nova (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Química Nova (Online) |
collection |
Química Nova (Online) |
repository.name.fl_str_mv |
Química Nova (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
quimicanova@sbq.org.br |
_version_ |
1750318116661886976 |