AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA

Detalhes bibliográficos
Autor(a) principal: Lara,Daniela M. de
Data de Publicação: 2017
Outros Autores: Bresciani,Laís, Osterkamp,Isa Carla, Hilgemann,Maurício, Ethur,Eduardo, Jasper,André, Ferrão,Marco Flôres, Uhl,Dieter, Stülp,Simone
Tipo de documento: Artigo
Idioma: por
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000800895
Resumo: The aim of the study is to evaluate the physical and chemical changes that occur on wood fragments submitted to different temperatures, verifying their influence on significant chemical characteristics in the forming process. Carbonization process in muffle associated to the techniques of Thermogravimetry, Fourier Transform Infrared Spectroscopy (FTIR) and multivariate analysis. The analyses were performed on 3 replicates for each burn temperature. The temperature of the thermal muffle process was in every 50 °C, from 200 °C to 600 °C. TGA were performed under nitrogen atmosphere, using a heating ramp from 25 °C min-1 to 995 °C. A range between 1900 to 650 cm-1 was used, with a resolution of 4 cm-1 and 64 scans. The PCA showed that it is possible to describe 95.73% of the data, grouping the samples into three main clusters. These clusters were used to build a SIMCA (Soft Independent Modeling of Class Analogy) model, enabling to predict with 100%. Results showed that technical associations, such as TGA, FTIR and multivariate analysis may help to characterize the natural carbonization process and, in future works, contribute to significant (paleo)environmental inferences.
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spelling AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADAAraucariaceaethermogravimetrymid-infraredmultivariate analysisThe aim of the study is to evaluate the physical and chemical changes that occur on wood fragments submitted to different temperatures, verifying their influence on significant chemical characteristics in the forming process. Carbonization process in muffle associated to the techniques of Thermogravimetry, Fourier Transform Infrared Spectroscopy (FTIR) and multivariate analysis. The analyses were performed on 3 replicates for each burn temperature. The temperature of the thermal muffle process was in every 50 °C, from 200 °C to 600 °C. TGA were performed under nitrogen atmosphere, using a heating ramp from 25 °C min-1 to 995 °C. A range between 1900 to 650 cm-1 was used, with a resolution of 4 cm-1 and 64 scans. The PCA showed that it is possible to describe 95.73% of the data, grouping the samples into three main clusters. These clusters were used to build a SIMCA (Soft Independent Modeling of Class Analogy) model, enabling to predict with 100%. Results showed that technical associations, such as TGA, FTIR and multivariate analysis may help to characterize the natural carbonization process and, in future works, contribute to significant (paleo)environmental inferences.Sociedade Brasileira de Química2017-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000800895Química Nova v.40 n.8 2017reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0100-4042.20170095info:eu-repo/semantics/openAccessLara,Daniela M. deBresciani,LaísOsterkamp,Isa CarlaHilgemann,MaurícioEthur,EduardoJasper,AndréFerrão,Marco FlôresUhl,DieterStülp,Simonepor2017-10-04T00:00:00Zoai:scielo:S0100-40422017000800895Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2017-10-04T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA
title AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA
spellingShingle AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA
Lara,Daniela M. de
Araucariaceae
thermogravimetry
mid-infrared
multivariate analysis
title_short AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA
title_full AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA
title_fullStr AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA
title_full_unstemmed AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA
title_sort AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA
author Lara,Daniela M. de
author_facet Lara,Daniela M. de
Bresciani,Laís
Osterkamp,Isa Carla
Hilgemann,Maurício
Ethur,Eduardo
Jasper,André
Ferrão,Marco Flôres
Uhl,Dieter
Stülp,Simone
author_role author
author2 Bresciani,Laís
Osterkamp,Isa Carla
Hilgemann,Maurício
Ethur,Eduardo
Jasper,André
Ferrão,Marco Flôres
Uhl,Dieter
Stülp,Simone
author2_role author
author
author
author
author
author
author
author
dc.contributor.author.fl_str_mv Lara,Daniela M. de
Bresciani,Laís
Osterkamp,Isa Carla
Hilgemann,Maurício
Ethur,Eduardo
Jasper,André
Ferrão,Marco Flôres
Uhl,Dieter
Stülp,Simone
dc.subject.por.fl_str_mv Araucariaceae
thermogravimetry
mid-infrared
multivariate analysis
topic Araucariaceae
thermogravimetry
mid-infrared
multivariate analysis
description The aim of the study is to evaluate the physical and chemical changes that occur on wood fragments submitted to different temperatures, verifying their influence on significant chemical characteristics in the forming process. Carbonization process in muffle associated to the techniques of Thermogravimetry, Fourier Transform Infrared Spectroscopy (FTIR) and multivariate analysis. The analyses were performed on 3 replicates for each burn temperature. The temperature of the thermal muffle process was in every 50 °C, from 200 °C to 600 °C. TGA were performed under nitrogen atmosphere, using a heating ramp from 25 °C min-1 to 995 °C. A range between 1900 to 650 cm-1 was used, with a resolution of 4 cm-1 and 64 scans. The PCA showed that it is possible to describe 95.73% of the data, grouping the samples into three main clusters. These clusters were used to build a SIMCA (Soft Independent Modeling of Class Analogy) model, enabling to predict with 100%. Results showed that technical associations, such as TGA, FTIR and multivariate analysis may help to characterize the natural carbonization process and, in future works, contribute to significant (paleo)environmental inferences.
publishDate 2017
dc.date.none.fl_str_mv 2017-09-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000800895
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000800895
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv 10.21577/0100-4042.20170095
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.40 n.8 2017
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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