Absolute Configurations and Enantiomeric Compositions of 2-Methyl-1-butanol and 2-Methyl-1-pentanol by 1H-NMR Spectrometry of their Diastereomeric Valine Esters

Detalhes bibliográficos
Autor(a) principal: Andrade, Francisco A. de C.
Data de Publicação: 1998
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFBA
Texto Completo: http://www.repositorio.ufba.br/ri/handle/ri/4971
Resumo: p. 85-89, Jan/Feb.
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spelling Andrade, Francisco A. de C.Andrade, Francisco A. de C.2011-12-21T17:44:46Z2011-12-21T17:44:46Z19980103-5053http://www.repositorio.ufba.br/ri/handle/ri/4971v. 9, n. 1.p. 85-89, Jan/Feb.Ésteres diastereoméricos da L-valina com o 2-methyl-1-butanol e o 2-methyl-1-pentanol foram examinados como derivados para a análise estereoquímica dos álcoois por ressonância magnética nuclear de prótons. A ausência de racemização, durante suas preparações, e as diferenças de deslocamentos químicos apresentadas por seus epímeros indicam que estes ésteres são derivados úteis para a especificação da configuração e para a determinação da composição enantiomérica do álcool correspondente.Submitted by JURANDI DE SOUZA SILVA (jssufba@hotmail.com) on 2011-12-21T17:44:46Z No. of bitstreams: 1 a15v09n1.pdf: 76457 bytes, checksum: 9cf4c9cf022328856caa5b36f16498a3 (MD5)Made available in DSpace on 2011-12-21T17:44:46Z (GMT). No. of bitstreams: 1 a15v09n1.pdf: 76457 bytes, checksum: 9cf4c9cf022328856caa5b36f16498a3 (MD5) Previous issue date: 1998São Paulohttp://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100015&lng=en&nrm=isoreponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBAAbsolute configurationOptical purityChiral primary alcoholNMRAbsolute Configurations and Enantiomeric Compositions of 2-Methyl-1-butanol and 2-Methyl-1-pentanol by 1H-NMR Spectrometry of their Diastereomeric Valine EstersJournal of the Brazilian Chemical Societyinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleenginfo:eu-repo/semantics/openAccessORIGINALa15v09n1.pdfa15v09n1.pdfapplication/pdf76457https://repositorio.ufba.br/bitstream/ri/4971/1/a15v09n1.pdf9cf4c9cf022328856caa5b36f16498a3MD51LICENSElicense.txtlicense.txttext/plain1809https://repositorio.ufba.br/bitstream/ri/4971/2/license.txt8bb3e3eb871f5854a9ec419f68651b60MD52TEXTa15v09n1.pdf.txta15v09n1.pdf.txtExtracted texttext/plain19876https://repositorio.ufba.br/bitstream/ri/4971/3/a15v09n1.pdf.txt079f62923ec03b2147f175f6ef35101eMD53ri/49712022-07-05 14:03:15.681oai:repositorio.ufba.br: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ório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-07-05T17:03:15Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false
dc.title.pt_BR.fl_str_mv Absolute Configurations and Enantiomeric Compositions of 2-Methyl-1-butanol and 2-Methyl-1-pentanol by 1H-NMR Spectrometry of their Diastereomeric Valine Esters
dc.title.alternative.pt_BR.fl_str_mv Journal of the Brazilian Chemical Society
title Absolute Configurations and Enantiomeric Compositions of 2-Methyl-1-butanol and 2-Methyl-1-pentanol by 1H-NMR Spectrometry of their Diastereomeric Valine Esters
spellingShingle Absolute Configurations and Enantiomeric Compositions of 2-Methyl-1-butanol and 2-Methyl-1-pentanol by 1H-NMR Spectrometry of their Diastereomeric Valine Esters
Andrade, Francisco A. de C.
Absolute configuration
Optical purity
Chiral primary alcohol
NMR
title_short Absolute Configurations and Enantiomeric Compositions of 2-Methyl-1-butanol and 2-Methyl-1-pentanol by 1H-NMR Spectrometry of their Diastereomeric Valine Esters
title_full Absolute Configurations and Enantiomeric Compositions of 2-Methyl-1-butanol and 2-Methyl-1-pentanol by 1H-NMR Spectrometry of their Diastereomeric Valine Esters
title_fullStr Absolute Configurations and Enantiomeric Compositions of 2-Methyl-1-butanol and 2-Methyl-1-pentanol by 1H-NMR Spectrometry of their Diastereomeric Valine Esters
title_full_unstemmed Absolute Configurations and Enantiomeric Compositions of 2-Methyl-1-butanol and 2-Methyl-1-pentanol by 1H-NMR Spectrometry of their Diastereomeric Valine Esters
title_sort Absolute Configurations and Enantiomeric Compositions of 2-Methyl-1-butanol and 2-Methyl-1-pentanol by 1H-NMR Spectrometry of their Diastereomeric Valine Esters
author Andrade, Francisco A. de C.
author_facet Andrade, Francisco A. de C.
author_role author
dc.contributor.author.fl_str_mv Andrade, Francisco A. de C.
Andrade, Francisco A. de C.
dc.subject.por.fl_str_mv Absolute configuration
Optical purity
Chiral primary alcohol
NMR
topic Absolute configuration
Optical purity
Chiral primary alcohol
NMR
description p. 85-89, Jan/Feb.
publishDate 1998
dc.date.issued.fl_str_mv 1998
dc.date.accessioned.fl_str_mv 2011-12-21T17:44:46Z
dc.date.available.fl_str_mv 2011-12-21T17:44:46Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://www.repositorio.ufba.br/ri/handle/ri/4971
dc.identifier.issn.none.fl_str_mv 0103-5053
dc.identifier.number.pt_BR.fl_str_mv v. 9, n. 1.
identifier_str_mv 0103-5053
v. 9, n. 1.
url http://www.repositorio.ufba.br/ri/handle/ri/4971
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
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