A chemical study of b-carotene oxidation by ozone in an organic model system and the identification of the resulting products
Autor(a) principal: | |
---|---|
Data de Publicação: | 2011 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFBA |
Texto Completo: | http://www.repositorio.ufba.br/ri/handle/ri/5339 |
Resumo: | Acesso restrito: Texto completo. p. 927-934. |
id |
UFBA-2_6476a1b426183bc2223010d3d40b5544 |
---|---|
oai_identifier_str |
oai:repositorio.ufba.br:ri/5339 |
network_acronym_str |
UFBA-2 |
network_name_str |
Repositório Institucional da UFBA |
repository_id_str |
1932 |
spelling |
Benevides, Clícia Maria de JesusVeloso, Márcia Cristina da CunhaPereira, Pedro Afonso de PaulaAndrade, Jailson Bittencourt deBenevides, Clícia Maria de JesusVeloso, Márcia Cristina da CunhaPereira, Pedro Afonso de PaulaAndrade, Jailson Bittencourt de2012-02-08T17:30:45Z20110308-8146http://www.repositorio.ufba.br/ri/handle/ri/5339v. 126, n. 3.Acesso restrito: Texto completo. p. 927-934.Carotenoids are present in many foods. Due to their polyenic chains, they undergo oxidation reactions which may give several compounds. Ozone, a powerful antimicrobial agent, is applied in the food industry due to its high reactivity and penetrability. This work presents a chemical study of the degradation of b-carotene in solutions, under the influence of ozone. The experiments were carried out at ozone concentrations ranging from 0.8 to 2.5 ppm and the b-carotene solutions were sampled and analysed from zero to seven hours of reaction. The oxidation products were collected in C18 cartridges coated with dinitrophenylhydrazine and the hydrazones formed were analysed by LC-MS. The oxidation reaction was found to follow a zero order kinetic model and the b-carotene decay ranged between 17.2% and 99.8%. Fourteen oxidation products were tentatively identified, amongst them eight which had not been cited yet in the literature as oxidation products of b-carotene.Submitted by JURANDI DE SOUZA SILVA (jssufba@hotmail.com) on 2012-02-08T17:30:45Z No. of bitstreams: 1 __pdn.sciencedirect.com_....0-S0308814610015001-main.pdf: 145019 bytes, checksum: 0f4b5180eebe7702c86b55a23c02c2f9 (MD5)Made available in DSpace on 2012-02-08T17:30:45Z (GMT). No. of bitstreams: 1 __pdn.sciencedirect.com_....0-S0308814610015001-main.pdf: 145019 bytes, checksum: 0f4b5180eebe7702c86b55a23c02c2f9 (MD5) Previous issue date: 2011-06http://dx.doi.org.ez10.periodicos.capes.gov.br/10.1016/j.foodchem.2010.11.082reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBAb-CaroteneOzonolysisOrganic model systemOxidation productsLC-MSA chemical study of b-carotene oxidation by ozone in an organic model system and the identification of the resulting productsFood chemistryinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10000-01-01enginfo:eu-repo/semantics/openAccessORIGINAL__pdn.sciencedirect.com_....0-S0308814610015001-main.pdf__pdn.sciencedirect.com_....0-S0308814610015001-main.pdfapplication/pdf145019https://repositorio.ufba.br/bitstream/ri/5339/1/__pdn.sciencedirect.com_....0-S0308814610015001-main.pdf0f4b5180eebe7702c86b55a23c02c2f9MD51LICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/5339/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52TEXT__pdn.sciencedirect.com_....0-S0308814610015001-main.pdf.txt__pdn.sciencedirect.com_....0-S0308814610015001-main.pdf.txtExtracted texttext/plain35610https://repositorio.ufba.br/bitstream/ri/5339/3/__pdn.sciencedirect.com_....0-S0308814610015001-main.pdf.txtb164707e788f80d0614874669f7a7420MD53ri/53392022-10-08 11:42:51.689oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-10-08T14:42:51Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false |
