Avaliação de compostos potencialmente tóxicos em cimento anidro: proposta de método quantitativo por ensaios de lixiviação

Detalhes bibliográficos
Autor(a) principal: Rosa, Bruna Souza
Data de Publicação: 2024
Tipo de documento: Dissertação
Idioma: por
Título da fonte: Repositório Institucional da UFBA
Texto Completo: https://repositorio.ufba.br/handle/ri/39254
Resumo: Soluções seguras, eficazes e economicamente viáveis são preponderantes diante da importância de reduzir os impactos ambientais da produção de cimento. O emprego de coprocessamento de resíduos como fonte de energia, bem como matéria-prima na síntese de clínquer de cimento Portland tem sido utilizado propondo a redução da demanda de combustível fóssil e matérias-primas naturais na produção do cimento. No entanto, a incineração desses materiais pode resultar no aumento dos níveis de compostos potencialmente tóxicos (CPTs) no sistema do forno, incluindo metais tóxicos altamente voláteis, como chumbo, cádmio e outros, que são de grande preocupação ambiental e podem apresentar riscos à saúde humana. Uma das lacunas em relação ao estudo desses CPTs é a sua quantificação no cimento anidro. Assim, o objetivo dessa pesquisa é propor um método de quantificação de compostos potencialmente tóxicos aplicado à cimento anidro por meio de ensaios de lixiviação. Para isso foram aplicadas técnicas analíticas para caracterizar amostras de cimento Portland comercial e cimentos produzidos em laboratório, como a granulometria, ensaio de Blaine, FRX e DRX. Posteriormente foram aplicados ensaios de calorimetria com diferentes soluções para avaliar estágios de hidratação do cimento durante a manipulação do ensaio de lixiviação. Após a definição da solução foram realizados os ensaios de lixiviação. Por fim, frente aos resultados dos testes realizados foi proposto um método de quantificação de CPTs específico para cimentos anidros. Os resultados obtidos por meio da análise calorimétrica indicaram que, embora tenha sido utilizada a mesma solução lixiviante em todos os cimentos testados, foram observadas variações nos tempos de indução, tempo de pega associados a cada tipo de cimento. Em relação a utilização da solução definida no ensaio de lixiviação, o método proposto evidenciou habilidade na análise de 11 metais. Ao contrastar os resultados de quantificação obtidos segundo as diretrizes da NBR 10005 e do TCLP 1311 com os resultados gerados pelo método empregado neste estudo, constatou-se uma precisão quantitativa aprimorada após o refinamento do procedimento metodológico.
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spelling 2024-04-04T18:09:59Z2024-04-022024-04-04T18:09:59Z2024-02-08https://repositorio.ufba.br/handle/ri/39254Soluções seguras, eficazes e economicamente viáveis são preponderantes diante da importância de reduzir os impactos ambientais da produção de cimento. O emprego de coprocessamento de resíduos como fonte de energia, bem como matéria-prima na síntese de clínquer de cimento Portland tem sido utilizado propondo a redução da demanda de combustível fóssil e matérias-primas naturais na produção do cimento. No entanto, a incineração desses materiais pode resultar no aumento dos níveis de compostos potencialmente tóxicos (CPTs) no sistema do forno, incluindo metais tóxicos altamente voláteis, como chumbo, cádmio e outros, que são de grande preocupação ambiental e podem apresentar riscos à saúde humana. Uma das lacunas em relação ao estudo desses CPTs é a sua quantificação no cimento anidro. Assim, o objetivo dessa pesquisa é propor um método de quantificação de compostos potencialmente tóxicos aplicado à cimento anidro por meio de ensaios de lixiviação. Para isso foram aplicadas técnicas analíticas para caracterizar amostras de cimento Portland comercial e cimentos produzidos em laboratório, como a granulometria, ensaio de Blaine, FRX e DRX. Posteriormente foram aplicados ensaios de calorimetria com diferentes soluções para avaliar estágios de hidratação do cimento durante a manipulação do ensaio de lixiviação. Após a definição da solução foram realizados os ensaios de lixiviação. Por fim, frente aos resultados dos testes realizados foi proposto um método de quantificação de CPTs específico para cimentos anidros. Os resultados obtidos por meio da análise calorimétrica indicaram que, embora tenha sido utilizada a mesma solução lixiviante em todos