Thermodynamic properties of water desorption of forage turnip seeds
Autor(a) principal: | |
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Data de Publicação: | 2014 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Acta Scientiarum. Agronomy (Online) |
Texto Completo: | http://www.periodicos.uem.br/ojs/index.php/ActaSciAgron/article/view/19333 |
Resumo: | The purpose of this study was to determine the thermodynamic properties of the process of water sorption in forage turnip seeds. The equilibrium moisture content of forage turnip seeds was determined by the gravimetric-dynamic method for different values of temperature and water activity. According to the results, increasing the moisture content increases the energy required for the evaporation of water in forage turnip seeds, and the values of integral isosteric heat of desorption, within the moisture content range of 3.33 to 11.30 (% d.b.), varies from 4,222.70 to 2,870.34 kJ kg-1. With the elevation in the equilibrium moisture content, there is an increase in differential entropy and Gibbs free energy, which has positive values, demonstrating non-spontaneity in the process of desorption in the seeds. The theory of enthalpy-entropy compensation can be satisfactorily applied to the sorption phenomenon, and the process of water desorption of forage turnip seeds is controlled by enthalpy. |
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Acta Scientiarum. Agronomy (Online) |
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Thermodynamic properties of water desorption of forage turnip seedshygroscopic equilibriumisosteric heatgibbs free energycompensation theoryThe purpose of this study was to determine the thermodynamic properties of the process of water sorption in forage turnip seeds. The equilibrium moisture content of forage turnip seeds was determined by the gravimetric-dynamic method for different values of temperature and water activity. According to the results, increasing the moisture content increases the energy required for the evaporation of water in forage turnip seeds, and the values of integral isosteric heat of desorption, within the moisture content range of 3.33 to 11.30 (% d.b.), varies from 4,222.70 to 2,870.34 kJ kg-1. With the elevation in the equilibrium moisture content, there is an increase in differential entropy and Gibbs free energy, which has positive values, demonstrating non-spontaneity in the process of desorption in the seeds. The theory of enthalpy-entropy compensation can be satisfactorily applied to the sorption phenomenon, and the process of water desorption of forage turnip seeds is controlled by enthalpy. Universidade Estadual de Maringá2014-11-25info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfimage/jpegapplication/pdfhttp://www.periodicos.uem.br/ojs/index.php/ActaSciAgron/article/view/1933310.4025/actasciagron.v37i1.19333Acta Scientiarum. Agronomy; Vol 37 No 1 (2015); 11-19Acta Scientiarum. Agronomy; v. 37 n. 1 (2015); 11-191807-86211679-9275reponame:Acta Scientiarum. Agronomy (Online)instname:Universidade Estadual de Maringá (UEM)instacron:UEMenghttp://www.periodicos.uem.br/ojs/index.php/ActaSciAgron/article/view/19333/pdf_47http://www.periodicos.uem.br/ojs/index.php/ActaSciAgron/article/view/19333/751375142007http://www.periodicos.uem.br/ojs/index.php/ActaSciAgron/article/view/19333/751375142008Sousa, Kelly AparecidaResende, OsvaldoGoneli, André Luis DuarteSmaniotto, Thaís Adriana de SouzaOliveira, Daniel Emanuel Cabral deinfo:eu-repo/semantics/openAccess2015-01-15T15:03:22Zoai:periodicos.uem.br/ojs:article/19333Revistahttp://www.periodicos.uem.br/ojs/index.php/ActaSciAgronPUBhttp://www.periodicos.uem.br/ojs/index.php/ActaSciAgron/oaiactaagron@uem.br||actaagron@uem.br|| edamasio@uem.br1807-86211679-9275opendoar:2015-01-15T15:03:22Acta Scientiarum. Agronomy (Online) - Universidade Estadual de Maringá (UEM)false |
dc.title.none.fl_str_mv |
