Brønsted ionic liquids for sustainable processes: synthesis and physical properties
Autor(a) principal: | |
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Data de Publicação: | 2010 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFBA |
Texto Completo: | http://www.repositorio.ufba.br/ri/handle/ri/6010 |
Resumo: | Trabalho completo: acesso restrito, p. 625–632 |
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Alvarez, Víctor H.Dosil, NoeliaGonzalez-Cabaleiro, RebecaSilva, Silvana Mattedi ePastor, Manuel MartinDuro, Miguel Angel IglesiasNavaza, José M.Alvarez, Víctor H.Dosil, NoeliaGonzalez-Cabaleiro, RebecaSilva, Silvana Mattedi ePastor, Manuel MartinDuro, Miguel Angel IglesiasNavaza, José M.2012-05-30T21:10:32Z20100021-9568http://www.repositorio.ufba.br/ri/handle/ri/6010v. 55, n. 2Trabalho completo: acesso restrito, p. 625–632This report describes the synthesis of ionic liquids that incorporate the N-methyl-2-hydroxyethylammonium cation with various carboxylic acid anions and the study of some of their physical properties, including self-diffusion coefficients, density, speed of sound, viscosity, and refractive index. 1H and 13C NMR spectra were used to characterize the chemical structure of the species in concordance with FT-IR spectra. DOSY NMR spectra was used to determine the self-diffusion coefficients of the components, which were consistent with the formation of a lamellar or micellar liquid-crystal phase in samples containing an alkyl chain in the anion species. Thermoacoustic parameters showed that anion alkyl chain has an influence on the molecular packing of these ionic liquids. In addition, the effect of temperature on the properties seems to be related to the size and the type of aliphatic chain of the ionic liquid.Submitted by Bruna Lessa (lessbruna@gmail.com) on 2012-05-30T21:10:32Z No. of bitstreams: 1 (45)je900550v.pdf: 269197 bytes, checksum: a1a474765bbf865b7c96747b970f78c3 (MD5)Made available in DSpace on 2012-05-30T21:10:32Z (GMT). No. of bitstreams: 1 (45)je900550v.pdf: 269197 bytes, checksum: a1a474765bbf865b7c96747b970f78c3 (MD5) Previous issue date: 2010American Chemical Society10.1021/je900550vreponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBABrønsted ionic liquids for sustainable processes: synthesis and physical propertiesJournal of Chemical & Engineering DataArtigo de Periódicoinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion10000-01-01enginfo:eu-repo/semantics/openAccessORIGINAL(45)je900550v.pdf(45)je900550v.pdfapplication/pdf269197https://repositorio.ufba.br/bitstream/ri/6010/1/%2845%29je900550v.pdfa1a474765bbf865b7c96747b970f78c3MD51LICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/6010/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52TEXT(45)je900550v.pdf.txt(45)je900550v.pdf.txtExtracted texttext/plain39313https://repositorio.ufba.br/bitstream/ri/6010/3/%2845%29je900550v.pdf.txtcea6f440ac8a341560e7eb7de119ab1aMD53ri/60102022-08-26 11:47:05.922oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-08-26T14:47:05Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false |
dc.title.pt_BR.fl_str_mv |
Brønsted ionic liquids for sustainable processes: synthesis and physical properties |
dc.title.alternative.pt_BR.fl_str_mv |
Journal of Chemical & Engineering Data |
title |
Brønsted ionic liquids for sustainable processes: synthesis and physical properties |
spellingShingle |
Brønsted ionic liquids for sustainable processes: synthesis and physical properties Alvarez, Víctor H. |
title_short |
Brønsted ionic liquids for sustainable processes: synthesis and physical properties |
title_full |
Brønsted ionic liquids for sustainable processes: synthesis and physical properties |
title_fullStr |
Brønsted ionic liquids for sustainable processes: synthesis and physical properties |
title_full_unstemmed |
Brønsted ionic liquids for sustainable processes: synthesis and physical properties |
title_sort |
Brønsted ionic liquids for sustainable processes: synthesis and physical properties |
author |
Alvarez, Víctor H. |
author_facet |
Alvarez, Víctor H. Dosil, Noelia Gonzalez-Cabaleiro, Rebeca Silva, Silvana Mattedi e Pastor, Manuel Martin Duro, Miguel Angel Iglesias Navaza, José M. |
author_role |
author |
author2 |
Dosil, Noelia Gonzalez-Cabaleiro, Rebeca Silva, Silvana Mattedi e Pastor, Manuel Martin Duro, Miguel Angel Iglesias Navaza, José M. |
author2_role |
author author author author author author |
dc.contributor.author.fl_str_mv |
Alvarez, Víctor H. Dosil, Noelia Gonzalez-Cabaleiro, Rebeca Silva, Silvana Mattedi e Pastor, Manuel Martin Duro, Miguel Angel Iglesias Navaza, José M. Alvarez, Víctor H. Dosil, Noelia Gonzalez-Cabaleiro, Rebeca Silva, Silvana Mattedi e Pastor, Manuel Martin Duro, Miguel Angel Iglesias Navaza, José M. |
description |
Trabalho completo: acesso restrito, p. 625–632 |
publishDate |
2010 |
dc.date.issued.fl_str_mv |
2010 |
dc.date.accessioned.fl_str_mv |
2012-05-30T21:10:32Z |
dc.type.driver.fl_str_mv |
Artigo de Periódico info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.repositorio.ufba.br/ri/handle/ri/6010 |
dc.identifier.issn.none.fl_str_mv |
0021-9568 |
dc.identifier.number.pt_BR.fl_str_mv |
v. 55, n. 2 |
identifier_str_mv |
0021-9568 v. 55, n. 2 |
url |
http://www.repositorio.ufba.br/ri/handle/ri/6010 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.pt_BR.fl_str_mv |
10.1021/je900550v |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFBA instname:Universidade Federal da Bahia (UFBA) instacron:UFBA |
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Universidade Federal da Bahia (UFBA) |
instacron_str |
UFBA |
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UFBA |
reponame_str |
Repositório Institucional da UFBA |
collection |
Repositório Institucional da UFBA |
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