Anelasticidade em titânio, tântalo e na liga Ti-40Ta

Detalhes bibliográficos
Autor(a) principal: Patricio, Marco Antonio Tito
Data de Publicação: 2014
Tipo de documento: Dissertação
Idioma: por
Título da fonte: Repositório Institucional da UFSCAR
Texto Completo: https://repositorio.ufscar.br/handle/ufscar/5065
Resumo: The growing demand for increasingly resistant and biocompatible with the human body implantable materials, has led to an increase in demand for new metallic biomaterials. Some materials, such as titanium and its alloys, especially the Ti-6Al-4V, are widely used in the manufacture of orthopedic implants due to their excellent biocompatibility, high corrosion resistance and low density. However, the characteristics of these materials are not considered optimal, mainly because they have a high value of the elastic modulus when compared to the human bone. Include, that in the last decade studies have revealed diseases associated with elements such as Al and V, present in the alloy Ti-6Al-4V. Thus, it have looked for alternatives to the alloys used as biomaterials, still having one common element titanium, but having no toxic elements such as 𝛽 type titanium alloys, formed by non-toxic elements such as Nb, Ta, Zr, Mo and Sn has shown that lower values of modulus, greater fatigue resistance and corrosion resistance, exhibiting excellent biocompatibility. Accordingly, the alloys formed by Ti-Ta become promising candidates as biomaterials, since it has been observed that the content of Ta affects the value of the elastic modulus. For some compositions of this alloy, lower modulus values of this alloys that are currently used in biomedical applications were observed. However, the alloys formed by Ti-Ta still have properties that have been little studied. Thereby, the objectives of this master s project consist in getting the alloy Ti-40Ta and its characterization by means of the technique of mechanical spectroscopy, as of its elements that compose the alloy. The technique of mechanical spectroscopy to be non-destructive, it is widely used for providing the anelastic spectrum (oscillation frequency and internal friction as a function of temperature) is considered sensitive to phase transitions and dynamic processes, which are essential for understanding the structural changes occurring in these materials. This study was determined the dynamic elastic modulus for the pure Ti and Ta elements, and the Ti-40Ta through flexural vibrations. The elastic modulus found for the alloy at room temperature was (71 ± 5) GPa, which is in accordance with results available in the literature. The value of modulus of the alloy is lower when compared to the commercial biomedical alloys and is closer to that of human bone, which makes the alloy Ti-40Ta a potential candidate to be used in biomedical applications.
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spelling Patricio, Marco Antonio TitoFlorêncio, Odilahttp://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=E9418http://lattes.cnpq.br/288122105886097737b12463-6a5c-46cb-b1ab-f6eccf8598ab2016-06-02T20:16:53Z2014-07-252016-06-02T20:16:53Z2014-07-24PATRICIO, Marco Antonio Tito. Anelasticidade em titânio, tântalo e na liga Ti-40Ta. 2014. 88 f. Dissertação (Mestrado em Ciências Exatas e da Terra) - Universidade Federal de São Carlos, São Carlos, 2014.https://repositorio.ufscar.br/handle/ufscar/5065The growing demand for increasingly resistant and biocompatible with the human body implantable materials, has led to an increase in demand for new metallic biomaterials. Some materials, such as titanium and its alloys, especially the Ti-6Al-4V, are widely used in the manufacture of orthopedic implants due to their excellent biocompatibility, high corrosion resistance and low density. However, the characteristics of these materials are not considered optimal, mainly because they have a high value of the elastic modulus when compared to the human bone. Include, that in the last decade studies have revealed diseases associated with elements such as Al and V, present in the alloy Ti-6Al-4V. Thus, it have looked for alternatives to the alloys used as biomaterials, still having one common element titanium, but having no toxic elements such as 𝛽 type titanium alloys, formed by non-toxic elements such as Nb, Ta, Zr, Mo and Sn has shown that lower values of modulus, greater fatigue resistance and corrosion resistance, exhibiting excellent biocompatibility. Accordingly, the alloys formed by Ti-Ta become promising candidates as biomaterials, since it has been observed that the content of Ta affects the value of the elastic modulus. For some compositions of this alloy, lower modulus values of this alloys that are currently used in biomedical applications were observed. However, the alloys formed by Ti-Ta still have properties that have been little studied. Thereby, the objectives of this master s project consist in getting the alloy Ti-40Ta and its characterization by means of the technique of mechanical spectroscopy, as of its elements that compose the alloy. The technique