Effect of magnesium on the properties of nickel and lanthanum-based catalysts in steam reforming
Autor(a) principal: | |
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Data de Publicação: | 2008 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFBA |
Texto Completo: | http://www.repositorio.ufba.br/ri/handle/ri/5950 |
Resumo: | Acesso restrito: Texto completo. p. 3627-3630 |
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Moura, Jadson SantosSouza, Marluce Oliveira da GuardaVarela, Maria do Carmo Rangel SantosMoura, Jadson SantosSouza, Marluce Oliveira da GuardaVarela, Maria do Carmo Rangel Santos2012-05-24T13:39:40Z20080016-2361http://www.repositorio.ufba.br/ri/handle/ri/5950v. 87, n. 17-18Acesso restrito: Texto completo. p. 3627-3630Catalysts with basic properties have been used in many reactions with the aim of inhibiting coke deposition, but the addition of basic dopants may change both their activity and selectivity. In order to find efficient systems to methane steam reforming, the effect of magnesium on the properties of lanthana-supported nickel was investigated in this work. Catalysts with 15% of nickel and lanthanum to magnesium molar ratios of 5 and 10 were prepared and characterized, besides pure magnesia or lanthana-supported nickel. It was found that magnesium makes the nickel reduction more difficult at high temperatures but favors the reduction of amorphous nickel oxide at low temperature. Magnesium also increases the activity of lanthana-supported nickel catalyst in methane steam reforming reaction and affected the hydrogen and carbon monoxide selectivities, showing that it can be used for tailoring catalysts for several purposes.Submitted by JURANDI DE SOUZA SILVA (jssufba@hotmail.com) on 2012-05-24T13:39:39Z No. of bitstreams: 1 __ac.els-cdn.com_S001623...35deca9bef151a1fa67a35d97753b.pdf: 204906 bytes, checksum: ffe5c38135d5d122953dc6cfc9f0f4ce (MD5)Made available in DSpace on 2012-05-24T13:39:40Z (GMT). No. of bitstreams: 1 __ac.els-cdn.com_S001623...35deca9bef151a1fa67a35d97753b.pdf: 204906 bytes, checksum: ffe5c38135d5d122953dc6cfc9f0f4ce (MD5) Previous issue date: 2008http://dx.doi.org/10.1016/j.fuel.2008.06.017reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBAHydrogenNi catalystLanthanumEffect of magnesium on the properties of nickel and lanthanum-based catalysts in steam reformingFuelinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10000-01-01enginfo:eu-repo/semantics/openAccessLICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/5950/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52ORIGINAL__ac.els-cdn.com_S001623...35deca9bef151a1fa67a35d97753b.pdf__ac.els-cdn.com_S001623...35deca9bef151a1fa67a35d97753b.pdfapplication/pdf204906https://repositorio.ufba.br/bitstream/ri/5950/1/__ac.els-cdn.com_S001623...35deca9bef151a1fa67a35d97753b.pdfffe5c38135d5d122953dc6cfc9f0f4ceMD51TEXT__ac.els-cdn.com_S001623...35deca9bef151a1fa67a35d97753b.pdf.txt__ac.els-cdn.com_S001623...35deca9bef151a1fa67a35d97753b.pdf.txtExtracted texttext/plain18488https://repositorio.ufba.br/bitstream/ri/5950/3/__ac.els-cdn.com_S001623...35deca9bef151a1fa67a35d97753b.pdf.txtdb4826fa6fbdd5fc6089708dabea03d7MD53ri/59502022-07-05 14:03:13.226oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-07-05T17:03:13Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false |
dc.title.pt_BR.fl_str_mv |
Effect of magnesium on the properties of nickel and lanthanum-based catalysts in steam reforming |
dc.title.alternative.pt_BR.fl_str_mv |
Fuel |
title |
Effect of magnesium on the properties of nickel and lanthanum-based catalysts in steam reforming |
spellingShingle |
Effect of magnesium on the properties of nickel and lanthanum-based catalysts in steam reforming Moura, Jadson Santos Hydrogen Ni catalyst Lanthanum |
title_short |
Effect of magnesium on the properties of nickel and lanthanum-based catalysts in steam reforming |
title_full |
Effect of magnesium on the properties of nickel and lanthanum-based catalysts in steam reforming |
title_fullStr |
Effect of magnesium on the properties of nickel and lanthanum-based catalysts in steam reforming |
title_full_unstemmed |
Effect of magnesium on the properties of nickel and lanthanum-based catalysts in steam reforming |
title_sort |
Effect of magnesium on the properties of nickel and lanthanum-based catalysts in steam reforming |
author |
Moura, Jadson Santos |
author_facet |
Moura, Jadson Santos Souza, Marluce Oliveira da Guarda Varela, Maria do Carmo Rangel Santos |
author_role |
author |
author2 |
Souza, Marluce Oliveira da Guarda Varela, Maria do Carmo Rangel Santos |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Moura, Jadson Santos Souza, Marluce Oliveira da Guarda Varela, Maria do Carmo Rangel Santos Moura, Jadson Santos Souza, Marluce Oliveira da Guarda Varela, Maria do Carmo Rangel Santos |
dc.subject.por.fl_str_mv |
Hydrogen Ni catalyst Lanthanum |
topic |
Hydrogen Ni catalyst Lanthanum |
description |
Acesso restrito: Texto completo. p. 3627-3630 |
publishDate |
2008 |
dc.date.issued.fl_str_mv |
2008 |
dc.date.accessioned.fl_str_mv |
2012-05-24T13:39:40Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.repositorio.ufba.br/ri/handle/ri/5950 |
dc.identifier.issn.none.fl_str_mv |
0016-2361 |
dc.identifier.number.pt_BR.fl_str_mv |
v. 87, n. 17-18 |
identifier_str_mv |
0016-2361 v. 87, n. 17-18 |
url |
http://www.repositorio.ufba.br/ri/handle/ri/5950 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
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openAccess |
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http://dx.doi.org/10.1016/j.fuel.2008.06.017 |
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reponame:Repositório Institucional da UFBA instname:Universidade Federal da Bahia (UFBA) instacron:UFBA |
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Universidade Federal da Bahia (UFBA) |
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UFBA |
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UFBA |
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Repositório Institucional da UFBA |
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