Valorização do bio-óleo do resíduo de sisal

Detalhes bibliográficos
Autor(a) principal: Pereira, Luis Gabriel Gomes
Data de Publicação: 2023
Tipo de documento: Tese
Idioma: por
Título da fonte: Repositório Institucional da UFBA
Texto Completo: https://repositorio.ufba.br/handle/ri/38522
Resumo: O bio-óleo do resíduo de sisal, produzido por meio do processo de pirólise rápida em leito fluidizado, possui uma composição diferenciada, que se destaca pela alta viscosidade e ponto de fluidez, baixa razão O/C, elevada estabilidade térmica e alto teor de fenóis. Porém, ele ainda precisa ter suas características melhoradas, a fim de ser utilizado em biorrefinarias e para a produção de espécies químicas de interesse industrial. Sendo assim, o presente trabalho tem o objetivo de avaliar a redução das espécies oxigenadas no bio-óleo do resíduo de sisal a partir da manipulação das variáveis operacionais do processo de pirólise rápida e da sua transformação catalítica via hidrodesoxigenação (HDO). As relações processo/produto da pirólise foram estudadas variando-se a vazão de nitrogênio, vazão mássica de biomassa, temperatura e pressão. Em geral, a composição do bio-óleo foi intensamente dependente dos parâmetros do processo. A menor pressão estudada foi a melhor condição para obtenção do bio-óleo com alto rendimento (até 17%), com maior rendimento de monômeros (44,51% em peso) e menor razão O/C (0,11). Os resultados também indicaram que o bio-óleo do resíduo de sisal apresenta uma composição com altos teores de compostos fenólicos, alifáticos e naftalenos. Ele possui, portanto, grande potencial para a obtenção de biocombustíveis e/ou aromáticos e fenóis de alto valor agregado via valorização catalítica, devido ao baixo teor de oxigênio e alto grau de despolimerização. Na etapa de HDO, os catalisadores do tipo Ni-Cu/Al-MCM-41 se mostraram ativos no hidrotratamento dos bio-óleos do resíduo do sisal e da madeira de pinho. Para o bio-óleo de pinho, os catalisadores bimetálicos 20Ni5Cu e 20Ni10Cu apresentaram as melhores performances, promovendo os rendimentos de 53,1% e 51,2% em fase oleosa, superiores ao do “benchmark” RU/C (47,1%), além de promoverem os rendimentos de 43,35% e 42,84% em peso de monômeros, respectivamente. Foi verificada a redução do peso molecular médio (Mw), assim como da razão O/C e aumento da razão H/C, indicando predominância da via reacional de hidrogenação/hidrodesoxigenação/hidrocraqueamento. No caso do bio-óleo do resíduo do sisal, a via de reação de repolimerização foi predominante, resultando em consumos de H2 mais baixos, aumento do Mw e redução dos rendimentos dos monômeros. Entretanto, foi verificada a redução da razão O/C de aproximadamente 48% em média em relação à entrada, assim como o aumento de hidrocarbonetos alifáticos, aromáticos, álcoois e cetonas.
