Pesticide residues in Junca Onion (Allium fistulosum) cultivated in Risaralda, Colombia

Detalhes bibliográficos
Autor(a) principal: Velez, Juan Pablo Arrubla
Data de Publicação: 2020
Outros Autores: Pulgarín, Nathaly Villa, Betancur, Eddi Arsail Grisales, Bedoya, Jose Manuel Grisales, Benitez, Melissa Andrea Gómez, Álvarez, Gloria Edith Guerrero, Cuervo, Diego Paredes
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Semina. Ciências Agrárias (Online)
Texto Completo: https://ojs.uel.br/revistas/uel/index.php/semagrarias/article/view/36857
Resumo: By 2050, the world population will reach 9.2 billion, increasing the food demand by twice. Lowering loss due to pests is still challenging, where pesticides play an important role, but its indiscriminate use causes inadequate residual amounts to be present in foods. This study aims to monitor the organochlorine and organophosphorus pesticide residuality in Allium fistulosum cultivated in Risaralda, Colombia using gas chromatography - mass spectrometry (GC-MS). This method presented a highly sensitive (LOD: 0.11-7.15 µg kg-1), acceptable precision (RSD: 0.83-1.35%) and recoveries percentages between 46.32% - 118.67%. A greater presence of organochlorine pesticides banned or severely restricted by the Rotterdam agreement, such as 4,4'-DDT, was reported in samples of Allium fistulosum, with concentrations up to 221.22 ?g kg-1, while endrin with a concentration of 469.23 ?g kg-1 and its degradation products which exceed the maximum residue limite (MRL) for plant samples, reported by the Codex Alimentarius. According to this MRL, it was found that 73.1% of the samples have residual exceeding the allowed limit of organochlorine pesticides by more than forty times, posing a risk to human health and the ecosystem. Continuous monitoring and strict governmental control are required to reduce the exposure of humans and other living beings.
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spelling Pesticide residues in Junca Onion (Allium fistulosum) cultivated in Risaralda, ColombiaResíduos de pesticidas na Cebola Junca (Allium fistulosum) cultivada em Risaralda, ColômbiaAllium fistulosumChromatographyMROrganophosphorus pesticideOrganochlorine pesticide.Allium fistulosumCromatografiaPesticidas.By 2050, the world population will reach 9.2 billion, increasing the food demand by twice. Lowering loss due to pests is still challenging, where pesticides play an important role, but its indiscriminate use causes inadequate residual amounts to be present in foods. This study aims to monitor the organochlorine and organophosphorus pesticide residuality in Allium fistulosum cultivated in Risaralda, Colombia using gas chromatography - mass spectrometry (GC-MS). This method presented a highly sensitive (LOD: 0.11-7.15 µg kg-1), acceptable precision (RSD: 0.83-1.35%) and recoveries percentages between 46.32% - 118.67%. A greater presence of organochlorine pesticides banned or severely restricted by the Rotterdam agreement, such as 4,4'-DDT, was reported in samples of Allium fistulosum, with concentrations up to 221.22 ?g kg-1, while endrin with a concentration of 469.23 ?g kg-1 and its degradation products which exceed the maximum residue limite (MRL) for plant samples, reported by the Codex Alimentarius. According to this MRL, it was found that 73.1% of the samples have residual exceeding the allowed limit of organochlorine pesticides by more than forty times, posing a risk to human health and the ecosystem. Continuous monitoring and strict governmental control are required to reduce the exposure of humans and other living beings.Em 2050 a população mundial chegará a 9.2 bilhões, aumentando a demanda por alimentos em duas vezes. Diminuir as perdas devido a pragas ainda é um desafio, onde os pesticidas desempenham um papel importante, mas seu uso indiscriminado faz com que quantidades residuais inadequadas estejam presentes nos alimentos. Este estudo tem como objetivo