Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil - doi: 10.4025/actascitechnol.v34i2.12797
Autor(a) principal: | |
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Data de Publicação: | 2011 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | por eng |
Título da fonte: | Acta scientiarum. Technology (Online) |
DOI: | 10.4025/actascitechnol.v34i2.12797 |
Texto Completo: | http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/12797 |
Resumo: | Biodiesel has been obtained from methanolysis of buriti oil. This biodiesel was added in fossil diesel in order to obtain diesel/biodiesel blends. Thermal analysis of blends were carried on 30-600oC range at rate of 10oC min.-1. Kinetic parameters such as activation energy (Ea), pre-exponential factor (A), Gibbs energy (Δ≠G), enthalpy (Δ≠H) and entropy (Δ≠S) of activation were determined by using Coats–Redfern equation. The Ea, Δ≠H and Δ≠G values presented a linear increase with biodiesel amount added in blends. The heat of combustion of diesel/biodiesel blends was determined, and it was observed that the heat of combustion decreased with the addition of biodiesel in diesel/biodiesel blends. |
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Acta scientiarum. Technology (Online) |
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Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil - doi: 10.4025/actascitechnol.v34i2.12797transesterificationvegetable oilsthermogravimetric evaluationTermodinamica quimicaBiodiesel has been obtained from methanolysis of buriti oil. This biodiesel was added in fossil diesel in order to obtain diesel/biodiesel blends. Thermal analysis of blends were carried on 30-600oC range at rate of 10oC min.-1. Kinetic parameters such as activation energy (Ea), pre-exponential factor (A), Gibbs energy (Δ≠G), enthalpy (Δ≠H) and entropy (Δ≠S) of activation were determined by using Coats–Redfern equation. The Ea, Δ≠H and Δ≠G values presented a linear increase with biodiesel amount added in blends. The heat of combustion of diesel/biodiesel blends was determined, and it was observed that the heat of combustion decreased with the addition of biodiesel in diesel/biodiesel blends.Universidade Estadual De Maringá2011-11-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionTransesterificationapplication/pdfapplication/pdfhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/1279710.4025/actascitechnol.v34i2.12797Acta Scientiarum. Technology; Vol 34 No 2 (2012); 243-248Acta Scientiarum. Technology; v. 34 n. 2 (2012); 243-2481806-25631807-8664reponame:Acta scientiarum. Technology (Online)instname:Universidade Estadual de Maringá (UEM)instacron:UEMporenghttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/12797/pdf1http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/12797/pdf0Albuquerque Andrade, Rômulo DaviPozzebom, EllenFaria, Elaine AlvesDantas Filho, FranciscoSuarez, Paulo Anselmo ZianiPrado, Alexandre Gustavo Soares doinfo:eu-repo/semantics/openAccess2024-05-17T13:03:23Zoai:periodicos.uem.br/ojs:article/12797Revistahttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/indexPUBhttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/oai||actatech@uem.br1807-86641806-2563opendoar:2024-05-17T13:03:23Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM)false |
dc.title.none.fl_str_mv |
Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil - doi: 10.4025/actascitechnol.v34i2.12797 |
title |
Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil - doi: 10.4025/actascitechnol.v34i2.12797 |
spellingShingle |
Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil - doi: 10.4025/actascitechnol.v34i2.12797 Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil - doi: 10.4025/actascitechnol.v34i2.12797 Albuquerque Andrade, Rômulo Davi transesterification vegetable oils thermogravimetric evaluation Termodinamica quimica Albuquerque Andrade, Rômulo Davi transesterification vegetable oils thermogravimetric evaluation Termodinamica quimica |
title_short |
Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil - doi: 10.4025/actascitechnol.v34i2.12797 |
title_full |
Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil - doi: 10.4025/actascitechnol.v34i2.12797 |
title_fullStr |
Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil - doi: 10.4025/actascitechnol.v34i2.12797 Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil - doi: 10.4025/actascitechnol.v34i2.12797 |
title_full_unstemmed |
Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil - doi: 10.4025/actascitechnol.v34i2.12797 Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil - doi: 10.4025/actascitechnol.v34i2.12797 |
title_sort |
Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil - doi: 10.4025/actascitechnol.v34i2.12797 |
author |
Albuquerque Andrade, Rômulo Davi |
author_facet |
Albuquerque Andrade, Rômulo Davi Albuquerque Andrade, Rômulo Davi Pozzebom, Ellen Faria, Elaine Alves Dantas Filho, Francisco Suarez, Paulo Anselmo Ziani Prado, Alexandre Gustavo Soares do Pozzebom, Ellen Faria, Elaine Alves Dantas Filho, Francisco Suarez, Paulo Anselmo Ziani Prado, Alexandre Gustavo Soares do |
author_role |
author |
author2 |
Pozzebom, Ellen Faria, Elaine Alves Dantas Filho, Francisco Suarez, Paulo Anselmo Ziani Prado, Alexandre Gustavo Soares do |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Albuquerque Andrade, Rômulo Davi Pozzebom, Ellen Faria, Elaine Alves Dantas Filho, Francisco Suarez, Paulo Anselmo Ziani Prado, Alexandre Gustavo Soares do |
dc.subject.por.fl_str_mv |
transesterification vegetable oils thermogravimetric evaluation Termodinamica quimica |
topic |
transesterification vegetable oils thermogravimetric evaluation Termodinamica quimica |
description |
Biodiesel has been obtained from methanolysis of buriti oil. This biodiesel was added in fossil diesel in order to obtain diesel/biodiesel blends. Thermal analysis of blends were carried on 30-600oC range at rate of 10oC min.-1. Kinetic parameters such as activation energy (Ea), pre-exponential factor (A), Gibbs energy (Δ≠G), enthalpy (Δ≠H) and entropy (Δ≠S) of activation were determined by using Coats–Redfern equation. The Ea, Δ≠H and Δ≠G values presented a linear increase with biodiesel amount added in blends. The heat of combustion of diesel/biodiesel blends was determined, and it was observed that the heat of combustion decreased with the addition of biodiesel in diesel/biodiesel blends. |
publishDate |
2011 |
dc.date.none.fl_str_mv |
2011-11-09 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Transesterification |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/12797 10.4025/actascitechnol.v34i2.12797 |
url |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/12797 |
identifier_str_mv |
10.4025/actascitechnol.v34i2.12797 |
dc.language.iso.fl_str_mv |
por eng |
language |
por eng |
dc.relation.none.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/12797/pdf1 http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/12797/pdf0 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Estadual De Maringá |
publisher.none.fl_str_mv |
Universidade Estadual De Maringá |
dc.source.none.fl_str_mv |
Acta Scientiarum. Technology; Vol 34 No 2 (2012); 243-248 Acta Scientiarum. Technology; v. 34 n. 2 (2012); 243-248 1806-2563 1807-8664 reponame:Acta scientiarum. Technology (Online) instname:Universidade Estadual de Maringá (UEM) instacron:UEM |
instname_str |
Universidade Estadual de Maringá (UEM) |
instacron_str |
UEM |
institution |
UEM |
reponame_str |
Acta scientiarum. Technology (Online) |
collection |
Acta scientiarum. Technology (Online) |
repository.name.fl_str_mv |
Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM) |
repository.mail.fl_str_mv |
||actatech@uem.br |
_version_ |
1822182870008987648 |
dc.identifier.doi.none.fl_str_mv |
10.4025/actascitechnol.v34i2.12797 |