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spelling 2023-11-21T15:55:27Z2023-11-21T15:55:27Z2023-09-15https://repositorio.ufba.br/handle/ri/38522O bio-óleo do resíduo de sisal, produzido por meio do processo de pirólise rápida em leito fluidizado, possui uma composição diferenciada, que se destaca pela alta viscosidade e ponto de fluidez, baixa razão O/C, elevada estabilidade térmica e alto teor de fenóis. Porém, ele ainda precisa ter suas características melhoradas, a fim de ser utilizado em biorrefinarias e para a produção de espécies químicas de interesse industrial. Sendo assim, o presente trabalho tem o objetivo de avaliar a redução das espécies oxigenadas no bio-óleo do resíduo de sisal a partir da manipulação das variáveis operacionais do processo de pirólise rápida e da sua transformação catalítica via hidrodesoxigenação (HDO). As relações processo/produto da pirólise foram estudadas variando-se a vazão de nitrogênio, vazão mássica de biomassa, temperatura e pressão. Em geral, a composição do bio-óleo foi intensamente dependente dos parâmetros do processo. A menor pressão estudada foi a melhor condição para obtenção do bio-óleo com alto rendimento (até 17%), com maior rendimento de monômeros (44,51% em peso) e menor razão O/C (0,11). Os resultados também indicaram que o bio-óleo do resíduo de sisal apresenta uma composição com altos teores de compostos fenólicos, alifáticos e naftalenos. Ele possui, portanto, grande potencial para a obtenção de biocombustíveis e/ou aromáticos e fenóis de alto valor agregado via valorização catalítica, devido ao baixo teor de oxigênio e alto grau de despolimerização. Na etapa de HDO, os catalisadores do tipo Ni-Cu/Al-MCM-41 se mostraram ativos no hidrotratamento dos bio-óleos do resíduo do sisal e da madeira de pinho. Para o bio-óleo de pinho, os catalisadores bimetálicos 20Ni5Cu e 20Ni10Cu apresentaram as melhores performances, promovendo os rendimentos de 53,1% e 51,2% em fase oleosa, superiores ao do “benchmark” RU/C (47,1%), além de promoverem os rendimentos de 43,35% e 42,84% em peso de monômeros, respectivamente. Foi verificada a redução do peso molecular médio (Mw), assim como da razão O/C e aumento da razão H/C, indicando predominância da via reacional de hidrogenação/hidrodesoxigenação/hidrocraqueamento. No caso do bio-óleo do resíduo do sisal, a via de reação de repolimerização foi predominante, resultando em consumos de H2 mais baixos, aumento do Mw e redução dos rendimentos dos monômeros. Entretanto, foi verificada a redução da razão O/C de aproximadamente 48% em média em relação à entrada, assim como o aumento de hidrocarbonetos alifáticos, aromáticos, álcoois e cetonas.Bio-oil from sisal residue, produced through the process of fast pyrolysis in a fluidized bed, has a differentiated composition, which stands out due to its high viscosity and pour point, low O/C ratio, high thermal stability and high content of phenols. However, it still needs to be improved in order to be used in biorefineries and for the production of chemical species of industrial interest. Therefore, the present work aims to evaluate the reduction of oxygenated species in the bio-oil from sisal residue by manipulating the operational variables of the fast pyrolysis process and its catalytic transformation via hydrodeoxygenation (HDO). The process/product relations of the pyrolysis were studied by varying the nitrogen flow rate, biomass mass flow rate, temperature and pressure. In general, the bio-oil composition was intensely