Modelling of the pH effect on the biosorption of heavy metals by marine algae Sargassum filipendula

Detalhes bibliográficos
Autor(a) principal: Fagundes-Klen, Márcia Regina
Data de Publicação: 2011
Outros Autores: Veit, Márcia Teresinha, Silva, Edson Antônio da, Bergamasco, Rosangela, Martins, Tiago Dias, Canevesi, Rafael Luan Sehn
Tipo de documento: Artigo
Idioma: por
Título da fonte: Acta scientiarum. Technology (Online)
Texto Completo: http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/7605
Resumo: In this paper the biosorption of metal ions Cu2+, Cd2+ and Zn2+ in single-component system by Sargassum filipendula pre-treated with 0.5 M CaCl2 was studied. The experiments were carried out in a batch reactor at different fixed pH (3.0, 4.0, 5.0 and 6.0) and 30oC. All the equilibrium data obtained were described using two pH-dependent isotherm models, based on the Langmuir isotherm. Artificial neural networks was also used to represent the pH effect on the biosorption equilibrium. The input of the networks were the equilibrium concentration of the metal in the fluid phase and the pH. As output the concentration of the metallic specie in the biosorbent was used. The results showed that the modeling using artificial neural networks technique represented the equilibrium data much better than the conventional modeling by the pH-dependent isotherm models.
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spelling Modelling of the pH effect on the biosorption of heavy metals by marine algae Sargassum filipendulaModelagem do efeito do pH na biossorção de metais pela alga marinha Sargassum filipendula - doi: 10.4025/actascitechnol.v33i4.7605CoppercadmiumzincuptakeCobrecádmiozincoremoçãoEngenharia QuímicaIn this paper the biosorption of metal ions Cu2+, Cd2+ and Zn2+ in single-component system by Sargassum filipendula pre-treated with 0.5 M CaCl2 was studied. The experiments were carried out in a batch reactor at different fixed pH (3.0, 4.0, 5.0 and 6.0) and 30oC. All the equilibrium data obtained were described using two pH-dependent isotherm models, based on the Langmuir isotherm. Artificial neural networks was also used to represent the pH effect on the biosorption equilibrium. The input of the networks were the equilibrium concentration of the metal in the fluid phase and the pH. As output the concentration of the metallic specie in the biosorbent was used. The results showed that the modeling using artificial neural networks technique represented the equilibrium data much better than the conventional modeling by the pH-dependent isotherm models.Neste trabalho foi estudada a biossorção, em solução monocomponente, dos íons Cu2+, Cd2+ e Zn2+ pela alga marinha Sargassm filipendula pré-tratada com CaCl2 0,5 M. Os experimentos foram realizados em reator batelada, em diferentes pHs fixos (3,0; 4,0; 5,0 e 6,0) e 30ºC. Todos os dados de equilíbrio obtidos foram representados empregando dois modelos de isotermas de adsorção dependentes do pH, baseados na isoterma de Langmuir. Redes neurais artificiais também foram utilizadas para representar o efeito do pH sobre o equilíbrio da biossorção, sendo as variáveis de entrada da rede a concentração de equilíbrio do metal e o respectivo pH e, como variável de saída, a quantidade adsorvida pela biomassa. Os resultados mostraram que a modelagem utilizando as redes neurais artificiais foi mais eficiente do que a modelagem através das isotermas de adsorção.Universidade Estadual De Maringá2011-04-19info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionadsorçãoapplication/pdfhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/760510.4025/actascitechnol.v33i4.7605Acta Scientiarum. Technology; Vol 33 No 4 (2011); 439-446Acta Scientiarum. Technology; v. 33 n. 4 (2011); 439-4461806-25631807-8664reponame:Acta scientiarum. Technology (Online)instname:Universidade Estadual de Maringá (UEM)instacron:UEMporhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/7605/p7605Fagundes-Klen, Márcia ReginaVeit, Márcia TeresinhaSilva, Edson Antônio daBergamasco, RosangelaMartins, Tiago DiasCanevesi, Rafael Luan Sehninfo:eu-repo/semantics/openAccess2024-05-17T13:03:10Zoai:periodicos.uem.br/ojs:article/7605Revistahttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/indexPUBhttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/oai||actatech@uem.br1807-86641806-2563opendoar:2024-05-17T13:03:10Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM)false
