Stereoselective sodium borohydride reductions of cyclopentanones: influence of ceric chloride on the stereochemistry of reaction

Detalhes bibliográficos
Autor(a) principal: Constantino,Mauricio Gomes
Data de Publicação: 1998
Outros Autores: Matias,Luiz Gonzaga de Oliveira, Silva,Gil Valdo José da, Barbieri,Emerson, Gambardella,Maria Teresa do Prado
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421998000600009
Resumo: In this paper we describe the reduction by NaBH4 of some cyclopentanones containing an oxygenated function at the side chain position beta to the carbonyl group, both in the presence and in the absence of CeCl3. Some suggestions for the rationalization of the results are discussed, considering the stereochemical course of the reactions.
id SBQ-3_a5fdb0a84a8eea5c5bb78c65834fc65f
oai_identifier_str oai:scielo:S0100-40421998000600009
network_acronym_str SBQ-3
network_name_str Química Nova (Online)
repository_id_str
spelling Stereoselective sodium borohydride reductions of cyclopentanones: influence of ceric chloride on the stereochemistry of reactioncyclopentanonesstereoselective reductionsodium borohydrideceric chlorideIn this paper we describe the reduction by NaBH4 of some cyclopentanones containing an oxygenated function at the side chain position beta to the carbonyl group, both in the presence and in the absence of CeCl3. Some suggestions for the rationalization of the results are discussed, considering the stereochemical course of the reactions.Sociedade Brasileira de Química1998-11-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421998000600009Química Nova v.21 n.6 1998reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40421998000600009info:eu-repo/semantics/openAccessConstantino,Mauricio GomesMatias,Luiz Gonzaga de OliveiraSilva,Gil Valdo José daBarbieri,EmersonGambardella,Maria Teresa do Pradoeng2001-04-10T00:00:00Zoai:scielo:S0100-40421998000600009Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2001-04-10T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Stereoselective sodium borohydride reductions of cyclopentanones: influence of ceric chloride on the stereochemistry of reaction
title Stereoselective sodium borohydride reductions of cyclopentanones: influence of ceric chloride on the stereochemistry of reaction
spellingShingle Stereoselective sodium borohydride reductions of cyclopentanones: influence of ceric chloride on the stereochemistry of reaction
Constantino,Mauricio Gomes
cyclopentanones
stereoselective reduction
sodium borohydride
ceric chloride
title_short Stereoselective sodium borohydride reductions of cyclopentanones: influence of ceric chloride on the stereochemistry of reaction
title_full Stereoselective sodium borohydride reductions of cyclopentanones: influence of ceric chloride on the stereochemistry of reaction
title_fullStr Stereoselective sodium borohydride reductions of cyclopentanones: influence of ceric chloride on the stereochemistry of reaction
title_full_unstemmed Stereoselective sodium borohydride reductions of cyclopentanones: influence of ceric chloride on the stereochemistry of reaction
title_sort Stereoselective sodium borohydride reductions of cyclopentanones: influence of ceric chloride on the stereochemistry of reaction
author Constantino,Mauricio Gomes
author_facet Constantino,Mauricio Gomes
Matias,Luiz Gonzaga de Oliveira
Silva,Gil Valdo José da
Barbieri,Emerson
Gambardella,Maria Teresa do Prado
author_role author
author2 Matias,Luiz Gonzaga de Oliveira
Silva,Gil Valdo José da
Barbieri,Emerson
Gambardella,Maria Teresa do Prado
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Constantino,Mauricio Gomes
Matias,Luiz Gonzaga de Oliveira
Silva,Gil Valdo José da
Barbieri,Emerson
Gambardella,Maria Teresa do Prado
dc.subject.por.fl_str_mv cyclopentanones
stereoselective reduction
sodium borohydride
ceric chloride
topic cyclopentanones
stereoselective reduction
sodium borohydride
ceric chloride
description In this paper we describe the reduction by NaBH4 of some cyclopentanones containing an oxygenated function at the side chain position beta to the carbonyl group, both in the presence and in the absence of CeCl3. Some suggestions for the rationalization of the results are discussed, considering the stereochemical course of the reactions.
publishDate 1998
dc.date.none.fl_str_mv 1998-11-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421998000600009
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421998000600009
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0100-40421998000600009
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.21 n.6 1998
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
_version_ 1750318100828389376

Registros relacionados