dependent on the process parameters. The lowest pressure studied was the best condition for obtaining bio-oil with high yield (up to 17 wt%), with higher yield of monomers (44.51 wt%) and lower O/C ratio (0.11). The results also indicated that the bio-oil from the sisal residue has a composition with high levels of phenolic, aliphatic and naphthalene compounds. It has, therefore, great potential for obtaining biofuels and/or aromatics and phenols with high added value via catalytic upgrade, due to the low oxygen content and high degree of depolymerization. In the HDO step, Ni-Cu/Al-MCM-41 type catalysts were active in the hydrotreatment of bio-oils from sisal residue and pinewood. The bimetallic catalysts 20Ni5Cu and 20Ni10Cu showed the best performances, promoting yields of 53.1 wt% and 51.2 wt% in the organic phase, higher than the benchmark RU/C (47.1%), in addition to promoting yields of 43.35 wt% and 42.84 wt% of monomers, respectively. There was a reduction in the average molecular weight (Mw), as well as in the O/C ratio and an increase in the H/C ratio, indicating a predominance of the hydrogenation/hydrodeoxygenation/hydrocracking route. In the case of bio-oil from sisal residue, the repolymerization route was predominant, resulting in lower H2 uptake, increased Mw and reduced monomer yields. However, there was a reduction in the O/C ratio of approximately 48 wt% on average compared to the feed, as well as an increase in aliphatic and aromatic hydrocarbons, alcohols and ketones.Submitted by Luis Pereira (l.ggomes@outlook.com) on 2023-11-14T18:54:17Z No. of bitstreams: 2 license_rdf: 811 bytes, checksum: e39d27027a6cc9cb039ad269a5db8e34 (MD5) Tese_LuisGabrielGomes_Pereira_versãofinal.pdf: 3261084 bytes, checksum: 98f647baa180f83b21a03bd034c761ad (MD5)Approved for entry into archive by Biblioteca Engenharia Processamento Técnico (biengproc@ufba.br) on 2023-11-21T15:55:27Z (GMT) No. of bitstreams: 2 Tese_LuisGabrielGomes_Pereira_versãofinal.pdf: 3261084 bytes, checksum: 98f647baa180f83b21a03bd034c761ad (MD5) license_rdf: 811 bytes, checksum: e39d27027a6cc9cb039ad269a5db8e34 (MD5)Made available in DSpace on 2023-11-21T15:55:27Z (GMT). No. of bitstreams: 2 Tese_LuisGabrielGomes_Pereira_versãofinal.pdf: 3261084 bytes, checksum: 98f647baa180f83b21a03bd034c761ad (MD5) license_rdf: 811 bytes, checksum: e39d27027a6cc9cb039ad269a5db8e34 (MD5) Previous issue date: 2023-09-15CapesFAPESBBanco do NordesteporUniversidade Federal da BahiaPrograma de Pós-Graduação em Engenharia Quimica (PPEQ) UFBABrasilEscola PolitécnicaAttribution-NonCommercial-NoDerivs 3.0 Brazilhttp://creativecommons.org/licenses/by-nc-nd/3.0/br/info:eu-repo/semantics/openAccessBio-oilSisal residueFast pyrolysisCatalytic hydrotreatmentNi-Cu/Al-MCM-41CNPQ::ENGENHARIAS::ENGENHARIA QUIMICA::PROCESSOS INDUSTRIAIS DE ENGENHARIA QUIMICA::PROCESSOS ORGANICOSBio-óleoResíduo de sisalPirólise rápidaHidrodesoxigenação catalíticaNi-Cu/Al-MCM-41Valorização do bio-óleo do resíduo de sisalValorization of bio-oil from sisal residueDoutoradoinfo:eu-repo/semantics/doctoralThesisinfo:eu-repo/semantics/publishedVersionPires, Carlos Augusto de Moraeshttps://orcid.org/0000-0003-4231-6495http://lattes.cnpq.br/7185462874845405Lima, Sirlene Barbosahttp://lattes.cnpq.br/4677727390063135Campos, Leila Maria AguileraPires, Carlos Augusto de Moraeshttps://orcid.org/0000-0003-4231-6495http://lattes.cnpq.br/7185462874845405Lima, Sirlene Barbosahttp://lattes.cnpq.br/4677727390063135Trierweiler, Jorge Otáviohttps://orcid.org/0000-0002-6328-945Xhttp://lattes.cnpq.br/5718970374865864Silva Júnior, Roberto Batista dahttps://orcid.org/0000-0002-6281-7820http://lattes.cnpq.br/8404741392766812Varela, Maria do Carmo Rangel Santoshttps://orcid.org/0000-0002-2497-9837http://lattes.cnpq.br/0023950321397451ttp://lattes.cnpq.br/0402361716510097https://orcid.org/0000-0002-1055-0300http://lattes.cnpq.br/0624260902325890Pereira, Luis Gabriel Gomes2016 - Aysu, Durak et al. 