of mechanical spectroscopy to be non-destructive, it is widely used for providing the anelastic spectrum (oscillation frequency and internal friction as a function of temperature) is considered sensitive to phase transitions and dynamic processes, which are essential for understanding the structural changes occurring in these materials. This study was determined the dynamic elastic modulus for the pure Ti and Ta elements, and the Ti-40Ta through flexural vibrations. The elastic modulus found for the alloy at room temperature was (71 ± 5) GPa, which is in accordance with results available in the literature. The value of modulus of the alloy is lower when compared to the commercial biomedical alloys and is closer to that of human bone, which makes the alloy Ti-40Ta a potential candidate to be used in biomedical applications.A crescente demanda por materiais implantáveis cada vez mais resistentes e biocompatíveis com o organismo humano, tem levado a um aumento na procura por novos biomateriais metálicos. Alguns materiais, como o titânio e suas ligas, com destaque para a liga Ti-6Al-4V, são largamente utilizados na fabricação de implantes ortopédicos devido as suas excelentes características como biocompatibilidade, alta resistência à corrosão e baixa densidade. Entretanto, as características desses materiais ainda não são consideradas ideais, principalmente porque apresentam um alto valor do módulo de elasticidade quando comparado com o osso humano. Cabe mencionar, que na última década estudos revelaram doenças associadas a elementos como o Al e V, presentes na liga Ti-6Al-4V. Desta forma, busca-se alternativas às ligas empregadas como biomateriais, ainda contendo como elemento principal o titânio, mas que não possuam elementos tóxicos. Estudos recentes mostram que as ligas de titânio tipo 𝛽, formadas por elementos não tóxicos como Nb, Ta, Zr, Mo e Sn, tem apresentado valores mais baixos módulo de elasticidade, maior resistência à fadiga e maior resistência à corrosão, além de exibir uma excelente biocompatibilidade. Neste sentido, as ligas formadas por Ti-Ta tornaram-se candidatas promissoras como biomateriais, uma vez que, foi observado que o teor de Ta afeta o valor do módulo de elasticidade. Para algumas composições, desta liga, foram observados valores de módulo inferiores as ligas de Ti que atualmente são empregadas em aplicações biomédicas. No entanto, as ligas formadas por Ti-Ta ainda possuem propriedades pouco estudadas. Deste modo, os objetivos deste projeto de mestrado consistem na obtenção da liga Ti-40Ta e na sua caracterização por meio da técnica de espectroscopia mecânica, bem como a de cada elemento que compõem a liga. A técnica de espectroscopia mecânica, por ser não destrutiva, é amplamente usada por fornecer o espectro anelástico (frequência de oscilação e atrito interno em função da temperatura), sendo considerada sensível a transições de fase e a processos dinâmicos, que são essenciais para compreender as alterações estruturais que ocorrem nestes materiais. Neste estudo, determinou-se o módulo de elasticidade dinâmico para os elementos puros, Ti e Ta, e para a liga Ti-40Ta por meio das vibrações flexurais. O módulo de elasticidade encontrado para a liga, em temperatura ambiente, foi de (71 ± 5) GPa, estando em concordância com os resultados disponíveis na literatura. O valor de módulo da liga é menor quando comparado ao das ligas biomédicas comerciais e está mais próximo a do osso humano, o que a torna a liga Ti-40Ta uma potencial candidata a ser empregada em aplicações biomédicas.Financiadora de Estudos e Projetosapplication/pdfporUniversidade Federal de São CarlosPrograma de Pós-Graduação em Física - PPGFUFSCarBRFísica da matéria condensadaAtrito internoLigas de titânioBiomateriaisMódulo de elasticidadeEspectroscopia mecânicaAnelasticidadeBiomaterialsTitanium alloysMechanical spectroscopyElastic modulusAnelasticityCIENCIAS EXATAS E DA TERRA::FISICAAnelasticidade em titânio, tântalo e na liga Ti-40Tainfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesis-1-198fccbf4-a29d-40cb-86de-fd2c22710626info:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFSCARinstname:Universidade Federal de São Carlos (UFSCAR)instacron:UFSCARORIGINAL5978.pdfapplication/pdf11727715https://repositorio.ufscar.br/bitstream/ufscar/5065/1/5978.pdf7ecd56710aed6f64b6e687a355a259bfMD51TEXT5978.pdf.txt5978.pdf.txtExtracted texttext/plain0https://repositorio.ufscar.br/bitstream/ufscar/5065/2/5978.pdf.txtd41d8cd98f00b204e9800998ecf8427eMD52THUMBNAIL5978.pdf.jpg5978.pdf.jpgIM Thumbnailimage/jpeg6072https://repositorio.ufscar.br/bitstream/ufscar/5065/3/5978.pdf.jpg2e18eb83092fd4553c1309967f979764MD53ufscar/50652023-09-18 18:31:35.542oai:repositorio.ufscar.br:ufscar/5065Repositório InstitucionalPUBhttps://repositorio.ufscar.br/oai/requestopendoar:43222023-09-18T18:31:35Repositório Institucional da UFSCAR - Universidade Federal de São Carlos (UFSCAR)false
dc.title.por.fl_str_mv Anelasticidade em titânio, tântalo e na liga Ti-40Ta
title Anelasticidade em titânio, tântalo e na liga Ti-40Ta
