Desenvolvimento de uma matriz de fenda instrumentada para o monitoramento reo-óptico do processo de extrusão
Autor(a) principal: | |
---|---|
Data de Publicação: | 2015 |
Tipo de documento: | Tese |
Idioma: | por |
Título da fonte: | Repositório Institucional da UFSCAR |
Texto Completo: | https://repositorio.ufscar.br/handle/ufscar/7174 |
Resumo: | A novel slit-die flow cell is presented for the evaluation of extrusion thermo-mechanical history on the flow character of polymers. The rheo-optical concept is claimed once both flow-birefringence and rheological character of polystyrene are probed during the process. To accomplish this task, three pressure gauges are flush-mounted along the channel of the slit-die to determine the pressure drop of the flowing polymer. Moreover, borosilicate optical windows are adjusted into two different sites in-between the pressure transducers. Thus, one could assess the rheo-optical responses at two different entrance lengths. When studying polystyrene melt, the flow birefringence measurements showed different molecular orientation levels along the channel axial direction, being slightly lower in the second section next to the slit die outlet. The viscosity values measured in-process were lower at the second section of the slit-die. In addition, they were well below that calculated from rotational rheometry. By following the time-temperature superposition, the melt temperatures assessed in real time were found to be considerably higher than those chosen as the set points. This was ascribed to viscous dissipation generated mainly at the extrusion barrel boundaries. The real time assessment of polymer melt by the use of thermocouples agreed with estimated ones from reduced variables method. On the other hand, temperature increments were found to be a function of the mass flow. This is not taken into account on bench techniques due to isothermal flow assumption. Rheo-optical measurements carried out at both steady state and transient mass flow procedure showed that polystyrene behaves as a thermo-rheological material and, apparently, the stress optical rule holds for the processing conditions investigated given the independence of the flow-birefringence versus stress curve slopes with feed rate and temperature set-points. |
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Santos, Adillys Marcelo da CunhaCanevarolo Júnior, Sebastião Vicentehttp://lattes.cnpq.br/4153664441338178http://lattes.cnpq.br/4714910313876978995e0f9e-7dd4-48f5-85e7-ec778026e5e12016-09-15T13:46:40Z2016-09-15T13:46:40Z2015-03-13SANTOS, Adillys Marcelo da Cunha. Desenvolvimento de uma matriz de fenda instrumentada para o monitoramento reo-óptico do processo de extrusão. 2015. Tese (Doutorado em Ciência e Engenharia de Materiais) – Universidade Federal de São Carlos, São Carlos, 2015. Disponível em: https://repositorio.ufscar.br/handle/ufscar/7174.https://repositorio.ufscar.br/handle/ufscar/7174A novel slit-die flow cell is presented for the evaluation of extrusion thermo-mechanical history on the flow character of polymers. The rheo-optical concept is claimed once both flow-birefringence and rheological character of polystyrene are probed during the process. To accomplish this task, three pressure gauges are flush-mounted along the channel of the slit-die to determine the pressure drop of the flowing polymer. Moreover, borosilicate optical windows are adjusted into two different sites in-between the pressure transducers. Thus, one could assess the rheo-optical responses at two different entrance lengths. When studying polystyrene melt, the flow birefringence measurements showed different molecular orientation levels along the channel axial direction, being slightly lower in the second section next to the slit die outlet. The viscosity values measured in-process were lower at the second section of the slit-die. In addition, they were well below that calculated from rotational rheometry. By following the time-temperature superposition, the melt temperatures assessed in real time were found to be considerably higher than those chosen as the set points. This was ascribed to viscous dissipation generated mainly at the extrusion barrel boundaries. The real time assessment of polymer melt by the use of thermocouples agreed with estimated ones from reduced variables method. On the other hand, temperature increments were found to be a function of the mass flow. This is not taken into account on bench techniques due to isothermal flow assumption. Rheo-optical measurements carried out at both steady state and transient mass flow procedure showed that polystyrene behaves as a thermo-rheological material and, apparently, the stress optical rule holds for the processing conditions investigated given the independence of the flow-birefringence versus stress curve slopes