Determination of trace metals in electrolytic copper by ICP OES and ICP-MS

Detalhes bibliográficos
Autor(a) principal: Santos,Éder José dos
Data de Publicação: 2005
Outros Autores: Herrmann,Amanda Beatriz, Olkuszewski,José Luiz, Saint'Pierre,Tatiana D., Curtius,Adilson José
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Brazilian Archives of Biology and Technology
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-89132005000600002
Resumo: The performance of axial view ICP OES and ICP-MS techniques were compared through the determination of As, Fe, Mn, Pb, Sb and Sn in electrolytic copper. Samples were prepared by two procedures: 1. Total dissolution with 5 % v/v HNO3 and 2. Dissolution with 1.4 % v/v HNO3 plus 2.0 % v/v H2SO4, followed by separation of the Cu by electrodeposition. The methods were applied for the analysis of standard copper solutions, using calibration against aqueous solutions with or without the addition of Cu. The results obtained by the two techniques were similar, but the separation of Cu from the sample matrix proved to be more adequate for practical reasons.
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spelling Determination of trace metals in electrolytic copper by ICP OES and ICP-MSICP-MSaxial view ICP OESelectrolytic copperelectrodepositionThe performance of axial view ICP OES and ICP-MS techniques were compared through the determination of As, Fe, Mn, Pb, Sb and Sn in electrolytic copper. Samples were prepared by two procedures: 1. Total dissolution with 5 % v/v HNO3 and 2. Dissolution with 1.4 % v/v HNO3 plus 2.0 % v/v H2SO4, followed by separation of the Cu by electrodeposition. The methods were applied for the analysis of standard copper solutions, using calibration against aqueous solutions with or without the addition of Cu. The results obtained by the two techniques were similar, but the separation of Cu from the sample matrix proved to be more adequate for practical reasons.Instituto de Tecnologia do Paraná - Tecpar2005-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-89132005000600002Brazilian Archives of Biology and Technology v.48 n.5 2005reponame:Brazilian Archives of Biology and Technologyinstname:Instituto de Tecnologia do Paraná (Tecpar)instacron:TECPAR10.1590/S1516-89132005000600002info:eu-repo/semantics/openAccessSantos,Éder José dosHerrmann,Amanda BeatrizOlkuszewski,José LuizSaint'Pierre,Tatiana D.Curtius,Adilson Joséeng2005-11-21T00:00:00Zoai:scielo:S1516-89132005000600002Revistahttps://www.scielo.br/j/babt/https://old.scielo.br/oai/scielo-oai.phpbabt@tecpar.br||babt@tecpar.br1678-43241516-8913opendoar:2005-11-21T00:00Brazilian Archives of Biology and Technology - Instituto de Tecnologia do Paraná (Tecpar)false
dc.title.none.fl_str_mv Determination of trace metals in electrolytic copper by ICP OES and ICP-MS
title Determination of trace metals in electrolytic copper by ICP OES and ICP-MS
spellingShingle Determination of trace metals in electrolytic copper by ICP OES and ICP-MS
Santos,Éder José dos
ICP-MS
axial view ICP OES
electrolytic copper
electrodeposition
title_short Determination of trace metals in electrolytic copper by ICP OES and ICP-MS
title_full Determination of trace metals in electrolytic copper by ICP OES and ICP-MS
title_fullStr Determination of trace metals in electrolytic copper by ICP OES and ICP-MS
title_full_unstemmed Determination of trace metals in electrolytic copper by ICP OES and ICP-MS
title_sort Determination of trace metals in electrolytic copper by ICP OES and ICP-MS
author Santos,Éder José dos
author_facet Santos,Éder José dos
Herrmann,Amanda Beatriz
Olkuszewski,José Luiz
Saint'Pierre,Tatiana D.
Curtius,Adilson José
author_role author
author2 Herrmann,Amanda Beatriz
Olkuszewski,José Luiz
Saint'Pierre,Tatiana D.
Curtius,Adilson José
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Santos,Éder José dos
Herrmann,Amanda Beatriz
Olkuszewski,José Luiz
Saint'Pierre,Tatiana D.
Curtius,Adilson José
dc.subject.por.fl_str_mv ICP-MS
axial view ICP OES
electrolytic copper
electrodeposition
topic ICP-MS
axial view ICP OES
electrolytic copper
electrodeposition
description The performance of axial view ICP OES and ICP-MS techniques were compared through the determination of As, Fe, Mn, Pb, Sb and Sn in electrolytic copper. Samples were prepared by two procedures: 1. Total dissolution with 5 % v/v HNO3 and 2. Dissolution with 1.4 % v/v HNO3 plus 2.0 % v/v H2SO4, followed by separation of the Cu by electrodeposition. The methods were applied for the analysis of standard copper solutions, using calibration against aqueous solutions with or without the addition of Cu. The results obtained by the two techniques were similar, but the separation of Cu from the sample matrix proved to be more adequate for practical reasons.
publishDate 2005
dc.date.none.fl_str_mv 2005-09-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-89132005000600002
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-89132005000600002
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S1516-89132005000600002
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Instituto de Tecnologia do Paraná - Tecpar
publisher.none.fl_str_mv Instituto de Tecnologia do Paraná - Tecpar
dc.source.none.fl_str_mv Brazilian Archives of Biology and Technology v.48 n.5 2005
reponame:Brazilian Archives of Biology and Technology
instname:Instituto de Tecnologia do Paraná (Tecpar)
instacron:TECPAR
instname_str Instituto de Tecnologia do Paraná (Tecpar)
instacron_str TECPAR
institution TECPAR
reponame_str Brazilian Archives of Biology and Technology
collection Brazilian Archives of Biology and Technology
repository.name.fl_str_mv Brazilian Archives of Biology and Technology - Instituto de Tecnologia do Paraná (Tecpar)
repository.mail.fl_str_mv babt@tecpar.br||babt@tecpar.br
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