2-(2-Thiazolylazo)-p-cresol (TAC) as a reagent for the spectrophotometric determination of indium(III)

Detalhes bibliográficos
Autor(a) principal: Ferreira, Sergio Luis Costa
Data de Publicação: 1991
Outros Autores: Costa, Antonio Celso Spinola, Andrade, H. A. S.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFBA
Texto Completo: http://www.repositorio.ufba.br/ri/handle/ri/7470
Resumo: Texto completo: acesso restrito. p. 63-66
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spelling Ferreira, Sergio Luis CostaCosta, Antonio Celso SpinolaAndrade, H. A. S.Ferreira, Sergio Luis CostaCosta, Antonio Celso SpinolaAndrade, H. A. S.2012-12-12T18:38:31Z2012-12-12T18:38:31Z19910026-265Xhttp://www.repositorio.ufba.br/ri/handle/ri/7470v. 44, n.1Texto completo: acesso restrito. p. 63-66The reaction between indium(III) and the 2-(2-thiazolylazo)-p-cresol (TAC) in aqueous methanol media at apparent pH 5.0–6.0 results in an intensely colored complex which is stable for at least 2 h. The composition is 1:2 cation: TAC and the log of the formation constant is 10.78 ± 0.64. Beer's law is obeyed up to 8.0 μg · ml−1 of indium(III) at 580 nm. The apparent molar absorptivity at 580 nm is 1.21 × 104 liter · mol−1 · cm−1 and the detection limit was obtained as 10.0 ng · ml−1 of indium(III). The method is applied to the determination of indium in a catalyst.Submitted by Santiago Fabio (fabio.ssantiago@hotmail.com) on 2012-12-12T18:38:31Z No. of bitstreams: 1 11222.pdf: 235975 bytes, checksum: d2468d823b0e2bf1156e65d79bd74576 (MD5)Made available in DSpace on 2012-12-12T18:38:31Z (GMT). No. of bitstreams: 1 11222.pdf: 235975 bytes, checksum: d2468d823b0e2bf1156e65d79bd74576 (MD5) Previous issue date: 1991SalvadorMicrochemical Journalhttp://dx.doi.org/10.1016/0026-265X(91)90077-3reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBA2-(2-Thiazolylazo)-p-cresol (TAC) as a reagent for the spectrophotometric determination of indium(III)Microchemical Journalinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleenginfo:eu-repo/semantics/openAccessORIGINAL11222.pdf11222.pdfapplication/pdf235975https://repositorio.ufba.br/bitstream/ri/7470/1/11222.pdfd2468d823b0e2bf1156e65d79bd74576MD51LICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/7470/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52TEXT11222.pdf.txt11222.pdf.txtExtracted texttext/plain9104https://repositorio.ufba.br/bitstream/ri/7470/3/11222.pdf.txtfac4c791e004de0686df9cad0b98cebaMD53ri/74702022-07-05 14:03:19.7oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-07-05T17:03:19Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false
dc.title.pt_BR.fl_str_mv 2-(2-Thiazolylazo)-p-cresol (TAC) as a reagent for the spectrophotometric determination of indium(III)
dc.title.alternative.pt_BR.fl_str_mv Microchemical Journal
title 2-(2-Thiazolylazo)-p-cresol (TAC) as a reagent for the spectrophotometric determination of indium(III)
spellingShingle 2-(2-Thiazolylazo)-p-cresol (TAC) as a reagent for the spectrophotometric determination of indium(III)
Ferreira, Sergio Luis Costa
title_short 2-(2-Thiazolylazo)-p-cresol (TAC) as a reagent for the spectrophotometric determination of indium(III)
title_full 2-(2-Thiazolylazo)-p-cresol (TAC) as a reagent for the spectrophotometric determination of indium(III)
title_fullStr 2-(2-Thiazolylazo)-p-cresol (TAC) as a reagent for the spectrophotometric determination of indium(III)
title_full_unstemmed 2-(2-Thiazolylazo)-p-cresol (TAC) as a reagent for the spectrophotometric determination of indium(III)
title_sort 2-(2-Thiazolylazo)-p-cresol (TAC) as a reagent for the spectrophotometric determination of indium(III)
author Ferreira, Sergio Luis Costa
author_facet Ferreira, Sergio Luis Costa
Costa, Antonio Celso Spinola
Andrade, H. A. S.
author_role author
author2 Costa, Antonio Celso Spinola
Andrade, H. A. S.
author2_role author
author
dc.contributor.author.fl_str_mv Ferreira, Sergio Luis Costa
Costa, Antonio Celso Spinola
Andrade, H. A. S.
Ferreira, Sergio Luis Costa
Costa, Antonio Celso Spinola
Andrade, H. A. S.
description Texto completo: acesso restrito. p. 63-66
publishDate 1991
dc.date.issued.fl_str_mv 1991
dc.date.accessioned.fl_str_mv 2012-12-12T18:38:31Z
dc.date.available.fl_str_mv 2012-12-12T18:38:31Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
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status_str publishedVersion
dc.identifier.uri.fl_str_mv http://www.repositorio.ufba.br/ri/handle/ri/7470
dc.identifier.issn.none.fl_str_mv 0026-265X
dc.identifier.number.pt_BR.fl_str_mv v. 44, n.1
identifier_str_mv 0026-265X
v. 44, n.1
url http://www.repositorio.ufba.br/ri/handle/ri/7470
dc.language.iso.fl_str_mv eng
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dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
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dc.publisher.none.fl_str_mv Microchemical Journal
publisher.none.fl_str_mv Microchemical Journal
dc.source.pt_BR.fl_str_mv http://dx.doi.org/10.1016/0026-265X(91)90077-3
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