os cimentos testados, foram observadas variações nos tempos de indução, tempo de pega associados a cada tipo de cimento. Em relação a utilização da solução definida no ensaio de lixiviação, o método proposto evidenciou habilidade na análise de 11 metais. Ao contrastar os resultados de quantificação obtidos segundo as diretrizes da NBR 10005 e do TCLP 1311 com os resultados gerados pelo método empregado neste estudo, constatou-se uma precisão quantitativa aprimorada após o refinamento do procedimento metodológico.Safe, effective, and economically viable solutions are essential given the importance of reducing the environmental impact of cement production. The use of waste co-processing as an energy source as well as a raw material in the synthesis of Portland cement clinker has been used to reduce the demand for fossil fuels and natural raw materials in cement production. However, the incineration of these materials can result in increased levels of potentially toxic compounds (PTCs) in the kiln system, including highly volatile heavy metals such as lead, cadmium and others, which are of great environmental concern and can pose risks to human health. One of the gaps in the study of these CPTs is their quantification in anhydrous cement. The aim of this research is to propose a method for quantifying potentially toxic compounds in anhydrous cement by means of leaching tests. To this end, analytical techniques were applied to characterize samples of commercial Portland cement and cements produced in the laboratory, such as granulometry, Blaine test, XRF and XRD. Calorimetry tests were then carried out with different solutions to assess the stages of cement hydration during the leaching test. After defining the solution, the leaching tests were carried out. Finally, based on the results of the tests carried out, a specific method for quantifying CPTs for anhydrous cements was proposed. The results obtained through calorimetric analysis indicated that, although the same leaching solution was used for all the cements tested, variations were observed in the induction times and setting times associated with each type of cement. In relation to the use of the solution defined in the leaching test, the proposed method was able to analyse 11 metals. By contrasting the quantification results obtained according to the guidelines of NBR 10005 and TCLP 1311 with the results generated by the method used in this study, an improved quantitative precision was found after the methodological procedure was refined.porUNIVERSIDADE FEDERAL DA BAHIAPrograma de Pós-graduação em Engenharia Civil (PPEC) UFBABrasilEscola PolitécnicaAcesso Restrito/Embargadoinfo:eu-repo/semantics/openAccessPotentially toxic compoundsLeachingCoprocessing.CNPQ::ENGENHARIASCompostos potencialmente tóxicoslixiviaçãocoprocessamento.Avaliação de compostos potencialmente tóxicos em cimento anidro: proposta de método quantitativo por ensaios de lixiviaçãoAvaliação de compostos potencialmente tóxicos em cimento anidro: proposta de método quantitativo por ensaios de lixiviação SalvadorMestrado Acadêmicoinfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/publishedVersionGonçalves., Jardel Pereirahttp://lattes.cnpq.br/5363080225273626Kirchheim, Ana Paulahttp://lattes.cnpq.br/4014435019322019Silva, Guilherme Jorge Brigolinhttp://lattes.cnpq.br/8755682183778618Cabral, Elaine Christine de Magalhãeshttp://lattes.cnpq.br/1624091546521389Kirchheim, Ana Paula Kirchheimhttp://lattes.cnpq.br/4014435019322019http://lattes.cnpq.br/8681761766391522Rosa, Bruna SouzaALBERT, B., Guy, B., Damidot, D. 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dc.title.pt_BR.fl_str_mv Avaliação de compostos potencialmente tóxicos em cimento anidro: proposta de método quantitativo por ensaios de lixiviação
dc.title.alternative.pt_BR.fl_str_mv Avaliação de compostos potencialmente tóxicos em cimento anidro: proposta de método quantitativo por ensaios de lixiviação Salvador
title Avaliação de compostos potencialmente tóxicos em cimento anidro: proposta de método quantitativo por ensaios de lixiviação
spellingShingle Avaliação de compostos potencialmente tóxicos em cimento anidro: proposta de método quantitativo por ensaios de lixiviação
Rosa, Bruna Souza
CNPQ::ENGENHARIAS
Compostos potencialmente tóxicos
lixiviação
coprocessamento.
Potentially toxic compounds
Leaching
Coprocessing.