with feed rate and temperature set-points.Este trabalho apresenta o desenvolvimento de uma matriz de fenda instrumentada para avaliar a influência das condições termomecânicas do processo de extrusão dupla rosca no fluxo dos polímeros. A birrefringência de fluxo e as características reológicas do polímero são calculadas a partir dos dados obtidos no exato momento do processamento. Três transdutores de pressão foram montados ao longo do canal da matriz para permitir a determinação das quedas de pressão geradas pelo fluxo polimérico. Janelas ópticas de borossilicato foram ajustadas à matriz de fenda em dois sítios distintos. Ao se estudar o fluxo de poliestireno por birrefringência de fluxo foi possível verificar níveis de orientação distintos ao longo do canal, sendo maior para a primeira seção próxima a entrada da matriz. A caracterização reológica em tempo real sugere que as viscosidades nas duas seções analisadas são diferentes. Estas estavam bem abaixo dos valores experimentais obtidos por reometria rotacional. As estimativas de temperatura pelo princípio da superposição tempo-temperatura indicam que esta disparidade é função da liberação de energia interna na forma de calor gerada pelo histórico termomecânico no processo de extrusão, em função da dissipação viscosa. A medida da temperatura do fundido em tempo real pelo uso de termopares na região interna da matriz e em sua saída corroboram os dados estimados pelo método de redução de variáveis. No entanto, o aumento de temperatura é função da vazão mássica trabalhada, mostrando ainda mais característica térmica não uniforme do processo de extrusão. Os dados reo-ópticos obtidos no estado estacionário e no transiente de vazão mássica demonstram que o poliestireno usado é um material termoreologicamente simples e que, aparentemente, a regra do coeficiente de tensão óptica é válida nas condições trabalhadas, dado a independência da inclinação da curva de birrefringência de fluxo versus tensão na parede com a vazão e com a temperatura.Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)porUniversidade Federal de São CarlosCâmpus São CarlosPrograma de Pós-Graduação em Ciência e Engenharia de Materiais - PPGCEMUFSCarExtrusãoMonitoramento reo-ópticoBirrefringênciaMedidas em tempo realPoliestirenoENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICA::MATERIAIS NAO METALICOSDesenvolvimento de uma matriz de fenda instrumentada para o monitoramento reo-óptico do processo de extrusãoA novel slit die for rheo-optical monitoring of the extrusion processinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisOnline6006006b2d5997-da68-4e0a-acd3-60ce6225978finfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFSCARinstname:Universidade Federal de São Carlos (UFSCAR)instacron:UFSCARORIGINALTeseAMCS.pdfTeseAMCS.pdfapplication/pdf12834976https://repositorio.ufscar.br/bitstream/ufscar/7174/1/TeseAMCS.pdff37e04e7bd14b94b91c24c7b3f48e5ffMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81957https://repositorio.ufscar.br/bitstream/ufscar/7174/2/license.txtae0398b6f8b235e40ad82cba6c50031dMD52TEXTTeseAMCS.pdf.txtTeseAMCS.pdf.txtExtracted texttext/plain229408https://repositorio.ufscar.br/bitstream/ufscar/7174/3/TeseAMCS.pdf.txt8fc96faba6f09bc876e9b91fcee81696MD53THUMBNAILTeseAMCS.pdf.jpgTeseAMCS.pdf.jpgIM Thumbnailimage/jpeg6523https://repositorio.ufscar.br/bitstream/ufscar/7174/4/TeseAMCS.pdf.jpg3cec2d00493a7b00a1046a9d1b55ebffMD54ufscar/71742023-09-18 18:31:09.057oai:repositorio.ufscar.br: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Repositório InstitucionalPUBhttps://repositorio.ufscar.br/oai/requestopendoar:43222023-09-18T18:31:09Repositório Institucional da UFSCAR - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.por.fl_str_mv |
Desenvolvimento de uma matriz de fenda instrumentada para o monitoramento reo-óptico do processo de extrusão |
dc.title.alternative.eng.fl_str_mv |
A novel slit die for rheo-optical monitoring of the extrusion process |
title |
Desenvolvimento de uma matriz de fenda instrumentada para o monitoramento reo-óptico do processo de extrusão |
spellingShingle |
Desenvolvimento de uma matriz de fenda instrumentada para o monitoramento reo-óptico do processo de extrusão Santos, Adillys Marcelo da Cunha Extrusão Monitoramento reo-óptico Birrefringência Medidas em tempo real Poliestireno ENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICA::MATERIAIS NAO METALICOS |
title_short |
Desenvolvimento de uma matriz de fenda instrumentada para o monitoramento reo-óptico do processo de extrusão |
title_full |
Desenvolvimento de uma matriz de fenda instrumentada para o monitoramento reo-óptico do processo de extrusão |
title_fullStr |
Desenvolvimento de uma matriz de fenda instrumentada para o monitoramento reo-óptico do processo de extrusão |
title_full_unstemmed |
