A FORMAÇÃO DA CAMADA PROTETORA DE FeCO3 E O CONTROLE DA CORROSÃO POR CO2 EM CONDIÇOES DE FLUXO TURBULENTO
Autor(a) principal: | |
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Data de Publicação: | 2016 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Química Nova (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000901027 |
Resumo: | The formation of a protective layer of iron carbonate (FeCO3) can reduce the rates of corrosion and prolong the useful life of carbon steel. However, turbulent flow conditions in this layer can easily be damaged and thus compromise the protection of the steel. In this work, will be presented a methodology based on the chemical aspects of the mechanism of formation of iron carbonate layer in a Thin Channel Flow Cell (TCFC). Electrochemical techniques were used to measure the corrosion rate and corrosion potential on the surface of steel API X65 exposed to aqueous solution of 1 wt.% NaCl purged with CO2 at 2 atm, pH 6.6 and 80°C in turbulent flow conditions. The surfaces and cross sections of the samples were characterized by means of Scanning Electron Microscopy (SEM) and Energy-Dispersive X-ray (EDS) analysis. The results confirm the nucleation and growth of iron carbonate layer: the extension of supersaturation of the solution and the corrosion rate have decreased, and the corrosion potential has increased. The surface analysis showed dense and uniform FeCO3 layer with c.a. 20 µm thick after 120 hours in turbulent flow conditions. |
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A FORMAÇÃO DA CAMADA PROTETORA DE FeCO3 E O CONTROLE DA CORROSÃO POR CO2 EM CONDIÇOES DE FLUXO TURBULENTOiron carbonate (FeCO3)CO2 corrosionflow cellThe formation of a protective layer of iron carbonate (FeCO3) can reduce the rates of corrosion and prolong the useful life of carbon steel. However, turbulent flow conditions in this layer can easily be damaged and thus compromise the protection of the steel. In this work, will be presented a methodology based on the chemical aspects of the mechanism of formation of iron carbonate layer in a Thin Channel Flow Cell (TCFC). Electrochemical techniques were used to measure the corrosion rate and corrosion potential on the surface of steel API X65 exposed to aqueous solution of 1 wt.% NaCl purged with CO2 at 2 atm, pH 6.6 and 80°C in turbulent flow conditions. The surfaces and cross sections of the samples were characterized by means of Scanning Electron Microscopy (SEM) and Energy-Dispersive X-ray (EDS) analysis. The results confirm the nucleation and growth of iron carbonate layer: the extension of supersaturation of the solution and the corrosion rate have decreased, and the corrosion potential has increased. The surface analysis showed dense and uniform FeCO3 layer with c.a. 20 µm thick after 120 hours in turbulent flow conditions.Sociedade Brasileira de Química2016-11-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000901027Química Nova v.39 n.9 2016reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0100-4042.20160116info:eu-repo/semantics/openAccessFerreira,Lilian R. M.Klok,Simone M.Ponte,Haroldo de A.Farelas,Fernandopor2016-11-23T00:00:00Zoai:scielo:S0100-40422016000901027Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2016-11-23T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
A FORMAÇÃO DA CAMADA PROTETORA DE FeCO3 E O CONTROLE DA CORROSÃO POR CO2 EM CONDIÇOES DE FLUXO TURBULENTO |
title |
A FORMAÇÃO DA CAMADA PROTETORA DE FeCO3 E O CONTROLE DA CORROSÃO POR CO2 EM CONDIÇOES DE FLUXO TURBULENTO |
spellingShingle |
A FORMAÇÃO DA CAMADA PROTETORA DE FeCO3 E O CONTROLE DA CORROSÃO POR CO2 EM CONDIÇOES DE FLUXO TURBULENTO Ferreira,Lilian R. M. iron carbonate (FeCO3) CO2 corrosion flow cell |
title_short |
A FORMAÇÃO DA CAMADA PROTETORA DE FeCO3 E O CONTROLE DA CORROSÃO POR CO2 EM CONDIÇOES DE FLUXO TURBULENTO |
title_full |
A FORMAÇÃO DA CAMADA PROTETORA DE FeCO3 E O CONTROLE DA CORROSÃO POR CO2 EM CONDIÇOES DE FLUXO TURBULENTO |
title_fullStr |
A FORMAÇÃO DA CAMADA PROTETORA DE FeCO3 E O CONTROLE DA CORROSÃO POR CO2 EM CONDIÇOES DE FLUXO TURBULENTO |
title_full_unstemmed |
A FORMAÇÃO DA CAMADA PROTETORA DE FeCO3 E O CONTROLE DA CORROSÃO POR CO2 EM CONDIÇOES DE FLUXO TURBULENTO |
title_sort |
A FORMAÇÃO DA CAMADA PROTETORA DE FeCO3 E O CONTROLE DA CORROSÃO POR CO2 EM CONDIÇOES DE FLUXO TURBULENTO |
author |
Ferreira,Lilian R. M. |
author_facet |
Ferreira,Lilian R. M. Klok,Simone M. Ponte,Haroldo de A. Farelas,Fernando |
author_role |
author |
author2 |
Klok,Simone M. Ponte,Haroldo de A. Farelas,Fernando |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Ferreira,Lilian R. M. Klok,Simone M. Ponte,Haroldo de A. Farelas,Fernando |
dc.subject.por.fl_str_mv |
iron carbonate (FeCO3) CO2 corrosion flow cell |
topic |
iron carbonate (FeCO3) CO2 corrosion flow cell |
description |
The formation of a protective layer of iron carbonate (FeCO3) can reduce the rates of corrosion and prolong the useful life of carbon steel. However, turbulent flow conditions in this layer can easily be damaged and thus compromise the protection of the steel. In this work, will be presented a methodology based on the chemical aspects of the mechanism of formation of iron carbonate layer in a Thin Channel Flow Cell (TCFC). Electrochemical techniques were used to measure the corrosion rate and corrosion potential on the surface of steel API X65 exposed to aqueous solution of 1 wt.% NaCl purged with CO2 at 2 atm, pH 6.6 and 80°C in turbulent flow conditions. The surfaces and cross sections of the samples were characterized by means of Scanning Electron Microscopy (SEM) and Energy-Dispersive X-ray (EDS) analysis. The results confirm the nucleation and growth of iron carbonate layer: the extension of supersaturation of the solution and the corrosion rate have decreased, and the corrosion potential has increased. The surface analysis showed dense and uniform FeCO3 layer with c.a. 20 µm thick after 120 hours in turbulent flow conditions. |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016-11-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000901027 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000901027 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
10.5935/0100-4042.20160116 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Química Nova v.39 n.9 2016 reponame:Química Nova (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Química Nova (Online) |
collection |
Química Nova (Online) |
repository.name.fl_str_mv |
Química Nova (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
quimicanova@sbq.org.br |
_version_ |
1750318117892915200 |