title_short Avaliação de compostos potencialmente tóxicos em cimento anidro: proposta de método quantitativo por ensaios de lixiviação
title_full Avaliação de compostos potencialmente tóxicos em cimento anidro: proposta de método quantitativo por ensaios de lixiviação
title_fullStr Avaliação de compostos potencialmente tóxicos em cimento anidro: proposta de método quantitativo por ensaios de lixiviação
title_full_unstemmed Avaliação de compostos potencialmente tóxicos em cimento anidro: proposta de método quantitativo por ensaios de lixiviação
title_sort Avaliação de compostos potencialmente tóxicos em cimento anidro: proposta de método quantitativo por ensaios de lixiviação
author Rosa, Bruna Souza
author_facet Rosa, Bruna Souza
author_role author
dc.contributor.advisor1.fl_str_mv Gonçalves., Jardel Pereira
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/5363080225273626
dc.contributor.advisor-co1.fl_str_mv Kirchheim, Ana Paula
dc.contributor.advisor-co1Lattes.fl_str_mv http://lattes.cnpq.br/4014435019322019
dc.contributor.referee1.fl_str_mv Silva, Guilherme Jorge Brigolin
dc.contributor.referee1Lattes.fl_str_mv http://lattes.cnpq.br/8755682183778618
dc.contributor.referee2.fl_str_mv Cabral, Elaine Christine de Magalhães
dc.contributor.referee2Lattes.fl_str_mv http://lattes.cnpq.br/1624091546521389
dc.contributor.referee3.fl_str_mv Kirchheim, Ana Paula Kirchheim
dc.contributor.referee3Lattes.fl_str_mv http://lattes.cnpq.br/4014435019322019
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/8681761766391522
dc.contributor.author.fl_str_mv Rosa, Bruna Souza
contributor_str_mv Gonçalves., Jardel Pereira
Kirchheim, Ana Paula
Silva, Guilherme Jorge Brigolin
Cabral, Elaine Christine de Magalhães
Kirchheim, Ana Paula Kirchheim
dc.subject.cnpq.fl_str_mv CNPQ::ENGENHARIAS
topic CNPQ::ENGENHARIAS
Compostos potencialmente tóxicos
lixiviação
coprocessamento.
Potentially toxic compounds
Leaching
Coprocessing.
dc.subject.por.fl_str_mv Compostos potencialmente tóxicos
lixiviação
coprocessamento.
dc.subject.other.pt_BR.fl_str_mv Potentially toxic compounds
Leaching
Coprocessing.
description Soluções seguras, eficazes e economicamente viáveis são preponderantes diante da importância de reduzir os impactos ambientais da produção de cimento. O emprego de coprocessamento de resíduos como fonte de energia, bem como matéria-prima na síntese de clínquer de cimento Portland tem sido utilizado propondo a redução da demanda de combustível fóssil e matérias-primas naturais na produção do cimento. No entanto, a incineração desses materiais pode resultar no aumento dos níveis de compostos potencialmente tóxicos (CPTs) no sistema do forno, incluindo metais tóxicos altamente voláteis, como chumbo, cádmio e outros, que são de grande preocupação ambiental e podem apresentar riscos à saúde humana. Uma das lacunas em relação ao estudo desses CPTs é a sua quantificação no cimento anidro. Assim, o objetivo dessa pesquisa é propor um método de quantificação de compostos potencialmente tóxicos aplicado à cimento anidro por meio de ensaios de lixiviação. Para isso foram aplicadas técnicas analíticas para caracterizar amostras de cimento Portland comercial e cimentos produzidos em laboratório, como a granulometria, ensaio de Blaine, FRX e DRX. Posteriormente foram aplicados ensaios de calorimetria com diferentes soluções para avaliar estágios de hidratação do cimento durante a manipulação do ensaio de lixiviação. Após a definição da solução foram realizados os ensaios de lixiviação. Por fim, frente aos resultados dos testes realizados foi proposto um método de quantificação de CPTs específico para cimentos anidros. Os resultados obtidos por meio da análise calorimétrica indicaram que, embora tenha sido utilizada a mesma solução lixiviante em todos os cimentos testados, foram observadas variações nos tempos de indução, tempo de pega associados a cada tipo de cimento. Em relação a utilização da solução definida no ensaio de lixiviação, o método proposto evidenciou habilidade na análise de 11 metais. Ao contrastar os resultados de quantificação obtidos segundo as diretrizes da NBR 10005 e do TCLP 1311 com os resultados gerados pelo método empregado neste estudo, constatou-se uma precisão quantitativa aprimorada após o refinamento do procedimento metodológico.
publishDate 2024
dc.date.accessioned.fl_str_mv 2024-04-04T18:09:59Z
dc.date.available.fl_str_mv 2024-04-02
2024-04-04T18:09:59Z
dc.date.issued.fl_str_mv 2024-02-08
dc.type.driver.fl_str_mv Mestrado Acadêmico
info:eu-repo/semantics/masterThesis
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format masterThesis
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://repositorio.ufba.br/handle/ri/39254
url https://repositorio.ufba.br/handle/ri/39254
dc.language.iso.fl_str_mv por
language por
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