monitorar a concentração residual de pesticidas organoclorados e organofosforados em cebola junca (Allium fistulosum) cultivada na Colômbia, como ou uso de GC-MS. O método usado tem alta sensibilidade (LOD: 0.11-7.15 µg kg-1), precisão aceitável precision (RSD: 0.83-1.35%) e percentagens de recuperações entre 46.32% - 118.67%. Pesticidas clorados proibidos pela Convenção de Roterdã foram encontrados nas amostras com concentrações acima de 221.22 ?g kg-1, enquanto endrin com uma concentração de 469.23 ?g kg-1 e seus produtos de degradação que excedem o limite máximo de resíduos (LMR) para amostras de plantas. De acordo com o LMR do Codex Alimentarius, constatou-se que 73.1% das amostras têm residual superior ao limite permitido de pesticidas organoclorados em mais de 40 vezes, o que representa um risco para a saúde humana e ecossistema. Monitoramento contínuo e rigoroso controle governamental são necessários para reduzir a exposição de seres humanos e outros seres vivos.UEL2020-08-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://ojs.uel.br/revistas/uel/index.php/semagrarias/article/view/3685710.5433/1679-0359.2020v41n5supl1p1875Semina: Ciências Agrárias; Vol. 41 No. 5supl1 (2020); 1875-1896Semina: Ciências Agrárias; v. 41 n. 5supl1 (2020); 1875-18961679-03591676-546Xreponame:Semina. Ciências Agrárias (Online)instname:Universidade Estadual de Londrina (UEL)instacron:UELenghttps://ojs.uel.br/revistas/uel/index.php/semagrarias/article/view/36857/27767Copyright (c) 2020 Semina: Ciências Agráriashttp://creativecommons.org/licenses/by-nc/4.0info:eu-repo/semantics/openAccessVelez, Juan Pablo ArrublaPulgarín, Nathaly VillaBetancur, Eddi Arsail GrisalesBedoya, Jose Manuel GrisalesBenitez, Melissa Andrea GómezÁlvarez, Gloria Edith GuerreroCuervo, Diego Paredes2022-10-07T12:37:15Zoai:ojs.pkp.sfu.ca:article/36857Revistahttp://www.uel.br/revistas/uel/index.php/semagrariasPUBhttps://ojs.uel.br/revistas/uel/index.php/semagrarias/oaisemina.agrarias@uel.br1679-03591676-546Xopendoar:2022-10-07T12:37:15Semina. Ciências Agrárias (Online) - Universidade Estadual de Londrina (UEL)false
dc.title.none.fl_str_mv Pesticide residues in Junca Onion (Allium fistulosum) cultivated in Risaralda, Colombia
Resíduos de pesticidas na Cebola Junca (Allium fistulosum) cultivada em Risaralda, Colômbia
title Pesticide residues in Junca Onion (Allium fistulosum) cultivated in Risaralda, Colombia
spellingShingle Pesticide residues in Junca Onion (Allium fistulosum) cultivated in Risaralda, Colombia
Velez, Juan Pablo Arrubla
Allium fistulosum
Chromatography
MR
Organophosphorus pesticide
Organochlorine pesticide.
Allium fistulosum
Cromatografia
Pesticidas.
title_short Pesticide residues in Junca Onion (Allium fistulosum) cultivated in Risaralda, Colombia
title_full Pesticide residues in Junca Onion (Allium fistulosum) cultivated in Risaralda, Colombia
title_fullStr Pesticide residues in Junca Onion (Allium fistulosum) cultivated in Risaralda, Colombia
title_full_unstemmed Pesticide residues in Junca Onion (Allium fistulosum) cultivated in Risaralda, Colombia
title_sort Pesticide residues in Junca Onion (Allium fistulosum) cultivated in Risaralda, Colombia
author Velez, Juan Pablo Arrubla
author_facet Velez, Juan Pablo Arrubla
Pulgarín, Nathaly Villa
Betancur, Eddi Arsail Grisales
Bedoya, Jose Manuel Grisales
Benitez, Melissa Andrea Gómez
Álvarez, Gloria Edith Guerrero
Cuervo, Diego Paredes
author_role author
author2 Pulgarín, Nathaly Villa
Betancur, Eddi Arsail Grisales
Bedoya, Jose Manuel Grisales
Benitez, Melissa Andrea Gómez
Álvarez, Gloria Edith Guerrero
Cuervo, Diego Paredes
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Velez, Juan Pablo Arrubla
Pulgarín, Nathaly Villa
Betancur, Eddi Arsail Grisales
Bedoya, Jose Manuel Grisales
Benitez, Melissa Andrea Gómez
Álvarez, Gloria Edith Guerrero
Cuervo, Diego Paredes
dc.subject.por.fl_str_mv Allium fistulosum
Chromatography
MR
Organophosphorus pesticide
Organochlorine pesticide.