Desenvolvimento de uma matriz de fenda instrumentada para o monitoramento reo-óptico do processo de extrusão |
title_sort |
Desenvolvimento de uma matriz de fenda instrumentada para o monitoramento reo-óptico do processo de extrusão |
author |
Santos, Adillys Marcelo da Cunha |
author_facet |
Santos, Adillys Marcelo da Cunha |
author_role |
author |
dc.contributor.authorlattes.por.fl_str_mv |
http://lattes.cnpq.br/4714910313876978 |
dc.contributor.author.fl_str_mv |
Santos, Adillys Marcelo da Cunha |
dc.contributor.advisor1.fl_str_mv |
Canevarolo Júnior, Sebastião Vicente |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/4153664441338178 |
dc.contributor.authorID.fl_str_mv |
995e0f9e-7dd4-48f5-85e7-ec778026e5e1 |
contributor_str_mv |
Canevarolo Júnior, Sebastião Vicente |
dc.subject.por.fl_str_mv |
Extrusão Monitoramento reo-óptico Birrefringência Medidas em tempo real Poliestireno |
topic |
Extrusão Monitoramento reo-óptico Birrefringência Medidas em tempo real Poliestireno ENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICA::MATERIAIS NAO METALICOS |
dc.subject.cnpq.fl_str_mv |
ENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICA::MATERIAIS NAO METALICOS |
description |
A novel slit-die flow cell is presented for the evaluation of extrusion thermo-mechanical history on the flow character of polymers. The rheo-optical concept is claimed once both flow-birefringence and rheological character of polystyrene are probed during the process. To accomplish this task, three pressure gauges are flush-mounted along the channel of the slit-die to determine the pressure drop of the flowing polymer. Moreover, borosilicate optical windows are adjusted into two different sites in-between the pressure transducers. Thus, one could assess the rheo-optical responses at two different entrance lengths. When studying polystyrene melt, the flow birefringence measurements showed different molecular orientation levels along the channel axial direction, being slightly lower in the second section next to the slit die outlet. The viscosity values measured in-process were lower at the second section of the slit-die. In addition, they were well below that calculated from rotational rheometry. By following the time-temperature superposition, the melt temperatures assessed in real time were found to be considerably higher than those chosen as the set points. This was ascribed to viscous dissipation generated mainly at the extrusion barrel boundaries. The real time assessment of polymer melt by the use of thermocouples agreed with estimated ones from reduced variables method. On the other hand, temperature increments were found to be a function of the mass flow. This is not taken into account on bench techniques due to isothermal flow assumption. Rheo-optical measurements carried out at both steady state and transient mass flow procedure showed that polystyrene behaves as a thermo-rheological material and, apparently, the stress optical rule holds for the processing conditions investigated given the independence of the flow-birefringence versus stress curve slopes with feed rate and temperature set-points. |
publishDate |
2015 |
dc.date.issued.fl_str_mv |
2015-03-13 |
dc.date.accessioned.fl_str_mv |
2016-09-15T13:46:40Z |
dc.date.available.fl_str_mv |
2016-09-15T13:46:40Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/doctoralThesis |
format |
doctoralThesis |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
SANTOS, Adillys Marcelo da Cunha. Desenvolvimento de uma matriz de fenda instrumentada para o monitoramento reo-óptico do processo de extrusão. 2015. Tese (Doutorado em Ciência e Engenharia de Materiais) – Universidade Federal de São Carlos, São Carlos, 2015. Disponível em: https://repositorio.ufscar.br/handle/ufscar/7174. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufscar.br/handle/ufscar/7174 |
identifier_str_mv |
SANTOS, Adillys Marcelo da Cunha. Desenvolvimento de uma matriz de fenda instrumentada para o monitoramento reo-óptico do processo de extrusão. 2015. Tese (Doutorado em Ciência e Engenharia de Materiais) – Universidade Federal de São Carlos, São Carlos, 2015. Disponível em: https://repositorio.ufscar.br/handle/ufscar/7174. |
url |
https://repositorio.ufscar.br/handle/ufscar/7174 |
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por |
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600 600 |
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openAccess |
dc.publisher.none.fl_str_mv |
Universidade Federal de São Carlos Câmpus São Carlos |
dc.publisher.program.fl_str_mv |
Programa de Pós-Graduação em Ciência e Engenharia de Materiais - PPGCEM |
dc.publisher.initials.fl_str_mv |
UFSCar |
publisher.none.fl_str_mv |
Universidade Federal de São Carlos Câmpus São Carlos |
dc.source.none.fl_str_mv |
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