Simple and efficient assembly for preparative photochemistry

Detalhes bibliográficos
Autor(a) principal: Federman Neto, Alberto
Data de Publicação: 2008
Outros Autores: Silva, Flávia Cristina, Esteves Dias, Cíntia Arisse, Daltin Júnior, Nereu, Vichnewski, Valter, Bonilha, João Batista Sargi, Borges, Áurea Donizete Lanchote
Tipo de documento: Artigo
Idioma: por
Título da fonte: Acta scientiarum. Technology (Online)
Texto Completo: http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/2459
Resumo: A simplified and efficient assembly for the preparative photochemistry is described. The apparatus was tested in some classical organic photochemical reactions such as photobleaching of riboflavin, and photo reduction of the benzophenone, as well as in some organometallic reactions: photodimerization of pentacarbonyliron and in inorganic reactions: photo reduction of silver and platinum salts or complexes. Two new protocols were described: the photo reduction of copper (II) chloride and the first photochemical synthesis of ferricenium tetrachloroferrate. We demonstrated that the assembly may be useful in organic, inorganic and organometallic preparative photochemistry.
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spelling Simple and efficient assembly for preparative photochemistryUm aparelho simples para fotoquímica preparativafotoquímica (aparelho para)foto-reatorfotoquímica (reações)1.06.00.00-0 QuímicaA simplified and efficient assembly for the preparative photochemistry is described. The apparatus was tested in some classical organic photochemical reactions such as photobleaching of riboflavin, and photo reduction of the benzophenone, as well as in some organometallic reactions: photodimerization of pentacarbonyliron and in inorganic reactions: photo reduction of silver and platinum salts or complexes. Two new protocols were described: the photo reduction of copper (II) chloride and the first photochemical synthesis of ferricenium tetrachloroferrate. We demonstrated that the assembly may be useful in organic, inorganic and organometallic preparative photochemistry.Uma aparelhagem laboratorial eficiente e simplificada para fotoquímica preparativa é descrita. O aparelho foi testado em algumas reações clássicas de Química Orgânica, como o foto-branqueamento de riboflavina e a fotoredução de benzofenona, bem como em algumas reações organometálicas: fotodimerização de ferro pentacarbonilo e em reações inorgânicas: fotorredução de sais ou complexos de prata e platina. Dois novos protocolos, fotoredução de cloreto de cobre (II) e a primeira síntese fotoquímica de tetracloroferrato de ferricínio, são descritos. Demonstramos, assim, que o aparelho pode ser útil em fotoquímica preparativa orgânica, inorgânica e organometálica.Universidade Estadual De Maringá2008-04-22info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/245910.4025/actascitechnol.v24i0.2459Acta Scientiarum. Technology; Vol 24 (2002); 1591-1598Acta Scientiarum. Technology; v. 24 (2002); 1591-15981806-25631807-8664reponame:Acta scientiarum. Technology (Online)instname:Universidade Estadual de Maringá (UEM)instacron:UEMporhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/2459/1552Federman Neto, AlbertoSilva, Flávia CristinaEsteves Dias, Cíntia ArisseDaltin Júnior, NereuVichnewski, ValterBonilha, João Batista SargiBorges, Áurea Donizete Lanchoteinfo:eu-repo/semantics/openAccess2024-05-17T13:02:44Zoai:periodicos.uem.br/ojs:article/2459Revistahttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/indexPUBhttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/oai||actatech@uem.br1807-86641806-2563opendoar:2024-05-17T13:02:44Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM)false
dc.title.none.fl_str_mv Simple and efficient assembly for preparative photochemistry
Um aparelho simples para fotoquímica preparativa
title Simple and efficient assembly for preparative photochemistry
spellingShingle Simple and efficient assembly for preparative photochemistry
Federman Neto, Alberto
fotoquímica (aparelho para)
foto-reator
fotoquímica (reações)
1.06.00.00-0 Química
title_short Simple and efficient assembly for preparative photochemistry
title_full Simple and efficient assembly for preparative photochemistry
title_fullStr Simple and efficient assembly for preparative photochemistry
title_full_unstemmed Simple and efficient assembly for preparative photochemistry
title_sort Simple and efficient assembly for preparative photochemistry
author Federman Neto, Alberto
author_facet Federman Neto, Alberto
Silva, Flávia Cristina
Esteves Dias, Cíntia Arisse
Daltin Júnior, Nereu
Vichnewski, Valter
Bonilha, João Batista Sargi
Borges, Áurea Donizete Lanchote
author_role author
author2 Silva, Flávia Cristina
Esteves Dias, Cíntia Arisse
Daltin Júnior, Nereu
Vichnewski, Valter
Bonilha, João Batista Sargi
Borges, Áurea Donizete Lanchote
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Federman Neto, Alberto
Silva, Flávia Cristina
Esteves Dias, Cíntia Arisse
Daltin Júnior, Nereu
Vichnewski, Valter
Bonilha, João Batista Sargi
Borges, Áurea Donizete Lanchote
dc.subject.por.fl_str_mv fotoquímica (aparelho para)
foto-reator
fotoquímica (reações)
1.06.00.00-0 Química
topic fotoquímica (aparelho para)
foto-reator
fotoquímica (reações)
1.06.00.00-0 Química
description A simplified and efficient assembly for the preparative photochemistry is described. The apparatus was tested in some classical organic photochemical reactions such as photobleaching of riboflavin, and photo reduction of the benzophenone, as well as in some organometallic reactions: photodimerization of pentacarbonyliron and in inorganic reactions: photo reduction of silver and platinum salts or complexes. Two new protocols were described: the photo reduction of copper (II) chloride and the first photochemical synthesis of ferricenium tetrachloroferrate. We demonstrated that the assembly may be useful in organic, inorganic and organometallic preparative photochemistry.
publishDate 2008
dc.date.none.fl_str_mv 2008-04-22
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/2459
10.4025/actascitechnol.v24i0.2459
url http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/2459
identifier_str_mv 10.4025/actascitechnol.v24i0.2459
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/2459/1552
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Estadual De Maringá
publisher.none.fl_str_mv Universidade Estadual De Maringá
dc.source.none.fl_str_mv Acta Scientiarum. Technology; Vol 24 (2002); 1591-1598
Acta Scientiarum. Technology; v. 24 (2002); 1591-1598
1806-2563
1807-8664
reponame:Acta scientiarum. Technology (Online)
instname:Universidade Estadual de Maringá (UEM)
instacron:UEM
instname_str Universidade Estadual de Maringá (UEM)
instacron_str UEM
institution UEM
reponame_str Acta scientiarum. Technology (Online)
collection Acta scientiarum. Technology (Online)
repository.name.fl_str_mv Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM)
repository.mail.fl_str_mv ||actatech@uem.br
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