SULFONIC ACID-FUNCTIONALIZED LUS-1: AN EFFICIENT CATALYST FOR ONE-POT SYNTHESIS OF 2,4-DIAMINO PYRIMIDINE-5-CARBONITRILE DERIVATIVES

Detalhes bibliográficos
Autor(a) principal: Rahimifard,Mahshid
Data de Publicação: 2016
Outros Autores: Ziarani,Ghodsi Mohammadi, Badiei,Alireza
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000800962
Resumo: An efficient acidic functionalization of mesoporous silica LUS-1 (Laval University Silica) and its application as a recyclable heterogeneous catalyst in the synthesis of 2,4-diamino pyrimidine-5-carbonitriles via condensation reaction of aromatic aldehydes, malononitrile and guanidine carbonate in solvent-free condition has been reported. This green method offers a number of advantages such as short reaction time, good yields, simple work-up procedure, recyclable catalyst and environmentally friendly conditions.
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spelling SULFONIC ACID-FUNCTIONALIZED LUS-1: AN EFFICIENT CATALYST FOR ONE-POT SYNTHESIS OF 2,4-DIAMINO PYRIMIDINE-5-CARBONITRILE DERIVATIVESsulfonic acid functionalized LUS-12,4-diamino pyrimidine-5-carbonitrileguanidine carbonatenanoporous heterogeneous acid catalystsolvent-free conditionAn efficient acidic functionalization of mesoporous silica LUS-1 (Laval University Silica) and its application as a recyclable heterogeneous catalyst in the synthesis of 2,4-diamino pyrimidine-5-carbonitriles via condensation reaction of aromatic aldehydes, malononitrile and guanidine carbonate in solvent-free condition has been reported. This green method offers a number of advantages such as short reaction time, good yields, simple work-up procedure, recyclable catalyst and environmentally friendly conditions.Sociedade Brasileira de Química2016-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000800962Química Nova v.39 n.8 2016reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0100-4042.20160111info:eu-repo/semantics/openAccessRahimifard,MahshidZiarani,Ghodsi MohammadiBadiei,Alirezaeng2016-10-18T00:00:00Zoai:scielo:S0100-40422016000800962Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2016-10-18T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv SULFONIC ACID-FUNCTIONALIZED LUS-1: AN EFFICIENT CATALYST FOR ONE-POT SYNTHESIS OF 2,4-DIAMINO PYRIMIDINE-5-CARBONITRILE DERIVATIVES
title SULFONIC ACID-FUNCTIONALIZED LUS-1: AN EFFICIENT CATALYST FOR ONE-POT SYNTHESIS OF 2,4-DIAMINO PYRIMIDINE-5-CARBONITRILE DERIVATIVES
spellingShingle SULFONIC ACID-FUNCTIONALIZED LUS-1: AN EFFICIENT CATALYST FOR ONE-POT SYNTHESIS OF 2,4-DIAMINO PYRIMIDINE-5-CARBONITRILE DERIVATIVES
Rahimifard,Mahshid
sulfonic acid functionalized LUS-1
2,4-diamino pyrimidine-5-carbonitrile
guanidine carbonate
nanoporous heterogeneous acid catalyst
solvent-free condition
title_short SULFONIC ACID-FUNCTIONALIZED LUS-1: AN EFFICIENT CATALYST FOR ONE-POT SYNTHESIS OF 2,4-DIAMINO PYRIMIDINE-5-CARBONITRILE DERIVATIVES
title_full SULFONIC ACID-FUNCTIONALIZED LUS-1: AN EFFICIENT CATALYST FOR ONE-POT SYNTHESIS OF 2,4-DIAMINO PYRIMIDINE-5-CARBONITRILE DERIVATIVES
title_fullStr SULFONIC ACID-FUNCTIONALIZED LUS-1: AN EFFICIENT CATALYST FOR ONE-POT SYNTHESIS OF 2,4-DIAMINO PYRIMIDINE-5-CARBONITRILE DERIVATIVES
title_full_unstemmed SULFONIC ACID-FUNCTIONALIZED LUS-1: AN EFFICIENT CATALYST FOR ONE-POT SYNTHESIS OF 2,4-DIAMINO PYRIMIDINE-5-CARBONITRILE DERIVATIVES
title_sort SULFONIC ACID-FUNCTIONALIZED LUS-1: AN EFFICIENT CATALYST FOR ONE-POT SYNTHESIS OF 2,4-DIAMINO PYRIMIDINE-5-CARBONITRILE DERIVATIVES
author Rahimifard,Mahshid
author_facet Rahimifard,Mahshid
Ziarani,Ghodsi Mohammadi
Badiei,Alireza
author_role author
author2 Ziarani,Ghodsi Mohammadi
Badiei,Alireza
author2_role author
author
dc.contributor.author.fl_str_mv Rahimifard,Mahshid
Ziarani,Ghodsi Mohammadi
Badiei,Alireza
dc.subject.por.fl_str_mv sulfonic acid functionalized LUS-1
2,4-diamino pyrimidine-5-carbonitrile
guanidine carbonate
nanoporous heterogeneous acid catalyst
solvent-free condition
topic sulfonic acid functionalized LUS-1
2,4-diamino pyrimidine-5-carbonitrile
guanidine carbonate
nanoporous heterogeneous acid catalyst
solvent-free condition
description An efficient acidic functionalization of mesoporous silica LUS-1 (Laval University Silica) and its application as a recyclable heterogeneous catalyst in the synthesis of 2,4-diamino pyrimidine-5-carbonitriles via condensation reaction of aromatic aldehydes, malononitrile and guanidine carbonate in solvent-free condition has been reported. This green method offers a number of advantages such as short reaction time, good yields, simple work-up procedure, recyclable catalyst and environmentally friendly conditions.
publishDate 2016
dc.date.none.fl_str_mv 2016-09-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000800962
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000800962
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.5935/0100-4042.20160111
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.39 n.8 2016
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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