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dc.title.pt_BR.fl_str_mv Valorização do bio-óleo do resíduo de sisal
dc.title.alternative.pt_BR.fl_str_mv Valorization of bio-oil from sisal residue
title Valorização do bio-óleo do resíduo de sisal
spellingShingle Valorização do bio-óleo do resíduo de sisal
Pereira, Luis Gabriel Gomes
CNPQ::ENGENHARIAS::ENGENHARIA QUIMICA::PROCESSOS INDUSTRIAIS DE ENGENHARIA QUIMICA::PROCESSOS ORGANICOS
Bio-óleo
Resíduo de sisal
Pirólise rápida
Hidrodesoxigenação catalítica
Ni-Cu/Al-MCM-41
Bio-oil
Sisal residue
Fast pyrolysis
Catalytic hydrotreatment
Ni-Cu/Al-MCM-41
title_short Valorização do bio-óleo do resíduo de sisal
title_full Valorização do bio-óleo do resíduo de sisal
title_fullStr Valorização do bio-óleo do resíduo de sisal
title_full_unstemmed Valorização do bio-óleo do resíduo de sisal
title_sort Valorização do bio-óleo do resíduo de sisal
author Pereira, Luis Gabriel Gomes
author_facet Pereira, Luis Gabriel Gomes
author_role author
dc.contributor.refereesLattes.pt_BR.fl_str_mv ttp://lattes.cnpq.br/0402361716510097
dc.contributor.advisor1.fl_str_mv Pires, Carlos Augusto de Moraes
dc.contributor.advisor1ID.fl_str_mv https://orcid.org/0000-0003-4231-6495
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/7185462874845405
dc.contributor.advisor-co1.fl_str_mv Lima, Sirlene Barbosa
dc.contributor.advisor-co1Lattes.fl_str_mv http://lattes.cnpq.br/4677727390063135
dc.contributor.referee1.fl_str_mv Campos, Leila Maria Aguilera
Pires, Carlos Augusto de Moraes
dc.contributor.referee1ID.fl_str_mv https://orcid.org/0000-0003-4231-6495
dc.contributor.referee1Lattes.fl_str_mv http://lattes.cnpq.br/7185462874845405
dc.contributor.referee2.fl_str_mv Lima, Sirlene Barbosa
dc.contributor.referee2Lattes.fl_str_mv http://lattes.cnpq.br/4677727390063135
dc.contributor.referee3.fl_str_mv Trierweiler, Jorge Otávio
dc.contributor.referee3ID.fl_str_mv https://orcid.org/0000-0002-6328-945X
dc.contributor.referee3Lattes.fl_str_mv http://lattes.cnpq.br/5718970374865864
dc.contributor.referee4.fl_str_mv Silva Júnior, Roberto Batista da
dc.contributor.referee4ID.fl_str_mv https://orcid.org/0000-0002-6281-7820
dc.contributor.referee4Lattes.fl_str_mv http://lattes.cnpq.br/8404741392766812
dc.contributor.referee5.fl_str_mv Varela, Maria do Carmo Rangel Santos
dc.contributor.referee5ID.fl_str_mv https://orcid.org/0000-0002-2497-9837
dc.contributor.referee5Lattes.fl_str_mv http://lattes.cnpq.br/0023950321397451
dc.contributor.authorID.fl_str_mv https://orcid.org/0000-0002-1055-0300
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/0624260902325890
dc.contributor.author.fl_str_mv Pereira, Luis Gabriel Gomes
contributor_str_mv Pires, Carlos Augusto de Moraes
Lima, Sirlene Barbosa
Campos, Leila Maria Aguilera
Pires, Carlos Augusto de Moraes
Lima, Sirlene Barbosa
Trierweiler, Jorge Otávio
Silva Júnior, Roberto Batista da
Varela, Maria do Carmo Rangel Santos
dc.subject.cnpq.fl_str_mv CNPQ::ENGENHARIAS::ENGENHARIA QUIMICA::PROCESSOS INDUSTRIAIS DE ENGENHARIA QUIMICA::PROCESSOS ORGANICOS
