Avaliação do processo de tratamento de água utilizando aassociação do coagulante natural Moringa oleifera LAM Ecoagulantes químicos

Detalhes bibliográficos
Autor(a) principal: Valverde, Karina Cardoso
Data de Publicação: 2014
Tipo de documento: Tese
Idioma: por
Título da fonte: Repositório Institucional da Universidade Estadual de Maringá (RI-UEM)
Texto Completo: http://repositorio.uem.br:8080/jspui/handle/1/3699
Resumo: The use of natural coagulants, such as Moringa oleifera Lam (M. oleifera) has been largely studied in order to produce a better quality of treated water, also reduce the use of chemical coagulants in the process. This study purpose to evaluate the process of coagulation/ flocculation, sedimentation and filtration using the association of natural and chemical coagulants: M. oleifera and ferric chloride, M. oleifera and aluminum polychloride (PAC), and M. oleifera and aluminum sulphate. In the tests it was used raw water provides from the Pirapo River basin, Maringa, PR, with an initial turbidity of about 70 NTU. Firstly, tests were conducted to evaluate the different methods of preparation of natural coagulant obtained from the M. oleifera seeds. After this, it was evaluated the degradation time of M. oleifera coagulant whole powder. Regarding the association of coagulants, the study of the optimization of operating conditions was performed in terms of coagulation/flocculation and sedimentation, such as: speed and mixing times and sedimentation. In order to build the coagulation diagrams, the pH ranged from clotting and the dosage of standard solution of natural and chemical coagulants. The descending fast filtration step using a double layer filter sand and anthracite were studied to evaluate the possibility to obtain potable water. Ingenerally, it can be considerate that the whole powder seeds of M. oleifera is a suitable natural coagulant and coagulant association, contributing significantly to reduce the quantity of chemical coagulants applied to the process. It has been observed that the mixing parameters affect the removal efficiency of the quality parameters. It has be found that the results obtained for the physical, chemical and microbiological characteristics of treated water were quite significant and consistent with the values required by the legislation (Ordinance no. 2914 of the Ministry of Health), including the trihalomethanes parameter. The association of M. oleifera coagulant and PAC showed better results in terms of residual values of apparent color, turbidity, compounds with absorption at UV254nm and dissolved organic carbon in comparison with other associations studied, which is related to the size of the particles formed and zeta potential. It is pertinent to mention that the use of 80% of M. oleifera with 20% chemical coagulant (ferric chloride, PAC or aluminum sulphate) are suitable for the production of drinking water, the operating conditions studied efficiencies obtained with removing around 99% for apparent color, 96% for turbidity and 89% for compounds with absorption at UV254nm. However, the disinfection step should be added to the process to ensure the absence of microrganisms. It can concluded that the use of M. oleifera as coagulant associated with ferric chloride, PAC or aluminum sulphate, in optimal conditions of the coagulation/flocculation, sedimentation and filtration process ensures removal efficiency of water quality parameters as well as the possibility of producing water with potability standards required by legislation
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spelling Avaliação do processo de tratamento de água utilizando aassociação do coagulante natural Moringa oleifera LAM Ecoagulantes químicosEvaluation of water treatment process using a association of natural coagulant moringa oleifera lam and chemicals coagulantsÁgua potávelTratamento de águaMoringa oleifera LamCoagulantes químicosBrasil.Moringa oleifera LamChemical coagulantsConventional water treatmentBrazil.EngenhariasEngenharia QuímicaThe use of natural coagulants, such as Moringa oleifera Lam (M. oleifera) has been largely studied in order to produce a better quality of treated water, also reduce the use of chemical coagulants in the process. This study purpose to evaluate the process of coagulation/ flocculation, sedimentation and filtration using the