Selective hydrogenation of furfural on Ir/TiO2 catalysts

Detalhes bibliográficos
Autor(a) principal: Reyes,Patricio
Data de Publicação: 2010
Outros Autores: Salinas,Daniela, Campos,Cristian, Oportus,Marcelo, Murcia,Julie, Rojas,Hugo, Borda,Gloria, Fierro,José Luís García
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000400002
Resumo: Titania-supported Ir catalysts were used in the hydrogenation of furfural. Reactions were carried out in a stirred batch type reactor at 0.62MPa and 363K using a 0.10M solution of furfural in a 1:1 mixture n-heptane -ethanol as solvent. Catalysts containing 2 wt% of Ir were reduced in H2 flow at different temperatures in the range 473-773K. The catalysts were characterized by H2 chemisorption, TEM, TPR, TPD of NH3 and XPS. Conversion of furfural is higher at lower reduction temperatures, but leads to byproducts whereas reduction at higher temperatures shows selectivity to furfuryl alcohol close to 100%.
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spelling Selective hydrogenation of furfural on Ir/TiO2 catalystsiridiumTiO2furfuralTitania-supported Ir catalysts were used in the hydrogenation of furfural. Reactions were carried out in a stirred batch type reactor at 0.62MPa and 363K using a 0.10M solution of furfural in a 1:1 mixture n-heptane -ethanol as solvent. Catalysts containing 2 wt% of Ir were reduced in H2 flow at different temperatures in the range 473-773K. The catalysts were characterized by H2 chemisorption, TEM, TPR, TPD of NH3 and XPS. Conversion of furfural is higher at lower reduction temperatures, but leads to byproducts whereas reduction at higher temperatures shows selectivity to furfuryl alcohol close to 100%.Sociedade Brasileira de Química2010-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000400002Química Nova v.33 n.4 2010reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422010000400002info:eu-repo/semantics/openAccessReyes,PatricioSalinas,DanielaCampos,CristianOportus,MarceloMurcia,JulieRojas,HugoBorda,GloriaFierro,José Luís Garcíaeng2010-06-02T00:00:00Zoai:scielo:S0100-40422010000400002Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2010-06-02T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Selective hydrogenation of furfural on Ir/TiO2 catalysts
title Selective hydrogenation of furfural on Ir/TiO2 catalysts
spellingShingle Selective hydrogenation of furfural on Ir/TiO2 catalysts
Reyes,Patricio
iridium
TiO2
furfural
title_short Selective hydrogenation of furfural on Ir/TiO2 catalysts
title_full Selective hydrogenation of furfural on Ir/TiO2 catalysts
title_fullStr Selective hydrogenation of furfural on Ir/TiO2 catalysts
title_full_unstemmed Selective hydrogenation of furfural on Ir/TiO2 catalysts
title_sort Selective hydrogenation of furfural on Ir/TiO2 catalysts
author Reyes,Patricio
author_facet Reyes,Patricio
Salinas,Daniela
Campos,Cristian
Oportus,Marcelo
Murcia,Julie
Rojas,Hugo
Borda,Gloria
Fierro,José Luís García
author_role author
author2 Salinas,Daniela
Campos,Cristian
Oportus,Marcelo
Murcia,Julie
Rojas,Hugo
Borda,Gloria
Fierro,José Luís García
author2_role author
author
author
author
author
author
author
dc.contributor.author.fl_str_mv Reyes,Patricio
Salinas,Daniela
Campos,Cristian
Oportus,Marcelo
Murcia,Julie
Rojas,Hugo
Borda,Gloria
Fierro,José Luís García
dc.subject.por.fl_str_mv iridium
TiO2
furfural
topic iridium
TiO2
furfural
description Titania-supported Ir catalysts were used in the hydrogenation of furfural. Reactions were carried out in a stirred batch type reactor at 0.62MPa and 363K using a 0.10M solution of furfural in a 1:1 mixture n-heptane -ethanol as solvent. Catalysts containing 2 wt% of Ir were reduced in H2 flow at different temperatures in the range 473-773K. The catalysts were characterized by H2 chemisorption, TEM, TPR, TPD of NH3 and XPS. Conversion of furfural is higher at lower reduction temperatures, but leads to byproducts whereas reduction at higher temperatures shows selectivity to furfuryl alcohol close to 100%.
publishDate 2010
dc.date.none.fl_str_mv 2010-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000400002
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000400002
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0100-40422010000400002
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.33 n.4 2010
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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