One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media
Autor(a) principal: | |
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Data de Publicação: | 2011 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFBA |
Texto Completo: | http://www.repositorio.ufba.br/ri/handle/ri/5448 |
Resumo: | texto completo: acesso restrito. p. 9653–9658. |
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Cunha, Vitor Hugo Moreau daVéras, Ilvania CostaSilva, Frederico A. L.Gonzales, Astria Dias FerrãoCunha, Vitor Hugo Moreau daVéras, Ilvania CostaSilva, Frederico A. L.Gonzales, Astria Dias Ferrão2012-02-25T15:13:53Z20111873-2976http://www.repositorio.ufba.br/ri/handle/ri/5448v. 102.texto completo: acesso restrito. p. 9653–9658.This work aims to demonstrate the enzymatic production of fatty acid ethyl ester biodiesel from highly acidic feedstock in a single-step reaction, without co-solvents and avoiding the inhibition of the enzyme by ethanol and glycerol. Additionally, an empirical equation is proposed to predict the kinetics of the production reaction as a function of the used feedstock and catalyst concentration. Biodiesel production from highly acidic feedstock perform via simultaneous esterification of free fatty acids and transesterification of triacylglycerols. Enzymatic catalysis is one of the most promising alternative technologies for the biodiesel production. Increasing of the enzymatic bioactivity is crucial for the success of such process in industrial scale. Currently, stepwise addition of the alcohol or the use of co-solvents have been proposed to avoid enzyme inhibition, such strategies add downstream processes to the production. These results can be applied to the development economical-viable enzymatic production of biodiesel in industrial scale.Submitted by Ana Valéria de Jesus Moura (anavaleria_131@hotmail.com) on 2012-02-25T15:13:53Z No. of bitstreams: 1 nps70.tmp.pdf: 136822 bytes, checksum: b2b15cdfd1cd8a7b3109915462010189 (MD5)Made available in DSpace on 2012-02-25T15:13:53Z (GMT). No. of bitstreams: 1 nps70.tmp.pdf: 136822 bytes, checksum: b2b15cdfd1cd8a7b3109915462010189 (MD5) Previous issue date: 2011doi:10.1016/j.biortech.2011.08.012reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBAEnzymatic productionLipaseBiodieselSolvent-free mediumOne-stepOne-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free mediaBioresource Technology journalinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10000-01-01enginfo:eu-repo/semantics/openAccessLICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/5448/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52ORIGINALnps70.tmp.pdfnps70.tmp.pdfapplication/pdf136822https://repositorio.ufba.br/bitstream/ri/5448/1/nps70.tmp.pdfb2b15cdfd1cd8a7b3109915462010189MD51TEXTnps70.tmp.pdf.txtnps70.tmp.pdf.txtExtracted texttext/plain35721https://repositorio.ufba.br/bitstream/ri/5448/3/nps70.tmp.pdf.txt114f5f3200da8a78b6eb973d2f5b6704MD53ri/54482022-07-05 14:03:21.35oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-07-05T17:03:21Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false |
dc.title.pt_BR.fl_str_mv |
One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media |
dc.title.alternative.pt_BR.fl_str_mv |
Bioresource Technology journal |
title |
One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media |
spellingShingle |
One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media Cunha, Vitor Hugo Moreau da Enzymatic production Lipase Biodiesel Solvent-free medium One-step |
title_short |
One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media |
title_full |
One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media |
title_fullStr |
One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media |
title_full_unstemmed |
One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media |
title_sort |
One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media |
author |
Cunha, Vitor Hugo Moreau da |
author_facet |
Cunha, Vitor Hugo Moreau da Véras, Ilvania Costa Silva, Frederico A. L. Gonzales, Astria Dias Ferrão |
author_role |
author |
author2 |
Véras, Ilvania Costa Silva, Frederico A. L. Gonzales, Astria Dias Ferrão |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Cunha, Vitor Hugo Moreau da Véras, Ilvania Costa Silva, Frederico A. L. Gonzales, Astria Dias Ferrão Cunha, Vitor Hugo Moreau da Véras, Ilvania Costa Silva, Frederico A. L. Gonzales, Astria Dias Ferrão |
dc.subject.por.fl_str_mv |
Enzymatic production Lipase Biodiesel Solvent-free medium One-step |
topic |
Enzymatic production Lipase Biodiesel Solvent-free medium One-step |
description |
texto completo: acesso restrito. p. 9653–9658. |
publishDate |
2011 |
dc.date.issued.fl_str_mv |
2011 |
dc.date.accessioned.fl_str_mv |
2012-02-25T15:13:53Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.repositorio.ufba.br/ri/handle/ri/5448 |
dc.identifier.issn.none.fl_str_mv |
1873-2976 |
dc.identifier.number.pt_BR.fl_str_mv |
v. 102. |
identifier_str_mv |
1873-2976 v. 102. |
url |
http://www.repositorio.ufba.br/ri/handle/ri/5448 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.pt_BR.fl_str_mv |
doi:10.1016/j.biortech.2011.08.012 |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFBA instname:Universidade Federal da Bahia (UFBA) instacron:UFBA |
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Universidade Federal da Bahia (UFBA) |
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UFBA |
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UFBA |
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Repositório Institucional da UFBA |
collection |
Repositório Institucional da UFBA |
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