Thermodynamic properties of water desorption of forage turnip seeds |
title |
Thermodynamic properties of water desorption of forage turnip seeds |
spellingShingle |
Thermodynamic properties of water desorption of forage turnip seeds Sousa, Kelly Aparecida hygroscopic equilibrium isosteric heat gibbs free energy compensation theory |
title_short |
Thermodynamic properties of water desorption of forage turnip seeds |
title_full |
Thermodynamic properties of water desorption of forage turnip seeds |
title_fullStr |
Thermodynamic properties of water desorption of forage turnip seeds |
title_full_unstemmed |
Thermodynamic properties of water desorption of forage turnip seeds |
title_sort |
Thermodynamic properties of water desorption of forage turnip seeds |
author |
Sousa, Kelly Aparecida |
author_facet |
Sousa, Kelly Aparecida Resende, Osvaldo Goneli, André Luis Duarte Smaniotto, Thaís Adriana de Souza Oliveira, Daniel Emanuel Cabral de |
author_role |
author |
author2 |
Resende, Osvaldo Goneli, André Luis Duarte Smaniotto, Thaís Adriana de Souza Oliveira, Daniel Emanuel Cabral de |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Sousa, Kelly Aparecida Resende, Osvaldo Goneli, André Luis Duarte Smaniotto, Thaís Adriana de Souza Oliveira, Daniel Emanuel Cabral de |
dc.subject.por.fl_str_mv |
hygroscopic equilibrium isosteric heat gibbs free energy compensation theory |
topic |
hygroscopic equilibrium isosteric heat gibbs free energy compensation theory |
description |
The purpose of this study was to determine the thermodynamic properties of the process of water sorption in forage turnip seeds. The equilibrium moisture content of forage turnip seeds was determined by the gravimetric-dynamic method for different values of temperature and water activity. According to the results, increasing the moisture content increases the energy required for the evaporation of water in forage turnip seeds, and the values of integral isosteric heat of desorption, within the moisture content range of 3.33 to 11.30 (% d.b.), varies from 4,222.70 to 2,870.34 kJ kg-1. With the elevation in the equilibrium moisture content, there is an increase in differential entropy and Gibbs free energy, which has positive values, demonstrating non-spontaneity in the process of desorption in the seeds. The theory of enthalpy-entropy compensation can be satisfactorily applied to the sorption phenomenon, and the process of water desorption of forage turnip seeds is controlled by enthalpy. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-11-25 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciAgron/article/view/19333 10.4025/actasciagron.v37i1.19333 |
url |
http://www.periodicos.uem.br/ojs/index.php/ActaSciAgron/article/view/19333 |
identifier_str_mv |
10.4025/actasciagron.v37i1.19333 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciAgron/article/view/19333/pdf_47 http://www.periodicos.uem.br/ojs/index.php/ActaSciAgron/article/view/19333/751375142007 http://www.periodicos.uem.br/ojs/index.php/ActaSciAgron/article/view/19333/751375142008 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf image/jpeg application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Estadual de Maringá |
publisher.none.fl_str_mv |
Universidade Estadual de Maringá |
dc.source.none.fl_str_mv |
Acta Scientiarum. Agronomy; Vol 37 No 1 (2015); 11-19 Acta Scientiarum. Agronomy; v. 37 n. 1 (2015); 11-19 1807-8621 1679-9275 reponame:Acta Scientiarum. Agronomy (Online) instname:Universidade Estadual de Maringá (UEM) instacron:UEM |
instname_str |
Universidade Estadual de Maringá (UEM) |
instacron_str |
UEM |
institution |
UEM |
reponame_str |
Acta Scientiarum. Agronomy (Online) |
collection |
Acta Scientiarum. Agronomy (Online) |
repository.name.fl_str_mv |
Acta Scientiarum. Agronomy (Online) - Universidade Estadual de Maringá (UEM) |
repository.mail.fl_str_mv |
actaagron@uem.br||actaagron@uem.br|| edamasio@uem.br |
_version_ |
1799305909291188224 |