topic CNPQ::ENGENHARIAS::ENGENHARIA QUIMICA::PROCESSOS INDUSTRIAIS DE ENGENHARIA QUIMICA::PROCESSOS ORGANICOS
Bio-óleo
Resíduo de sisal
Pirólise rápida
Hidrodesoxigenação catalítica
Ni-Cu/Al-MCM-41
Bio-oil
Sisal residue
Fast pyrolysis
Catalytic hydrotreatment
Ni-Cu/Al-MCM-41
dc.subject.por.fl_str_mv Bio-óleo
Resíduo de sisal
Pirólise rápida
Hidrodesoxigenação catalítica
Ni-Cu/Al-MCM-41
dc.subject.other.pt_BR.fl_str_mv Bio-oil
Sisal residue
Fast pyrolysis
Catalytic hydrotreatment
Ni-Cu/Al-MCM-41
description O bio-óleo do resíduo de sisal, produzido por meio do processo de pirólise rápida em leito fluidizado, possui uma composição diferenciada, que se destaca pela alta viscosidade e ponto de fluidez, baixa razão O/C, elevada estabilidade térmica e alto teor de fenóis. Porém, ele ainda precisa ter suas características melhoradas, a fim de ser utilizado em biorrefinarias e para a produção de espécies químicas de interesse industrial. Sendo assim, o presente trabalho tem o objetivo de avaliar a redução das espécies oxigenadas no bio-óleo do resíduo de sisal a partir da manipulação das variáveis operacionais do processo de pirólise rápida e da sua transformação catalítica via hidrodesoxigenação (HDO). As relações processo/produto da pirólise foram estudadas variando-se a vazão de nitrogênio, vazão mássica de biomassa, temperatura e pressão. Em geral, a composição do bio-óleo foi intensamente dependente dos parâmetros do processo. A menor pressão estudada foi a melhor condição para obtenção do bio-óleo com alto rendimento (até 17%), com maior rendimento de monômeros (44,51% em peso) e menor razão O/C (0,11). Os resultados também indicaram que o bio-óleo do resíduo de sisal apresenta uma composição com altos teores de compostos fenólicos, alifáticos e naftalenos. Ele possui, portanto, grande potencial para a obtenção de biocombustíveis e/ou aromáticos e fenóis de alto valor agregado via valorização catalítica, devido ao baixo teor de oxigênio e alto grau de despolimerização. Na etapa de HDO, os catalisadores do tipo Ni-Cu/Al-MCM-41 se mostraram ativos no hidrotratamento dos bio-óleos do resíduo do sisal e da madeira de pinho. Para o bio-óleo de pinho, os catalisadores bimetálicos 20Ni5Cu e 20Ni10Cu apresentaram as melhores performances, promovendo os rendimentos de 53,1% e 51,2% em fase oleosa, superiores ao do “benchmark” RU/C (47,1%), além de promoverem os rendimentos de 43,35% e 42,84% em peso de monômeros, respectivamente. Foi verificada a redução do peso molecular médio (Mw), assim como da razão O/C e aumento da razão H/C, indicando predominância da via reacional de hidrogenação/hidrodesoxigenação/hidrocraqueamento. No caso do bio-óleo do resíduo do sisal, a via de reação de repolimerização foi predominante, resultando em consumos de H2 mais baixos, aumento do Mw e redução dos rendimentos dos monômeros. Entretanto, foi verificada a redução da razão O/C de aproximadamente 48% em média em relação à entrada, assim como o aumento de hidrocarbonetos alifáticos, aromáticos, álcoois e cetonas.
publishDate 2023
dc.date.accessioned.fl_str_mv 2023-11-21T15:55:27Z
dc.date.available.fl_str_mv 2023-11-21T15:55:27Z
dc.date.issued.fl_str_mv 2023-09-15
dc.type.driver.fl_str_mv Doutorado
info:eu-repo/semantics/doctoralThesis
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format doctoralThesis
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://repositorio.ufba.br/handle/ri/38522
url https://repositorio.ufba.br/handle/ri/38522
dc.language.iso.fl_str_mv por
language por
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