association of natural and chemical coagulants: M. oleifera and ferric chloride, M. oleifera and aluminum polychloride (PAC), and M. oleifera and aluminum sulphate. In the tests it was used raw water provides from the Pirapo River basin, Maringa, PR, with an initial turbidity of about 70 NTU. Firstly, tests were conducted to evaluate the different methods of preparation of natural coagulant obtained from the M. oleifera seeds. After this, it was evaluated the degradation time of M. oleifera coagulant whole powder. Regarding the association of coagulants, the study of the optimization of operating conditions was performed in terms of coagulation/flocculation and sedimentation, such as: speed and mixing times and sedimentation. In order to build the coagulation diagrams, the pH ranged from clotting and the dosage of standard solution of natural and chemical coagulants. The descending fast filtration step using a double layer filter sand and anthracite were studied to evaluate the possibility to obtain potable water. Ingenerally, it can be considerate that the whole powder seeds of M. oleifera is a suitable natural coagulant and coagulant association, contributing significantly to reduce the quantity of chemical coagulants applied to the process. It has been observed that the mixing parameters affect the removal efficiency of the quality parameters. It has be found that the results obtained for the physical, chemical and microbiological characteristics of treated water were quite significant and consistent with the values required by the legislation (Ordinance no. 2914 of the Ministry of Health), including the trihalomethanes parameter. The association of M. oleifera coagulant and PAC showed better results in terms of residual values of apparent color, turbidity, compounds with absorption at UV254nm and dissolved organic carbon in comparison with other associations studied, which is related to the size of the particles formed and zeta potential. It is pertinent to mention that the use of 80% of M. oleifera with 20% chemical coagulant (ferric chloride, PAC or aluminum sulphate) are suitable for the production of drinking water, the operating conditions studied efficiencies obtained with removing around 99% for apparent color, 96% for turbidity and 89% for compounds with absorption at UV254nm. However, the disinfection step should be added to the process to ensure the absence of microrganisms. It can concluded that the use of M. oleifera as coagulant associated with ferric chloride, PAC or aluminum sulphate, in optimal conditions of the coagulation/flocculation, sedimentation and filtration process ensures removal efficiency of water quality parameters as well as the possibility of producing water with potability standards required by legislationA utilização de coagulantes naturais, tais como a Moringa oleifera Lam tem sido amplamente estudada com a finalidade de produzir àgua tratada de melhor qualidade, além de diminuir a utilização de produtos químicos no processo. Assim, este trabalho tem como objetivo avaliar o processo de coagulação/floculação, sedimentação e filtração utilizando a associação dos coagulantes natural e químico: M. oleifera e cloreto ferrico, M. oleifera e policloreto de alumínio (PAC), e M. oleifera e sulfato de alumínio. Nos ensaios, a àgua de estudo utilizada era proveniente da Bacia do Rio Pirapó, Maringá, PR, com turbidez inicial em torno de 70 UNT. Primeiramente, foram realizados ensaios a fim de avaliar os diferentes métodos de preparo do coagulante natural obtido a partir das sementes de M. oleifera. Após, foi avaliado o tempo de degradação do coagulante M. oleifera em pó integral. Em relação a associação dos coagulantes, foi realizado o estudo da otimização das condições de operação na etapa de coagulação/floculação e sedimentação, tais como: velocidades e tempos de mistura e sedimentação. A fim de construir os diagramas de coagulação, variou-se o pH de coagulação e a dosagem da solução padrão dos coagulantes natural e químicos. A etapa de filtração rápida descendente, com a utilização de um filtro de camada dupla (areia e antracito) foi estudada a fim de avaliar se e possível obter àgua potável. De um modo geral, pode-se considerar que o pó integral das sementes de M. oleifera e um propicio coagulante natural e na associação dos coagulantes, contribuiu