Low metal loading catalysts used for the selective hydrogenation of styrene

Detalhes bibliográficos
Autor(a) principal: Badano,Juan
Data de Publicação: 2010
Outros Autores: Lederhos,Cecilia, Quiroga,Mónica, L'Argentière,Pablo, Coloma-Pascual,Fernando
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000100010
Resumo: A series of Group VIII metal catalysts was obtained for the semi-hydrogenation of styrene. Catalysts were characterized by Hydrogen Chemisorption, TPR and XPS. Palladium, rhodium and platinum low metal loading prepared catalysts presented high activity and selectivity (ca. 98%) during the semi-hydrogenation of styrene, being palladium the most active catalyst. The ruthenium catalyst also presented high selectivity (ca. 98%), but the lowest activity. For the palladium catalyst, the influence of the precursor salt and of the reduction temperature on the activity and selectivity were studied. The following activity series was obtained: PdN-423 > PdCl-673 > PdCl-373> PtCl-673 > RhCl-673 >> RuCl-673. As determined by XPS, differences in activity could be attributed, at least in part, to electronic effects.
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spelling Low metal loading catalysts used for the selective hydrogenation of styreneselective hydrogenationmetal catalystsstyreneA series of Group VIII metal catalysts was obtained for the semi-hydrogenation of styrene. Catalysts were characterized by Hydrogen Chemisorption, TPR and XPS. Palladium, rhodium and platinum low metal loading prepared catalysts presented high activity and selectivity (ca. 98%) during the semi-hydrogenation of styrene, being palladium the most active catalyst. The ruthenium catalyst also presented high selectivity (ca. 98%), but the lowest activity. For the palladium catalyst, the influence of the precursor salt and of the reduction temperature on the activity and selectivity were studied. The following activity series was obtained: PdN-423 > PdCl-673 > PdCl-373> PtCl-673 > RhCl-673 >> RuCl-673. As determined by XPS, differences in activity could be attributed, at least in part, to electronic effects.Sociedade Brasileira de Química2010-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000100010Química Nova v.33 n.1 2010reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422010000100010info:eu-repo/semantics/openAccessBadano,JuanLederhos,CeciliaQuiroga,MónicaL'Argentière,PabloColoma-Pascual,Fernandoeng2010-02-05T00:00:00Zoai:scielo:S0100-40422010000100010Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2010-02-05T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Low metal loading catalysts used for the selective hydrogenation of styrene
title Low metal loading catalysts used for the selective hydrogenation of styrene
spellingShingle Low metal loading catalysts used for the selective hydrogenation of styrene
Badano,Juan
selective hydrogenation
metal catalysts
styrene
title_short Low metal loading catalysts used for the selective hydrogenation of styrene
title_full Low metal loading catalysts used for the selective hydrogenation of styrene
title_fullStr Low metal loading catalysts used for the selective hydrogenation of styrene
title_full_unstemmed Low metal loading catalysts used for the selective hydrogenation of styrene
title_sort Low metal loading catalysts used for the selective hydrogenation of styrene
author Badano,Juan
author_facet Badano,Juan
Lederhos,Cecilia
Quiroga,Mónica
L'Argentière,Pablo
Coloma-Pascual,Fernando
author_role author
author2 Lederhos,Cecilia
Quiroga,Mónica
L'Argentière,Pablo
Coloma-Pascual,Fernando
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Badano,Juan
Lederhos,Cecilia
Quiroga,Mónica
L'Argentière,Pablo
Coloma-Pascual,Fernando
dc.subject.por.fl_str_mv selective hydrogenation
metal catalysts
styrene
topic selective hydrogenation
metal catalysts
styrene
description A series of Group VIII metal catalysts was obtained for the semi-hydrogenation of styrene. Catalysts were characterized by Hydrogen Chemisorption, TPR and XPS. Palladium, rhodium and platinum low metal loading prepared catalysts presented high activity and selectivity (ca. 98%) during the semi-hydrogenation of styrene, being palladium the most active catalyst. The ruthenium catalyst also presented high selectivity (ca. 98%), but the lowest activity. For the palladium catalyst, the influence of the precursor salt and of the reduction temperature on the activity and selectivity were studied. The following activity series was obtained: PdN-423 > PdCl-673 > PdCl-373> PtCl-673 > RhCl-673 >> RuCl-673. As determined by XPS, differences in activity could be attributed, at least in part, to electronic effects.
publishDate 2010
dc.date.none.fl_str_mv 2010-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000100010
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000100010
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0100-40422010000100010
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.33 n.1 2010
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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