dc.title.none.fl_str_mv Modelling of the pH effect on the biosorption of heavy metals by marine algae Sargassum filipendula
Modelagem do efeito do pH na biossorção de metais pela alga marinha Sargassum filipendula - doi: 10.4025/actascitechnol.v33i4.7605
title Modelling of the pH effect on the biosorption of heavy metals by marine algae Sargassum filipendula
spellingShingle Modelling of the pH effect on the biosorption of heavy metals by marine algae Sargassum filipendula
Fagundes-Klen, Márcia Regina
Copper
cadmium
zinc
uptake
Cobre
cádmio
zinco
remoção
Engenharia Química
title_short Modelling of the pH effect on the biosorption of heavy metals by marine algae Sargassum filipendula
title_full Modelling of the pH effect on the biosorption of heavy metals by marine algae Sargassum filipendula
title_fullStr Modelling of the pH effect on the biosorption of heavy metals by marine algae Sargassum filipendula
title_full_unstemmed Modelling of the pH effect on the biosorption of heavy metals by marine algae Sargassum filipendula
title_sort Modelling of the pH effect on the biosorption of heavy metals by marine algae Sargassum filipendula
author Fagundes-Klen, Márcia Regina
author_facet Fagundes-Klen, Márcia Regina
Veit, Márcia Teresinha
Silva, Edson Antônio da
Bergamasco, Rosangela
Martins, Tiago Dias
Canevesi, Rafael Luan Sehn
author_role author
author2 Veit, Márcia Teresinha
Silva, Edson Antônio da
Bergamasco, Rosangela
Martins, Tiago Dias
Canevesi, Rafael Luan Sehn
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Fagundes-Klen, Márcia Regina
Veit, Márcia Teresinha
Silva, Edson Antônio da
Bergamasco, Rosangela
Martins, Tiago Dias
Canevesi, Rafael Luan Sehn
dc.subject.por.fl_str_mv Copper
cadmium
zinc
uptake
Cobre
cádmio
zinco
remoção
Engenharia Química
topic Copper
cadmium
zinc
uptake
Cobre
cádmio
zinco
remoção
Engenharia Química
description In this paper the biosorption of metal ions Cu2+, Cd2+ and Zn2+ in single-component system by Sargassum filipendula pre-treated with 0.5 M CaCl2 was studied. The experiments were carried out in a batch reactor at different fixed pH (3.0, 4.0, 5.0 and 6.0) and 30oC. All the equilibrium data obtained were described using two pH-dependent isotherm models, based on the Langmuir isotherm. Artificial neural networks was also used to represent the pH effect on the biosorption equilibrium. The input of the networks were the equilibrium concentration of the metal in the fluid phase and the pH. As output the concentration of the metallic specie in the biosorbent was used. The results showed that the modeling using artificial neural networks technique represented the equilibrium data much better than the conventional modeling by the pH-dependent isotherm models.
publishDate 2011
dc.date.none.fl_str_mv 2011-04-19
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
adsorção
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/7605
10.4025/actascitechnol.v33i4.7605
url http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/7605
identifier_str_mv 10.4025/actascitechnol.v33i4.7605
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/7605/p7605
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Estadual De Maringá
publisher.none.fl_str_mv Universidade Estadual De Maringá
dc.source.none.fl_str_mv Acta Scientiarum. Technology; Vol 33 No 4 (2011); 439-446
Acta Scientiarum. Technology; v. 33 n. 4 (2011); 439-446
1806-2563
1807-8664
reponame:Acta scientiarum. Technology (Online)
instname:Universidade Estadual de Maringá (UEM)
instacron:UEM
instname_str Universidade Estadual de Maringá (UEM)
instacron_str UEM
institution UEM
reponame_str Acta scientiarum. Technology (Online)
collection Acta scientiarum. Technology (Online)
repository.name.fl_str_mv Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM)
repository.mail.fl_str_mv ||actatech@uem.br
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