AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Química Nova (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000800895 |
Resumo: | The aim of the study is to evaluate the physical and chemical changes that occur on wood fragments submitted to different temperatures, verifying their influence on significant chemical characteristics in the forming process. Carbonization process in muffle associated to the techniques of Thermogravimetry, Fourier Transform Infrared Spectroscopy (FTIR) and multivariate analysis. The analyses were performed on 3 replicates for each burn temperature. The temperature of the thermal muffle process was in every 50 °C, from 200 °C to 600 °C. TGA were performed under nitrogen atmosphere, using a heating ramp from 25 °C min-1 to 995 °C. A range between 1900 to 650 cm-1 was used, with a resolution of 4 cm-1 and 64 scans. The PCA showed that it is possible to describe 95.73% of the data, grouping the samples into three main clusters. These clusters were used to build a SIMCA (Soft Independent Modeling of Class Analogy) model, enabling to predict with 100%. Results showed that technical associations, such as TGA, FTIR and multivariate analysis may help to characterize the natural carbonization process and, in future works, contribute to significant (paleo)environmental inferences. |
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oai:scielo:S0100-40422017000800895 |
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Química Nova (Online) |
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AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADAAraucariaceaethermogravimetrymid-infraredmultivariate analysisThe aim of the study is to evaluate the physical and chemical changes that occur on wood fragments submitted to different temperatures, verifying their influence on significant chemical characteristics in the forming process. Carbonization process in muffle associated to the techniques of Thermogravimetry, Fourier Transform Infrared Spectroscopy (FTIR) and multivariate analysis. The analyses were performed on 3 replicates for each burn temperature. The temperature of the thermal muffle process was in every 50 °C, from 200 °C to 600 °C. TGA were performed under nitrogen atmosphere, using a heating ramp from 25 °C min-1 to 995 °C. A range between 1900 to 650 cm-1 was used, with a resolution of 4 cm-1 and 64 scans. The PCA showed that it is possible to describe 95.73% of the data, grouping the samples into three main clusters. These clusters were used to build a SIMCA (Soft Independent Modeling of Class Analogy) model, enabling to predict with 100%. Results showed that technical associations, such as TGA, FTIR and multivariate analysis may help to characterize the natural carbonization process and, in future works, contribute to significant (paleo)environmental inferences.Sociedade Brasileira de Química2017-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000800895Química Nova v.40 n.8 2017reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0100-4042.20170095info:eu-repo/semantics/openAccessLara,Daniela M. deBresciani,LaísOsterkamp,Isa CarlaHilgemann,MaurícioEthur,EduardoJasper,AndréFerrão,Marco FlôresUhl,DieterStülp,Simonepor2017-10-04T00:00:00Zoai:scielo:S0100-40422017000800895Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2017-10-04T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA |
title |
AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA |
spellingShingle |
AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA Lara,Daniela M. de Araucariaceae thermogravimetry mid-infrared multivariate analysis |
title_short |
AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA |
title_full |
AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA |
title_fullStr |
AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA |
title_full_unstemmed |
AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA |
title_sort |
AVALIAÇÃO DE FRAGMENTOS DE LENHOS CARBONIZADOS DE ARAUCARIACEAE POR MEIO DE TERMOGRAVIMETRIA E INFRAVERMELHO ASSOCIADAS À ANÁLISE MULTIVARIADA |
author |
Lara,Daniela M. de |
author_facet |
Lara,Daniela M. de Bresciani,Laís Osterkamp,Isa Carla Hilgemann,Maurício Ethur,Eduardo Jasper,André Ferrão,Marco Flôres Uhl,Dieter Stülp,Simone |
author_role |
author |
author2 |
Bresciani,Laís Osterkamp,Isa Carla Hilgemann,Maurício Ethur,Eduardo Jasper,André Ferrão,Marco Flôres Uhl,Dieter Stülp,Simone |
author2_role |
author author author author author author author author |
dc.contributor.author.fl_str_mv |
Lara,Daniela M. de Bresciani,Laís Osterkamp,Isa Carla Hilgemann,Maurício Ethur,Eduardo Jasper,André Ferrão,Marco Flôres Uhl,Dieter Stülp,Simone |
dc.subject.por.fl_str_mv |
Araucariaceae thermogravimetry mid-infrared multivariate analysis |
topic |
Araucariaceae thermogravimetry mid-infrared multivariate analysis |
description |
The aim of the study is to evaluate the physical and chemical changes that occur on wood fragments submitted to different temperatures, verifying their influence on significant chemical characteristics in the forming process. Carbonization process in muffle associated to the techniques of Thermogravimetry, Fourier Transform Infrared Spectroscopy (FTIR) and multivariate analysis. The analyses were performed on 3 replicates for each burn temperature. The temperature of the thermal muffle process was in every 50 °C, from 200 °C to 600 °C. TGA were performed under nitrogen atmosphere, using a heating ramp from 25 °C min-1 to 995 °C. A range between 1900 to 650 cm-1 was used, with a resolution of 4 cm-1 and 64 scans. The PCA showed that it is possible to describe 95.73% of the data, grouping the samples into three main clusters. These clusters were used to build a SIMCA (Soft Independent Modeling of Class Analogy) model, enabling to predict with 100%. Results showed that technical associations, such as TGA, FTIR and multivariate analysis may help to characterize the natural carbonization process and, in future works, contribute to significant (paleo)environmental inferences. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-09-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000800895 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000800895 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
10.21577/0100-4042.20170095 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Química Nova v.40 n.8 2017 reponame:Química Nova (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Química Nova (Online) |
collection |
Química Nova (Online) |
repository.name.fl_str_mv |
Química Nova (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
quimicanova@sbq.org.br |
_version_ |
1750318118409863168 |