significativamente para a redução da quantidade de coagulantes químicos aplicados ao processo. Verificou-se também que os parâmetros de mistura afetam a eficiência de remoção dos parâmetros de qualidade. Pode-se verificar que os resultados obtidos para a caracterização físico, química e microbiologica da àgua tratada foram bastante expressivos e condizem com os valores solicitados pela legislação (Portaria no. 2914 do Ministério da Saúde), inclusive para o parâmetro trihalometanos. A associação dos coagulantes M. oleifera e PAC apresentou melhores resultados em termos de valores residuais de cor aparente, turbidez, compostos com absorção em UV254nm e COD, em comparação com as demais associações estudadas, o que esta relacionado ao tamanho das particulas formadas e ao potencial zeta. E pertinente citar que a utilização de 80% de M. oleifera com 20% de coagulante químico (cloreto ferrico, PAC, ou sulfato de alumínio) são indicadas para a obtenção de àgua potável, nas condições de operação estudadas, sendo obtidas eficiencias de remoção em torno de 99% para cor aparente, 96% para turbidez e 89% para compostos com absorção em UV254nm. Contudo, a etapa de desinfecção deve ser acrescentada ao processo, a fim de garantir a ausência de microrganismos. Conclui-se, então, que a utilização da M. oleifera como coagulante associada ao cloreto ferrico, PAC ou sulfato de alumínio, nas condições otimas do processo de coagulação/floculação, sedimentação e filtração, garantem a eficiência de remoção dos parâmetros de qualidade da àgua, assim como a possibilidade de produção de àgua com o devido padrão de potabilidade exigido pela legislação.Universidade Estadual de MaringáBrasilUEMMaringá, PRRosângela BergamascoOnélia Aparecida Andreo dos Santos [Orientador] - UEMLucila Adriani Coral - UTFPRGrasiele Scaramal Madrona - UEMValverde, Karina Cardoso2018-04-17T17:40:00Z2018-04-17T17:40:00Z2014info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesishttp://repositorio.uem.br:8080/jspui/handle/1/3699porinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da Universidade Estadual de Maringá (RI-UEM)instname:Universidade Estadual de Maringá (UEM)instacron:UEM2018-05-15T19:01:34Zoai:localhost:1/3699Repositório InstitucionalPUBhttp://repositorio.uem.br:8080/oai/requestopendoar:2024-04-23T14:56:51.086367Repositório Institucional da Universidade Estadual de Maringá (RI-UEM) - Universidade Estadual de Maringá (UEM)false
dc.title.none.fl_str_mv Avaliação do processo de tratamento de água utilizando aassociação do coagulante natural Moringa oleifera LAM Ecoagulantes químicos
Evaluation of water treatment process using a association of natural coagulant moringa oleifera lam and chemicals coagulants
title Avaliação do processo de tratamento de água utilizando aassociação do coagulante natural Moringa oleifera LAM Ecoagulantes químicos
spellingShingle Avaliação do processo de tratamento de água utilizando aassociação do coagulante natural Moringa oleifera LAM Ecoagulantes químicos
Valverde, Karina Cardoso
Água potável
Tratamento de água
Moringa oleifera Lam
Coagulantes químicos
Brasil.
Moringa oleifera Lam
Chemical coagulants
Conventional water treatment
Brazil.
Engenharias
Engenharia Química
title_short Avaliação do processo de tratamento de água utilizando aassociação do coagulante natural Moringa oleifera LAM Ecoagulantes químicos
title_full Avaliação do processo de tratamento de água utilizando aassociação do coagulante natural Moringa oleifera LAM Ecoagulantes químicos
title_fullStr Avaliação do processo de tratamento de água utilizando aassociação do coagulante natural Moringa oleifera LAM Ecoagulantes químicos
title_full_unstemmed Avaliação do processo de tratamento de água utilizando aassociação do coagulante natural Moringa oleifera LAM Ecoagulantes químicos
title_sort Avaliação do processo de tratamento de água utilizando aassociação do coagulante natural Moringa oleifera LAM Ecoagulantes químicos
author Valverde, Karina Cardoso
author_facet Valverde, Karina Cardoso
author_role author
dc.contributor.none.fl_str_mv Rosângela Bergamasco
Onélia Aparecida Andreo dos Santos [Orientador] - UEM
Lucila Adriani Coral - UTFPR
Grasiele Scaramal Madrona - UEM
dc.contributor.author.fl_str_mv Valverde, Karina Cardoso
dc.subject.por.fl_str_mv Água potável
Tratamento de água
Moringa oleifera Lam
Coagulantes químicos
Brasil.