dc.title.pt_BR.fl_str_mv |
A chemical study of b-carotene oxidation by ozone in an organic model system and the identification of the resulting products |
dc.title.alternative.pt_BR.fl_str_mv |
Food chemistry |
title |
A chemical study of b-carotene oxidation by ozone in an organic model system and the identification of the resulting products |
spellingShingle |
A chemical study of b-carotene oxidation by ozone in an organic model system and the identification of the resulting products Benevides, Clícia Maria de Jesus b-Carotene Ozonolysis Organic model system Oxidation products LC-MS |
title_short |
A chemical study of b-carotene oxidation by ozone in an organic model system and the identification of the resulting products |
title_full |
A chemical study of b-carotene oxidation by ozone in an organic model system and the identification of the resulting products |
title_fullStr |
A chemical study of b-carotene oxidation by ozone in an organic model system and the identification of the resulting products |
title_full_unstemmed |
A chemical study of b-carotene oxidation by ozone in an organic model system and the identification of the resulting products |
title_sort |
A chemical study of b-carotene oxidation by ozone in an organic model system and the identification of the resulting products |
author |
Benevides, Clícia Maria de Jesus |
author_facet |
Benevides, Clícia Maria de Jesus Veloso, Márcia Cristina da Cunha Pereira, Pedro Afonso de Paula Andrade, Jailson Bittencourt de |
author_role |
author |
author2 |
Veloso, Márcia Cristina da Cunha Pereira, Pedro Afonso de Paula Andrade, Jailson Bittencourt de |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Benevides, Clícia Maria de Jesus Veloso, Márcia Cristina da Cunha Pereira, Pedro Afonso de Paula Andrade, Jailson Bittencourt de Benevides, Clícia Maria de Jesus Veloso, Márcia Cristina da Cunha Pereira, Pedro Afonso de Paula Andrade, Jailson Bittencourt de |
dc.subject.por.fl_str_mv |
b-Carotene Ozonolysis Organic model system Oxidation products LC-MS |
topic |
b-Carotene Ozonolysis Organic model system Oxidation products LC-MS |
description |
Acesso restrito: Texto completo. p. 927-934. |
publishDate |
2011 |
dc.date.issued.fl_str_mv |
2011 |
dc.date.accessioned.fl_str_mv |
2012-02-08T17:30:45Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.repositorio.ufba.br/ri/handle/ri/5339 |
dc.identifier.issn.none.fl_str_mv |
0308-8146 |
dc.identifier.number.pt_BR.fl_str_mv |
v. 126, n. 3. |
identifier_str_mv |
0308-8146 v. 126, n. 3. |
url |
http://www.repositorio.ufba.br/ri/handle/ri/5339 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.pt_BR.fl_str_mv |
http://dx.doi.org.ez10.periodicos.capes.gov.br/10.1016/j.foodchem.2010.11.082 |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFBA instname:Universidade Federal da Bahia (UFBA) instacron:UFBA |
instname_str |
Universidade Federal da Bahia (UFBA) |
instacron_str |
UFBA |
institution |
UFBA |
reponame_str |
Repositório Institucional da UFBA |
collection |
Repositório Institucional da UFBA |
bitstream.url.fl_str_mv |
https://repositorio.ufba.br/bitstream/ri/5339/1/__pdn.sciencedirect.com_....0-S0308814610015001-main.pdf https://repositorio.ufba.br/bitstream/ri/5339/2/license.txt https://repositorio.ufba.br/bitstream/ri/5339/3/__pdn.sciencedirect.com_....0-S0308814610015001-main.pdf.txt |
bitstream.checksum.fl_str_mv |
0f4b5180eebe7702c86b55a23c02c2f9 1b89a9a0548218172d7c829f87a0eab9 b164707e788f80d0614874669f7a7420 |
bitstream.checksumAlgorithm.fl_str_mv |
MD5 MD5 MD5 |
repository.name.fl_str_mv |
Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA) |
repository.mail.fl_str_mv |
|
_version_ |
1808459394209284096 |