Effect of dye structure and redox mediators on anaerobic azo and anthraquinone dye reduction
Autor(a) principal: | |
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Data de Publicação: | 2012 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Química Nova (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012000300008 |
Resumo: | We investigated the biological decolourisation of dyes with different molecular structures. The kinetic constant values (k1) achieved with azo dye Reactive Red 120 were 7.6 and 10.1 times higher in the presence of RM (redox mediators) AQDS and riboflavin, respectively, than the assays lacking RM. The kinetic constant achieved with the azo dye Congo Red was 42 times higher than that obtained with the anthraquinone dye Reactive Blue 4. The effect of RM on dye reduction was more evident for azo dyes resistant to reductive processes, and ineffective for anthraquinone dyes because of the structural stability of the latter. |
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Effect of dye structure and redox mediators on anaerobic azo and anthraquinone dye reductioncolour removaldyesstructure/activityWe investigated the biological decolourisation of dyes with different molecular structures. The kinetic constant values (k1) achieved with azo dye Reactive Red 120 were 7.6 and 10.1 times higher in the presence of RM (redox mediators) AQDS and riboflavin, respectively, than the assays lacking RM. The kinetic constant achieved with the azo dye Congo Red was 42 times higher than that obtained with the anthraquinone dye Reactive Blue 4. The effect of RM on dye reduction was more evident for azo dyes resistant to reductive processes, and ineffective for anthraquinone dyes because of the structural stability of the latter.Sociedade Brasileira de Química2012-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012000300008Química Nova v.35 n.3 2012reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422012000300008info:eu-repo/semantics/openAccessCosta,Mayara CarantinoMota,Francisco Suetônio B.Santos,André Bezerra DosMendonça,Glaydson Leandro FariasNascimento,Ronaldo Ferreira doeng2012-04-24T00:00:00Zoai:scielo:S0100-40422012000300008Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2012-04-24T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Effect of dye structure and redox mediators on anaerobic azo and anthraquinone dye reduction |
title |
Effect of dye structure and redox mediators on anaerobic azo and anthraquinone dye reduction |
spellingShingle |
Effect of dye structure and redox mediators on anaerobic azo and anthraquinone dye reduction Costa,Mayara Carantino colour removal dyes structure/activity |
title_short |
Effect of dye structure and redox mediators on anaerobic azo and anthraquinone dye reduction |
title_full |
Effect of dye structure and redox mediators on anaerobic azo and anthraquinone dye reduction |
title_fullStr |
Effect of dye structure and redox mediators on anaerobic azo and anthraquinone dye reduction |
title_full_unstemmed |
Effect of dye structure and redox mediators on anaerobic azo and anthraquinone dye reduction |
title_sort |
Effect of dye structure and redox mediators on anaerobic azo and anthraquinone dye reduction |
author |
Costa,Mayara Carantino |
author_facet |
Costa,Mayara Carantino Mota,Francisco Suetônio B. Santos,André Bezerra Dos Mendonça,Glaydson Leandro Farias Nascimento,Ronaldo Ferreira do |
author_role |
author |
author2 |
Mota,Francisco Suetônio B. Santos,André Bezerra Dos Mendonça,Glaydson Leandro Farias Nascimento,Ronaldo Ferreira do |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Costa,Mayara Carantino Mota,Francisco Suetônio B. Santos,André Bezerra Dos Mendonça,Glaydson Leandro Farias Nascimento,Ronaldo Ferreira do |
dc.subject.por.fl_str_mv |
colour removal dyes structure/activity |
topic |
colour removal dyes structure/activity |
description |
We investigated the biological decolourisation of dyes with different molecular structures. The kinetic constant values (k1) achieved with azo dye Reactive Red 120 were 7.6 and 10.1 times higher in the presence of RM (redox mediators) AQDS and riboflavin, respectively, than the assays lacking RM. The kinetic constant achieved with the azo dye Congo Red was 42 times higher than that obtained with the anthraquinone dye Reactive Blue 4. The effect of RM on dye reduction was more evident for azo dyes resistant to reductive processes, and ineffective for anthraquinone dyes because of the structural stability of the latter. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012000300008 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012000300008 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0100-40422012000300008 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Química Nova v.35 n.3 2012 reponame:Química Nova (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Química Nova (Online) |
collection |
Química Nova (Online) |
repository.name.fl_str_mv |
Química Nova (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
quimicanova@sbq.org.br |
_version_ |
1750318113131331584 |