Activity and sulfur resistance of Rh(I) and Pd(II) complexes

Detalhes bibliográficos
Autor(a) principal: Rivas,Ivana
Data de Publicação: 2011
Outros Autores: Badano,Juan, Lederhos,Cecilia, Liprandi,Domingo, Cagnola,Edgardo, Vera,Carlos, Quiroga,Mónica
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422011000100017
Resumo: Two complexes of Rh(I) and Pd(II) with chloride and tridecylamine ligands were obtained and characterized by Elementary Analysis and by XPS and FTIR spectroscopies. Complexes anchored on γ-Al2O3 were tested in the styrene semi-hydrogenation reaction carried out in the absence or presence of a sulfur poison. Although both low loaded catalysts were highly selective, the Pd(II) complex was three times more active than the Rh(I) complex. The rhodium complex was more sulfur resistant but less active than the palladium complex. Differences in conversion and sulfur resistance between both complexes could be related to electronic and/or geometric effects.
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spelling Activity and sulfur resistance of Rh(I) and Pd(II) complexesPd and Rh complexesPYGAS selective hydrogenationsulfur poisoningTwo complexes of Rh(I) and Pd(II) with chloride and tridecylamine ligands were obtained and characterized by Elementary Analysis and by XPS and FTIR spectroscopies. Complexes anchored on γ-Al2O3 were tested in the styrene semi-hydrogenation reaction carried out in the absence or presence of a sulfur poison. Although both low loaded catalysts were highly selective, the Pd(II) complex was three times more active than the Rh(I) complex. The rhodium complex was more sulfur resistant but less active than the palladium complex. Differences in conversion and sulfur resistance between both complexes could be related to electronic and/or geometric effects.Sociedade Brasileira de Química2011-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422011000100017Química Nova v.34 n.1 2011reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422011000100017info:eu-repo/semantics/openAccessRivas,IvanaBadano,JuanLederhos,CeciliaLiprandi,DomingoCagnola,EdgardoVera,CarlosQuiroga,Mónicaeng2011-02-10T00:00:00Zoai:scielo:S0100-40422011000100017Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2011-02-10T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Activity and sulfur resistance of Rh(I) and Pd(II) complexes
title Activity and sulfur resistance of Rh(I) and Pd(II) complexes
spellingShingle Activity and sulfur resistance of Rh(I) and Pd(II) complexes
Rivas,Ivana
Pd and Rh complexes
PYGAS selective hydrogenation
sulfur poisoning
title_short Activity and sulfur resistance of Rh(I) and Pd(II) complexes
title_full Activity and sulfur resistance of Rh(I) and Pd(II) complexes
title_fullStr Activity and sulfur resistance of Rh(I) and Pd(II) complexes
title_full_unstemmed Activity and sulfur resistance of Rh(I) and Pd(II) complexes
title_sort Activity and sulfur resistance of Rh(I) and Pd(II) complexes
author Rivas,Ivana
author_facet Rivas,Ivana
Badano,Juan
Lederhos,Cecilia
Liprandi,Domingo
Cagnola,Edgardo
Vera,Carlos
Quiroga,Mónica
author_role author
author2 Badano,Juan
Lederhos,Cecilia
Liprandi,Domingo
Cagnola,Edgardo
Vera,Carlos
Quiroga,Mónica
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Rivas,Ivana
Badano,Juan
Lederhos,Cecilia
Liprandi,Domingo
Cagnola,Edgardo
Vera,Carlos
Quiroga,Mónica
dc.subject.por.fl_str_mv Pd and Rh complexes
PYGAS selective hydrogenation
sulfur poisoning
topic Pd and Rh complexes
PYGAS selective hydrogenation
sulfur poisoning
description Two complexes of Rh(I) and Pd(II) with chloride and tridecylamine ligands were obtained and characterized by Elementary Analysis and by XPS and FTIR spectroscopies. Complexes anchored on γ-Al2O3 were tested in the styrene semi-hydrogenation reaction carried out in the absence or presence of a sulfur poison. Although both low loaded catalysts were highly selective, the Pd(II) complex was three times more active than the Rh(I) complex. The rhodium complex was more sulfur resistant but less active than the palladium complex. Differences in conversion and sulfur resistance between both complexes could be related to electronic and/or geometric effects.
publishDate 2011
dc.date.none.fl_str_mv 2011-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422011000100017
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422011000100017
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0100-40422011000100017
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.34 n.1 2011
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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