Optimal operating policies for tailored linear polyethylene resins production
Autor(a) principal: | |
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Data de Publicação: | 2008 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFBA |
Texto Completo: | http://www.repositorio.ufba.br/ri/handle/ri/6045 |
Resumo: | Acesso restrito: Texto completo. p. 2346-2365 |
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Pontes, Karen ValverdeMaciel, R.Embiruçu, MarceloHartwich, A.Marquardt, W.Pontes, Karen ValverdeMaciel, R.Embiruçu, MarceloHartwich, A.Marquardt, W.2012-06-01T13:35:53Z20080001-1541http://www.repositorio.ufba.br/ri/handle/ri/6045v. 54, n. 9Acesso restrito: Texto completo. p. 2346-2365In this work, optimal operating policies for the ethylene polymerization in solution with a Ziegler-Natta catalyst in a series of tubular and stirred tank reactors are proposed. The polymer is specified through properties such as melt index, stress exponent and density. Usually such properties are predicted by means of a process model once the operating conditions are specified. However, the computation of appropriate operating conditions to match desired resins properties is a much more difficult and not yet industrially established task. This problem can be solved through optimization techniques, an efficient alternative to costly pilot plant or production scale tests. A formulation is proposed, where a stationary model of the flowsheet (DAE system) is cast into a multi-stage model with the spatial flow path coordinate as the independent variable. Discontinuities occur at the stage transitions because of model switches and reactants injection. Several studies, involving different polyethylene resin specifications, are carried out to present the high potential and versatility of the suggested procedure. © 2008 American Institute of Chemical Engineers AIChE J, 2008Submitted by JURANDI DE SOUZA SILVA (jssufba@hotmail.com) on 2012-06-01T13:35:53Z No. of bitstreams: 1 __onlinelibrary.wiley.co...26d45d5b26730fe5389fc376172c8.pdf: 441469 bytes, checksum: 11aba28bea05ca0a670c561f2aa24acf (MD5)Made available in DSpace on 2012-06-01T13:35:53Z (GMT). No. of bitstreams: 1 __onlinelibrary.wiley.co...26d45d5b26730fe5389fc376172c8.pdf: 441469 bytes, checksum: 11aba28bea05ca0a670c561f2aa24acf (MD5) Previous issue date: 2008http://onlinelibrary.wiley.com/doi/10.1002/aic.11566/pdfreponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBAMathematical modelingoptimizationpolymerizationsimulationprocessdesign (process simulation)Optimal operating policies for tailored linear polyethylene resins productionAIChE JournalArtigo de Periódicoinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion10000-01-01enginfo:eu-repo/semantics/openAccessORIGINAL__onlinelibrary.wiley.co...26d45d5b26730fe5389fc376172c8.pdf__onlinelibrary.wiley.co...26d45d5b26730fe5389fc376172c8.pdfapplication/pdf441469https://repositorio.ufba.br/bitstream/ri/6045/1/__onlinelibrary.wiley.co...26d45d5b26730fe5389fc376172c8.pdf11aba28bea05ca0a670c561f2aa24acfMD51LICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/6045/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52TEXT__onlinelibrary.wiley.co...26d45d5b26730fe5389fc376172c8.pdf.txt__onlinelibrary.wiley.co...26d45d5b26730fe5389fc376172c8.pdf.txtExtracted texttext/plain78697https://repositorio.ufba.br/bitstream/ri/6045/3/__onlinelibrary.wiley.co...26d45d5b26730fe5389fc376172c8.pdf.txt36698d2aeb5bbe9ea32fea95c1c89d32MD53ri/60452022-08-26 11:47:07.509oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-08-26T14:47:07Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false |
dc.title.pt_BR.fl_str_mv |
Optimal operating policies for tailored linear polyethylene resins production |
dc.title.alternative.pt_BR.fl_str_mv |
AIChE Journal |
title |
Optimal operating policies for tailored linear polyethylene resins production |
spellingShingle |
Optimal operating policies for tailored linear polyethylene resins production Pontes, Karen Valverde Mathematical modeling optimization polymerization simulation process design (process simulation) |
title_short |
Optimal operating policies for tailored linear polyethylene resins production |
title_full |
Optimal operating policies for tailored linear polyethylene resins production |
title_fullStr |
Optimal operating policies for tailored linear polyethylene resins production |
title_full_unstemmed |
Optimal operating policies for tailored linear polyethylene resins production |
title_sort |
Optimal operating policies for tailored linear polyethylene resins production |
author |
Pontes, Karen Valverde |
author_facet |
Pontes, Karen Valverde Maciel, R. Embiruçu, Marcelo Hartwich, A. Marquardt, W. |
author_role |
author |
author2 |
Maciel, R. Embiruçu, Marcelo Hartwich, A. Marquardt, W. |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Pontes, Karen Valverde Maciel, R. Embiruçu, Marcelo Hartwich, A. Marquardt, W. Pontes, Karen Valverde Maciel, R. Embiruçu, Marcelo Hartwich, A. Marquardt, W. |
dc.subject.por.fl_str_mv |
Mathematical modeling optimization polymerization simulation process design (process simulation) |
topic |
Mathematical modeling optimization polymerization simulation process design (process simulation) |
description |
Acesso restrito: Texto completo. p. 2346-2365 |
publishDate |
2008 |
dc.date.issued.fl_str_mv |
2008 |
dc.date.accessioned.fl_str_mv |
2012-06-01T13:35:53Z |
dc.type.driver.fl_str_mv |
Artigo de Periódico info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.repositorio.ufba.br/ri/handle/ri/6045 |
dc.identifier.issn.none.fl_str_mv |
0001-1541 |
dc.identifier.number.pt_BR.fl_str_mv |
v. 54, n. 9 |
identifier_str_mv |
0001-1541 v. 54, n. 9 |
url |
http://www.repositorio.ufba.br/ri/handle/ri/6045 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
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openAccess |
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http://onlinelibrary.wiley.com/doi/10.1002/aic.11566/pdf |
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reponame:Repositório Institucional da UFBA instname:Universidade Federal da Bahia (UFBA) instacron:UFBA |
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UFBA |
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