One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media

Detalhes bibliográficos
Autor(a) principal: Cunha, Vitor Hugo Moreau da
Data de Publicação: 2011
Outros Autores: Véras, Ilvania Costa, Silva, Frederico A. L., Gonzales, Astria Dias Ferrão
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFBA
Texto Completo: http://www.repositorio.ufba.br/ri/handle/ri/5448
Resumo: texto completo: acesso restrito. p. 9653–9658.
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spelling Cunha, Vitor Hugo Moreau daVéras, Ilvania CostaSilva, Frederico A. L.Gonzales, Astria Dias FerrãoCunha, Vitor Hugo Moreau daVéras, Ilvania CostaSilva, Frederico A. L.Gonzales, Astria Dias Ferrão2012-02-25T15:13:53Z20111873-2976http://www.repositorio.ufba.br/ri/handle/ri/5448v. 102.texto completo: acesso restrito. p. 9653–9658.This work aims to demonstrate the enzymatic production of fatty acid ethyl ester biodiesel from highly acidic feedstock in a single-step reaction, without co-solvents and avoiding the inhibition of the enzyme by ethanol and glycerol. Additionally, an empirical equation is proposed to predict the kinetics of the production reaction as a function of the used feedstock and catalyst concentration. Biodiesel production from highly acidic feedstock perform via simultaneous esterification of free fatty acids and transesterification of triacylglycerols. Enzymatic catalysis is one of the most promising alternative technologies for the biodiesel production. Increasing of the enzymatic bioactivity is crucial for the success of such process in industrial scale. Currently, stepwise addition of the alcohol or the use of co-solvents have been proposed to avoid enzyme inhibition, such strategies add downstream processes to the production. These results can be applied to the development economical-viable enzymatic production of biodiesel in industrial scale.Submitted by Ana Valéria de Jesus Moura (anavaleria_131@hotmail.com) on 2012-02-25T15:13:53Z No. of bitstreams: 1 nps70.tmp.pdf: 136822 bytes, checksum: b2b15cdfd1cd8a7b3109915462010189 (MD5)Made available in DSpace on 2012-02-25T15:13:53Z (GMT). No. of bitstreams: 1 nps70.tmp.pdf: 136822 bytes, checksum: b2b15cdfd1cd8a7b3109915462010189 (MD5) Previous issue date: 2011doi:10.1016/j.biortech.2011.08.012reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBAEnzymatic productionLipaseBiodieselSolvent-free mediumOne-stepOne-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free mediaBioresource Technology journalinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10000-01-01enginfo:eu-repo/semantics/openAccessLICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/5448/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52ORIGINALnps70.tmp.pdfnps70.tmp.pdfapplication/pdf136822https://repositorio.ufba.br/bitstream/ri/5448/1/nps70.tmp.pdfb2b15cdfd1cd8a7b3109915462010189MD51TEXTnps70.tmp.pdf.txtnps70.tmp.pdf.txtExtracted texttext/plain35721https://repositorio.ufba.br/bitstream/ri/5448/3/nps70.tmp.pdf.txt114f5f3200da8a78b6eb973d2f5b6704MD53ri/54482022-07-05 14:03:21.35oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-07-05T17:03:21Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false
dc.title.pt_BR.fl_str_mv One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media
dc.title.alternative.pt_BR.fl_str_mv Bioresource Technology journal
title One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media
spellingShingle One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media
Cunha, Vitor Hugo Moreau da
Enzymatic production
Lipase
Biodiesel
Solvent-free medium
One-step
title_short One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media
title_full One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media
title_fullStr One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media
title_full_unstemmed One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media
title_sort One-step enzymatic production of fatty acid ethyl ester from high-acidity waste feedstocks in solvent-free media
author Cunha, Vitor Hugo Moreau da
author_facet Cunha, Vitor Hugo Moreau da
Véras, Ilvania Costa
Silva, Frederico A. L.
Gonzales, Astria Dias Ferrão
author_role author
author2 Véras, Ilvania Costa
Silva, Frederico A. L.
Gonzales, Astria Dias Ferrão
author2_role author
author
author
dc.contributor.author.fl_str_mv Cunha, Vitor Hugo Moreau da
Véras, Ilvania Costa
Silva, Frederico A. L.
Gonzales, Astria Dias Ferrão
Cunha, Vitor Hugo Moreau da
Véras, Ilvania Costa
Silva, Frederico A. L.
Gonzales, Astria Dias Ferrão
dc.subject.por.fl_str_mv Enzymatic production
Lipase
Biodiesel
Solvent-free medium
One-step
topic Enzymatic production
Lipase
Biodiesel
Solvent-free medium
One-step
description texto completo: acesso restrito. p. 9653–9658.
publishDate 2011
dc.date.issued.fl_str_mv 2011
dc.date.accessioned.fl_str_mv 2012-02-25T15:13:53Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://www.repositorio.ufba.br/ri/handle/ri/5448
dc.identifier.issn.none.fl_str_mv 1873-2976
dc.identifier.number.pt_BR.fl_str_mv v. 102.
identifier_str_mv 1873-2976
v. 102.
url http://www.repositorio.ufba.br/ri/handle/ri/5448
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.pt_BR.fl_str_mv doi:10.1016/j.biortech.2011.08.012
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFBA
instname:Universidade Federal da Bahia (UFBA)
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reponame_str Repositório Institucional da UFBA
collection Repositório Institucional da UFBA
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