Phenol degradation evaluation by direct and sensitized photocatalysis - DOI: 10.4025/actascitechnol.v28i2.1189
Autor(a) principal: | |
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Data de Publicação: | 2008 |
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Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Acta scientiarum. Technology (Online) |
Texto Completo: | http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/1189 |
Resumo: | The influence of the VIS or UV irradiation was evaluated on the phenol photocatalytic degradation in different experimental conditions. Tests with TiO2 as photocatalyst were carried out during 5h, in which parameters as irradiation, aeration, mass of TiO2 and initial concentration of phenol were changed. The textural analysis and XRD results showed that the TiO2 is a mesoporous material and it is constituted of a rutile and anatase phase mixture. The photodegradation tests showed that the sensitized photocatalysis was much slower than the direct photocatalysis, that it was much easier to degrade diluted solutions and that the oxygen presence had no influence on the process efficiency |
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Phenol degradation evaluation by direct and sensitized photocatalysis - DOI: 10.4025/actascitechnol.v28i2.1189Avaliação da degradação de fenol via fotocatálise direta e sensibilizada - DOI: 10.4025/actascitechnol.v28i2.1189fotocatálise direta e sensibilizadacompostos fenólicosTiO23.06.00.00-6 Engenharia QuímicaThe influence of the VIS or UV irradiation was evaluated on the phenol photocatalytic degradation in different experimental conditions. Tests with TiO2 as photocatalyst were carried out during 5h, in which parameters as irradiation, aeration, mass of TiO2 and initial concentration of phenol were changed. The textural analysis and XRD results showed that the TiO2 is a mesoporous material and it is constituted of a rutile and anatase phase mixture. The photodegradation tests showed that the sensitized photocatalysis was much slower than the direct photocatalysis, that it was much easier to degrade diluted solutions and that the oxygen presence had no influence on the process efficiencyA influência do tipo de irradiação, VIS ou UV, foi avaliada na degradação fotocatalítica do fenol em diferentes condições operacionais. Testes com TiO2 como fotocatalisador foram realizados durante 5h, nos quais parâmetros como irradiação, aeração, massa de TiO2 e concentração inicial de fenol foram variados. Os resultados de análise textural e DRX mostraram que o TiO2 é um material mesoporoso e constituído de uma mistura das fases rutile e anatase. Os testes de fotodegradação mostraram que a fotocatálise sensibilizada foi muito mais lenta que a fotocatálise direta, que foi muito mais fácil degradar soluções diluídas e que a presença de oxigênio não influenciou a eficiência do processoUniversidade Estadual De Maringá2008-03-20info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/118910.4025/actascitechnol.v28i2.1189Acta Scientiarum. Technology; Vol 28 No 2 (2006); 155-163Acta Scientiarum. Technology; v. 28 n. 2 (2006); 155-1631806-25631807-8664reponame:Acta scientiarum. Technology (Online)instname:Universidade Estadual de Maringá (UEM)instacron:UEMporhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/1189/701Santana, Veronice SlusarskiMachado, Nádia Regina Camardo Fernandesinfo:eu-repo/semantics/openAccess2024-05-17T13:02:32Zoai:periodicos.uem.br/ojs:article/1189Revistahttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/indexPUBhttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/oai||actatech@uem.br1807-86641806-2563opendoar:2024-05-17T13:02:32Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM)false |
dc.title.none.fl_str_mv |
Phenol degradation evaluation by direct and sensitized photocatalysis - DOI: 10.4025/actascitechnol.v28i2.1189 Avaliação da degradação de fenol via fotocatálise direta e sensibilizada - DOI: 10.4025/actascitechnol.v28i2.1189 |
title |
Phenol degradation evaluation by direct and sensitized photocatalysis - DOI: 10.4025/actascitechnol.v28i2.1189 |
spellingShingle |
Phenol degradation evaluation by direct and sensitized photocatalysis - DOI: 10.4025/actascitechnol.v28i2.1189 Santana, Veronice Slusarski fotocatálise direta e sensibilizada compostos fenólicos TiO2 3.06.00.00-6 Engenharia Química |
title_short |
Phenol degradation evaluation by direct and sensitized photocatalysis - DOI: 10.4025/actascitechnol.v28i2.1189 |
title_full |
Phenol degradation evaluation by direct and sensitized photocatalysis - DOI: 10.4025/actascitechnol.v28i2.1189 |
title_fullStr |
Phenol degradation evaluation by direct and sensitized photocatalysis - DOI: 10.4025/actascitechnol.v28i2.1189 |
title_full_unstemmed |
Phenol degradation evaluation by direct and sensitized photocatalysis - DOI: 10.4025/actascitechnol.v28i2.1189 |
title_sort |
Phenol degradation evaluation by direct and sensitized photocatalysis - DOI: 10.4025/actascitechnol.v28i2.1189 |
author |
Santana, Veronice Slusarski |
author_facet |
Santana, Veronice Slusarski Machado, Nádia Regina Camardo Fernandes |
author_role |
author |
author2 |
Machado, Nádia Regina Camardo Fernandes |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Santana, Veronice Slusarski Machado, Nádia Regina Camardo Fernandes |
dc.subject.por.fl_str_mv |
fotocatálise direta e sensibilizada compostos fenólicos TiO2 3.06.00.00-6 Engenharia Química |
topic |
fotocatálise direta e sensibilizada compostos fenólicos TiO2 3.06.00.00-6 Engenharia Química |
description |
The influence of the VIS or UV irradiation was evaluated on the phenol photocatalytic degradation in different experimental conditions. Tests with TiO2 as photocatalyst were carried out during 5h, in which parameters as irradiation, aeration, mass of TiO2 and initial concentration of phenol were changed. The textural analysis and XRD results showed that the TiO2 is a mesoporous material and it is constituted of a rutile and anatase phase mixture. The photodegradation tests showed that the sensitized photocatalysis was much slower than the direct photocatalysis, that it was much easier to degrade diluted solutions and that the oxygen presence had no influence on the process efficiency |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-03-20 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/1189 10.4025/actascitechnol.v28i2.1189 |
url |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/1189 |
identifier_str_mv |
10.4025/actascitechnol.v28i2.1189 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/1189/701 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Estadual De Maringá |
publisher.none.fl_str_mv |
Universidade Estadual De Maringá |
dc.source.none.fl_str_mv |
Acta Scientiarum. Technology; Vol 28 No 2 (2006); 155-163 Acta Scientiarum. Technology; v. 28 n. 2 (2006); 155-163 1806-2563 1807-8664 reponame:Acta scientiarum. Technology (Online) instname:Universidade Estadual de Maringá (UEM) instacron:UEM |
instname_str |
Universidade Estadual de Maringá (UEM) |
instacron_str |
UEM |
institution |
UEM |
reponame_str |
Acta scientiarum. Technology (Online) |
collection |
Acta scientiarum. Technology (Online) |
repository.name.fl_str_mv |
Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM) |
repository.mail.fl_str_mv |
||actatech@uem.br |
_version_ |
1799315331525640192 |