SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC

Detalhes bibliográficos
Autor(a) principal: Israr,Farrukh
Data de Publicação: 2016
Outros Autores: Kim,Duk Kyung, Kim,Yeongmin, Chun,Wongee
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000600669
Resumo: Ni-BTC (BTC = 1,3,5-benzene tricarboxylate) metal organic framework (MOF) was synthesized using different solvent conditions. Solvent mixtures of water/N,N-dimethylformamide (DMF), water/ethanol, and water/ethanol/DMF were used for the reactions with or without a variety of bases at 160 ºC for 48 hours. Even with same green crystals, prepared MOFs show all different BET surface areas and different XRD patterns. The highest BET surface area of the crystals was 850 m2/g obtained from water/DMF solvent with NH4OH as a base. The measured surface areas of the crystals follows the order of Ni-BTC(water/DMF-NH4OH) > Ni-BTC(water/DMF-TMA) > Ni-BTC(water/DMF) > Ni-BTC(water/DMF-Pyridine)> Ni-BTC(water/ethanol)> Ni-BTC(water/DMF-aniline)> Ni-BTC(water/DMF-NaOH).
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network_name_str Química Nova (Online)
repository_id_str
spelling SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTCNi-BTC MOFdifferent solvent conditionsbasesdifferent BETsNi-BTC (BTC = 1,3,5-benzene tricarboxylate) metal organic framework (MOF) was synthesized using different solvent conditions. Solvent mixtures of water/N,N-dimethylformamide (DMF), water/ethanol, and water/ethanol/DMF were used for the reactions with or without a variety of bases at 160 ºC for 48 hours. Even with same green crystals, prepared MOFs show all different BET surface areas and different XRD patterns. The highest BET surface area of the crystals was 850 m2/g obtained from water/DMF solvent with NH4OH as a base. The measured surface areas of the crystals follows the order of Ni-BTC(water/DMF-NH4OH) > Ni-BTC(water/DMF-TMA) > Ni-BTC(water/DMF) > Ni-BTC(water/DMF-Pyridine)> Ni-BTC(water/ethanol)> Ni-BTC(water/DMF-aniline)> Ni-BTC(water/DMF-NaOH).Sociedade Brasileira de Química2016-07-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000600669Química Nova v.39 n.6 2016reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0100-4042.20160068info:eu-repo/semantics/openAccessIsrar,FarrukhKim,Duk KyungKim,YeongminChun,Wongeeeng2016-08-10T00:00:00Zoai:scielo:S0100-40422016000600669Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2016-08-10T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC
title SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC
spellingShingle SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC
Israr,Farrukh
Ni-BTC MOF
different solvent conditions
bases
different BETs
title_short SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC
title_full SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC
title_fullStr SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC
title_full_unstemmed SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC
title_sort SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC
author Israr,Farrukh
author_facet Israr,Farrukh
Kim,Duk Kyung
Kim,Yeongmin
Chun,Wongee
author_role author
author2 Kim,Duk Kyung
Kim,Yeongmin
Chun,Wongee
author2_role author
author
author
dc.contributor.author.fl_str_mv Israr,Farrukh
Kim,Duk Kyung
Kim,Yeongmin
Chun,Wongee
dc.subject.por.fl_str_mv Ni-BTC MOF
different solvent conditions
bases
different BETs
topic Ni-BTC MOF
different solvent conditions
bases
different BETs
description Ni-BTC (BTC = 1,3,5-benzene tricarboxylate) metal organic framework (MOF) was synthesized using different solvent conditions. Solvent mixtures of water/N,N-dimethylformamide (DMF), water/ethanol, and water/ethanol/DMF were used for the reactions with or without a variety of bases at 160 ºC for 48 hours. Even with same green crystals, prepared MOFs show all different BET surface areas and different XRD patterns. The highest BET surface area of the crystals was 850 m2/g obtained from water/DMF solvent with NH4OH as a base. The measured surface areas of the crystals follows the order of Ni-BTC(water/DMF-NH4OH) > Ni-BTC(water/DMF-TMA) > Ni-BTC(water/DMF) > Ni-BTC(water/DMF-Pyridine)> Ni-BTC(water/ethanol)> Ni-BTC(water/DMF-aniline)> Ni-BTC(water/DMF-NaOH).
publishDate 2016
dc.date.none.fl_str_mv 2016-07-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000600669
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000600669
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.5935/0100-4042.20160068
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.39 n.6 2016
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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