Allium fistulosum
Cromatografia
Pesticidas.
topic Allium fistulosum
Chromatography
MR
Organophosphorus pesticide
Organochlorine pesticide.
Allium fistulosum
Cromatografia
Pesticidas.
description By 2050, the world population will reach 9.2 billion, increasing the food demand by twice. Lowering loss due to pests is still challenging, where pesticides play an important role, but its indiscriminate use causes inadequate residual amounts to be present in foods. This study aims to monitor the organochlorine and organophosphorus pesticide residuality in Allium fistulosum cultivated in Risaralda, Colombia using gas chromatography - mass spectrometry (GC-MS). This method presented a highly sensitive (LOD: 0.11-7.15 µg kg-1), acceptable precision (RSD: 0.83-1.35%) and recoveries percentages between 46.32% - 118.67%. A greater presence of organochlorine pesticides banned or severely restricted by the Rotterdam agreement, such as 4,4'-DDT, was reported in samples of Allium fistulosum, with concentrations up to 221.22 ?g kg-1, while endrin with a concentration of 469.23 ?g kg-1 and its degradation products which exceed the maximum residue limite (MRL) for plant samples, reported by the Codex Alimentarius. According to this MRL, it was found that 73.1% of the samples have residual exceeding the allowed limit of organochlorine pesticides by more than forty times, posing a risk to human health and the ecosystem. Continuous monitoring and strict governmental control are required to reduce the exposure of humans and other living beings.
publishDate 2020
dc.date.none.fl_str_mv 2020-08-07
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
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dc.identifier.uri.fl_str_mv https://ojs.uel.br/revistas/uel/index.php/semagrarias/article/view/36857
10.5433/1679-0359.2020v41n5supl1p1875
url https://ojs.uel.br/revistas/uel/index.php/semagrarias/article/view/36857
identifier_str_mv 10.5433/1679-0359.2020v41n5supl1p1875
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv https://ojs.uel.br/revistas/uel/index.php/semagrarias/article/view/36857/27767
dc.rights.driver.fl_str_mv Copyright (c) 2020 Semina: Ciências Agrárias
http://creativecommons.org/licenses/by-nc/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Copyright (c) 2020 Semina: Ciências Agrárias
http://creativecommons.org/licenses/by-nc/4.0
eu_rights_str_mv openAccess
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dc.publisher.none.fl_str_mv UEL
publisher.none.fl_str_mv UEL
dc.source.none.fl_str_mv Semina: Ciências Agrárias; Vol. 41 No. 5supl1 (2020); 1875-1896
Semina: Ciências Agrárias; v. 41 n. 5supl1 (2020); 1875-1896
1679-0359
1676-546X
reponame:Semina. Ciências Agrárias (Online)
instname:Universidade Estadual de Londrina (UEL)
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instname_str Universidade Estadual de Londrina (UEL)
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institution UEL
reponame_str Semina. Ciências Agrárias (Online)
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repository.name.fl_str_mv Semina. Ciências Agrárias (Online) - Universidade Estadual de Londrina (UEL)
repository.mail.fl_str_mv semina.agrarias@uel.br
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