spellingShingle Anelasticidade em titânio, tântalo e na liga Ti-40Ta
Patricio, Marco Antonio Tito
Física da matéria condensada
Atrito interno
Ligas de titânio
Biomateriais
Módulo de elasticidade
Espectroscopia mecânica
Anelasticidade
Biomaterials
Titanium alloys
Mechanical spectroscopy
Elastic modulus
Anelasticity
CIENCIAS EXATAS E DA TERRA::FISICA
title_short Anelasticidade em titânio, tântalo e na liga Ti-40Ta
title_full Anelasticidade em titânio, tântalo e na liga Ti-40Ta
title_fullStr Anelasticidade em titânio, tântalo e na liga Ti-40Ta
title_full_unstemmed Anelasticidade em titânio, tântalo e na liga Ti-40Ta
title_sort Anelasticidade em titânio, tântalo e na liga Ti-40Ta
author Patricio, Marco Antonio Tito
author_facet Patricio, Marco Antonio Tito
author_role author
dc.contributor.authorlattes.por.fl_str_mv http://lattes.cnpq.br/2881221058860977
dc.contributor.author.fl_str_mv Patricio, Marco Antonio Tito
dc.contributor.advisor1.fl_str_mv Florêncio, Odila
dc.contributor.advisor1Lattes.fl_str_mv http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=E9418
dc.contributor.authorID.fl_str_mv 37b12463-6a5c-46cb-b1ab-f6eccf8598ab
contributor_str_mv Florêncio, Odila
dc.subject.por.fl_str_mv Física da matéria condensada
Atrito interno
Ligas de titânio
Biomateriais
Módulo de elasticidade
Espectroscopia mecânica
Anelasticidade
topic Física da matéria condensada
Atrito interno
Ligas de titânio
Biomateriais
Módulo de elasticidade
Espectroscopia mecânica
Anelasticidade
Biomaterials
Titanium alloys
Mechanical spectroscopy
Elastic modulus
Anelasticity
CIENCIAS EXATAS E DA TERRA::FISICA
dc.subject.eng.fl_str_mv Biomaterials
Titanium alloys
Mechanical spectroscopy
Elastic modulus
Anelasticity
dc.subject.cnpq.fl_str_mv CIENCIAS EXATAS E DA TERRA::FISICA
description The growing demand for increasingly resistant and biocompatible with the human body implantable materials, has led to an increase in demand for new metallic biomaterials. Some materials, such as titanium and its alloys, especially the Ti-6Al-4V, are widely used in the manufacture of orthopedic implants due to their excellent biocompatibility, high corrosion resistance and low density. However, the characteristics of these materials are not considered optimal, mainly because they have a high value of the elastic modulus when compared to the human bone. Include, that in the last decade studies have revealed diseases associated with elements such as Al and V, present in the alloy Ti-6Al-4V. Thus, it have looked for alternatives to the alloys used as biomaterials, still having one common element titanium, but having no toxic elements such as 𝛽 type titanium alloys, formed by non-toxic elements such as Nb, Ta, Zr, Mo and Sn has shown that lower values of modulus, greater fatigue resistance and corrosion resistance, exhibiting excellent biocompatibility. Accordingly, the alloys formed by Ti-Ta become promising candidates as biomaterials, since it has been observed that the content of Ta affects the value of the elastic modulus. For some compositions of this alloy, lower modulus values of this alloys that are currently used in biomedical applications were observed. However, the alloys formed by Ti-Ta still have properties that have been little studied. Thereby, the objectives of this master s project consist in getting the alloy Ti-40Ta and its characterization by means of the technique of mechanical spectroscopy, as of its elements that compose the alloy. The technique of mechanical spectroscopy to be non-destructive, it is widely used for providing the anelastic spectrum (oscillation frequency and internal friction as a function of temperature) is considered sensitive to phase transitions and dynamic processes, which are essential for understanding the structural changes occurring in these materials. This study was determined the dynamic elastic modulus for the pure Ti and Ta elements, and the Ti-40Ta through flexural vibrations. The elastic modulus found for the alloy at room temperature was (71 ± 5) GPa, which is in accordance with results available in the literature. The value of modulus of the alloy is lower when compared to the commercial biomedical alloys and is closer to that of human bone, which makes the alloy Ti-40Ta a potential candidate to be used in biomedical applications.
publishDate 2014
dc.date.available.fl_str_mv 2014-07-25
2016-06-02T20:16:53Z
dc.date.issued.fl_str_mv 2014-07-24
dc.date.accessioned.fl_str_mv 2016-06-02T20:16:53Z
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dc.identifier.citation.fl_str_mv PATRICIO, Marco Antonio Tito. Anelasticidade em titânio, tântalo e na liga Ti-40Ta. 2014. 88 f. Dissertação (Mestrado em Ciências Exatas e da Terra) - Universidade Federal de São Carlos, São Carlos, 2014.
dc.identifier.uri.fl_str_mv https://repositorio.ufscar.br/handle/ufscar/5065
identifier_str_mv PATRICIO, Marco Antonio Tito. Anelasticidade em titânio, tântalo e na liga Ti-40Ta. 2014. 88 f. Dissertação (Mestrado em Ciências Exatas e da Terra) - Universidade Federal de São Carlos, São Carlos, 2014.
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