Moringa oleifera Lam
Chemical coagulants
Conventional water treatment
Brazil.
Engenharias
Engenharia Química
topic Água potável
Tratamento de água
Moringa oleifera Lam
Coagulantes químicos
Brasil.
Moringa oleifera Lam
Chemical coagulants
Conventional water treatment
Brazil.
Engenharias
Engenharia Química
description The use of natural coagulants, such as Moringa oleifera Lam (M. oleifera) has been largely studied in order to produce a better quality of treated water, also reduce the use of chemical coagulants in the process. This study purpose to evaluate the process of coagulation/ flocculation, sedimentation and filtration using the association of natural and chemical coagulants: M. oleifera and ferric chloride, M. oleifera and aluminum polychloride (PAC), and M. oleifera and aluminum sulphate. In the tests it was used raw water provides from the Pirapo River basin, Maringa, PR, with an initial turbidity of about 70 NTU. Firstly, tests were conducted to evaluate the different methods of preparation of natural coagulant obtained from the M. oleifera seeds. After this, it was evaluated the degradation time of M. oleifera coagulant whole powder. Regarding the association of coagulants, the study of the optimization of operating conditions was performed in terms of coagulation/flocculation and sedimentation, such as: speed and mixing times and sedimentation. In order to build the coagulation diagrams, the pH ranged from clotting and the dosage of standard solution of natural and chemical coagulants. The descending fast filtration step using a double layer filter sand and anthracite were studied to evaluate the possibility to obtain potable water. Ingenerally, it can be considerate that the whole powder seeds of M. oleifera is a suitable natural coagulant and coagulant association, contributing significantly to reduce the quantity of chemical coagulants applied to the process. It has been observed that the mixing parameters affect the removal efficiency of the quality parameters. It has be found that the results obtained for the physical, chemical and microbiological characteristics of treated water were quite significant and consistent with the values required by the legislation (Ordinance no. 2914 of the Ministry of Health), including the trihalomethanes parameter. The association of M. oleifera coagulant and PAC showed better results in terms of residual values of apparent color, turbidity, compounds with absorption at UV254nm and dissolved organic carbon in comparison with other associations studied, which is related to the size of the particles formed and zeta potential. It is pertinent to mention that the use of 80% of M. oleifera with 20% chemical coagulant (ferric chloride, PAC or aluminum sulphate) are suitable for the production of drinking water, the operating conditions studied efficiencies obtained with removing around 99% for apparent color, 96% for turbidity and 89% for compounds with absorption at UV254nm. However, the disinfection step should be added to the process to ensure the absence of microrganisms. It can concluded that the use of M. oleifera as coagulant associated with ferric chloride, PAC or aluminum sulphate, in optimal conditions of the coagulation/flocculation, sedimentation and filtration process ensures removal efficiency of water quality parameters as well as the possibility of producing water with potability standards required by legislation
publishDate 2014
dc.date.none.fl_str_mv 2014
2018-04-17T17:40:00Z
2018-04-17T17:40:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
format doctoralThesis
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://repositorio.uem.br:8080/jspui/handle/1/3699
url http://repositorio.uem.br:8080/jspui/handle/1/3699
dc.language.iso.fl_str_mv por
language por
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Universidade Estadual de Maringá
Brasil
UEM
Maringá, PR
publisher.none.fl_str_mv Universidade Estadual de Maringá
Brasil
UEM
Maringá, PR
dc.source.none.fl_str_mv reponame:Repositório Institucional da Universidade Estadual de Maringá (RI-UEM)
instname:Universidade Estadual de Maringá (UEM)
instacron:UEM
instname_str Universidade Estadual de Maringá (UEM)
instacron_str UEM
institution UEM
reponame_str Repositório Institucional da Universidade Estadual de Maringá (RI-UEM)
collection Repositório Institucional da Universidade Estadual de Maringá (RI-UEM)
repository.name.fl_str_mv Repositório Institucional da Universidade Estadual de Maringá (RI-UEM) - Universidade Estadual de Maringá (UEM)
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